Foam Glass Crystalline Granular Material from a Polymineral Raw Mix

The article is devoted to the development of resource-saving technology of porous granular materials for energy-efficient construction. The relevance of the work for international research is to emphasize expanding the raw material base of porous lightweight concrete aggregates at the expense of technogenic and substandard materials. The work aims to study the processes of porization of glass crystalline granules from polymineral raw materials mixtures. The novelty of the work lies in the establishment of regularities of thermal foaming of glass crystalline granules when using waste of magnetic separation of skarn-magnetite (WMS) ores and lignite clay. Studies of liquid glass mixtures with various mineral fillers revealed the possibility of the formation of a porous structure with the participation of opoka, WMS and lignite clay. This is due to the presence in the materials of substances that exhibit thermal activity with the release of a gas phase. The foaming efficiency of the investigated materials increases when combined with glass breakage. The addition of WMS and lignite clay to the glass mixture increases the pore size in comparison with foam glass. The influence of the composition of raw mixtures on the molding and stability of granules is determined. The addition of sodium carbonate helps to strengthen the raw granules and reduce the softening temperature of the mass. The composition of the molding mixture of glass breakage, liquid glass and a multicomponent additive is developed, which provides an improvement in the molding properties of the glass mass, foaming of granules at a temperature of 750 °C. Foam glass crystalline granules have polymodal porosity, characterized by a density of 330–350 kg/m3, a compressive strength of 3.2–3.7 MPa, and a thermal conductivity of 0.057–0.061 W/(m·°C). Accordingly, the developed granules have a high potential use in structural and heat-insulating concretes.

Porcelain Enamel Coatings

Porcelain enamel is an inorganic-type coating, which is applied to metals or glass for both decorative and functional purposes. This coating is a silica-based solidified glass mass obtained by high-temperature firing (temperature can range between 450 and 1200 °C depending on the substrate). Porcelain enamel coatings differ from ceramic coatings mainly by their glass structure and dilatation coefficient, and from organic paints mainly by the inorganic nature of the matrix and the chemical bond that exists between the coating and the substrate.

The effect of the conductive walls of the cooking furnace of an electric furnace on the distribution of energy flows

A method for modeling the electric glass melting process, which allows obtaining information about the unity of electric and thermal processes in the glass mass in an electric glass melting furnace has been developed. The furnace’s cooking pool is made of conductive chromoxide. The work was carried out using modeling on the EGDA integrator, as a result of which two versions of experimental electric furnaces with different directions of power lines and a pilot industrial furnace with a capacity of 7 tons per day for melting E glass, widely used in the manufacture of fiberglass, were built.

Electrical properties of graphite-glass thick-film resistors

Purpose The purpose of this paper is to present the properties of thick-film resistors made of novel pastes prepared from glass and graphite. Design/methodology/approach Graphite-based resistors were made of thick-film pastes with different graphite-to-glass mass fraction were prepared and examined. Sheet resistance, temperature coefficient of resistance, impact of humidity and short-term overload were investigated. The properties of the layers fired in atmospheres of air at 550°C and nitrogen at 875°C were compared. Findings Graphite-based resistors with various graphite-to-glass ratios made possible to obtain a wide range of sheet resistance from single O/square to few kO/square. These values were dependent on firing atmosphere, paste composition and the number of screen-printed layers. The samples made of paste with 1:1 graphite-to-glass ratio exhibited the temperature coefficient of resistance of about −1,000 ppm/°C, almost independently on the firing atmosphere and presence of a top coating. The resistors fired in the air after coating with overglaze, exhibited significantly lower sheet resistance, reduced impact of humidity and improved power capabilities. Originality/value In this paper, graphite-based resistors for applications in typical high-temperature cermet thick-film circuits were presented, whereas typical graphite-based resistors were fabricated in polymer thick-film technology. Owing to very low cost of the graphite, the material is suitable for low-power passive circuits, where components are not subjected into high temperature, above the typical temperature of operation of standard electronic components.

