Sedimentology and ichnology of the mid-Cretaceous succession of Ouled Nail Mounts (Eastern Saharan Atlas, Algeria)

Shallow marine deposits characterize the upper Albian – lower Cenomanian deposits of Northern Algeria. In Djebel Azzeddine (Ouled Nail Mounts), the corresponding sediments have been subdivided into three distinctive units A to C. The first discovered ammonite fauna from the Bou Saada area allowed the attribution of a part of the mid-Cretaceous post-Continental Intercalaire deposits to the upper Albian. The ammonite-bearing level indicates a maximum flooding surface and could be correlated with similar levels from Northern Algeria. The studied succession is characterized by a low ichnodiversity containing eight ichnotaxa with abundant Thalassinoides, common Skolithos, and rare Gyrolithes, Oichnus, Planolites and cf. Tisoa. This ichnoassemblage is dominated by domichnion, fodinichnion and praedichnion trace fossils, and is attributed to the Skolithos and Glossifungites ichnofacies. These traces are produced mainly by decapod crustaceans, polychaetes and naticid gastropods. The sedimentological and ichnological data suggest shoreface to backshore environments with mixed tide/storm energy, and long subaerial exposures indicated by Lofer cyclothems in the lowermost part and dinosaur footprints in the upper part of the section.

Mineral assemblage and provenance of the Pliocene Viviparus beds from the Area of Vukomeričke Gorice (Central Croatia)

Viviparus beds are sediments deposited in lacustrine and fluvial freshwater environments (Lake Slavonia) during the Pliocene and the earliest Pleistocene. A detailed field study and mineralogical, petrographic and chemical analyses were carried out to determine their composition and origin in the area of Vukomeričke Gorice, Central Croatia. Viviparus beds are characterized by the vertical and lateral exchange of mineralogically and chemically mature pelites and sands. Pelitic sediments consist mainly of detrital quartz, calcite, dolomite and feldspar grains, with smectite as the most common clay mineral. Quartz and