Influence of the increased content of Calumite blast-furnace slag on the melting of sodium–calcium–silicate glass

A glass set with a high content of blast-furnace slag and a reduced amount of traditional raw materials requires optimization of the raw material composition and adjustment of its specificity to the temperature regime of melting, homogenizing and clarifying the glass mass. The introduction of an increased amount of blast-furnace slag allows to reduce the cost of raw materials: soda, limestone and high-class sand, reduce energy costs, whose consumption significantly decreases and reduces CO2 emissions in line with EU requirements. The tests of thermal analysis of a glass set with different contents of Calumite are aimed at learning the mechanism of its operation by determining the changes caused by its different presence in the course of subsequent reactions between the components of the glass set. Analysis of the influence of the addition of different Calumite slag contents treated as a substitute for the raw material on the melting process of glassware sets was analyzed. The tests were carried out using differential thermal analysis (DTA) and thermogravimetry (TG) based on the model glass [mass%]: 73.0% SiO2, 1.0% Al2O3, 10.0% CaO, 2.0% MgO and 14.0% Na2O. The effect of combining Calumite with sulphate and multi-component fining agent—mixtures of As2O3, Sb2O3, NaNO3 in proportions of 1:1:1 for chemical reaction and phase transformation, was investigated.

Improving Strength of Structural Steels by Preheating in an Oxygen-Containing Medium

The results of the preliminary heat treatment effecting in a medium with a high oxygen content on the microstructure and mechanical properties of structural steels are presented. It is shown that the usage of preheating in the glass mass in the range of (Ac130°C) – Ac1for steels of grades 50 and 40H leads to the formation of a structure with dispersed granular pearlite and crushed excess ferrite precipitates. Such a structure, when heated for quenching, provides rapid formation of a homogeneous austenite and a delay in the growth of austenite grain, which provides the best combination of strength and plasticity after the final heat treatment. It is established that the tensile strength increases 1.2-1.3 times while maintaining the plasticity characteristics. The reliability of the obtained estimates of the mechanical property characteristics is confirmed by the results of a statistical analysis.

CLAY MOLDS FOR MAKING GLASS VESSELS (after data from the excavations of the medieval production complex on Kyiv Podil District)

A unique find of four clay molds for making glass vessels was found during archaeological researches of the site on the Naberezhno-Khreshchatitska str., 21 (Kyiv Podil) in 2007. The excavations both on the street itself and on the bordering areas revealed the existence here of a large handicraft quarter with economic and production objects dated to the 11th and 12th centuries. Location of the studied site near the waterway (Dnieper River) was convenient for placing here fire-hazardous productions, such as glass-making workshops. On the site, remains of the construction of the furnace in the form of large pieces of vitrified clay and fragments of plinth form bricks were fixed. Numerous pieces of glass were found, as well as fragments of glassware, mainly those of bracelets and vessels. Among another finds there were such glass ornaments as beads and rings, and one inset for the ring. Among the ceramic material from the investigated complex, there were four clay molds for forming glass vessels. The molds were of bowl-like form and had a ribbed inner surface, made by hand. It is worthy to note that among the products there were two fragments of glass bottoms with ribbed outer surfaces, which could be made in such molds. Vessels with ribbed walls appear on the territory of Ancient Rus’ from the second half of the 12th century. Chemical analyzes of glass mass taken from the complex showed that samples could be identified as lead-potassium Ancient Rus’ glass. Glassware, certain materials (molds for glass vessels, crucibles, pieces of lead), allow to connect the excavated complex with glass-making production.

Preparation and properties of poly(ε-caprolactone)/bioactive glass nanofibre membranes for skin tissue engineering

Poly(ε-caprolactone) composite nanofibres for skin tissue engineering and regeneration applications were prepared via electrospinning of poly(ε-caprolactone) nanofibres with bioactive glass nanoparticles at bioactive glass contents of 0, 2, 4, 6 and 8 wt%. The surface properties, water absorptivities, porosities, mechanical properties and biocompatibilities of the composite electrospun nanofibres were characterised in detail. Addition of bioactive glass improved the hydrophilicity and elastic modulus of membranes. The fibre diameter of the neat poly(ε-caprolactone) nanofibres was only 700 nm, but reinforcement with 2, 4, 6 and 8 wt% bioactive glass nanofibres increased the diameter to 1000, 1100, 900 and 800 nm, respectively. The minimum elongation at break of the bioactive glass–reinforced poly(ε-caprolactone) exceeded 100%, which indicated that the composite nanofibres had good mechanical properties. The porosities of the various nanofibres containing different mass loadings of bioactive glass all exceeded 90%. The best performance in terms of cell proliferation and adhesion was found when the bioactive glass mass percent reached 6 wt%. However, higher loadings were unfavourable for cell growth. These preliminary results indicate that poly(ε-caprolactone)/bioactive glass composite nanofibres have promise for skin tissue engineering applications.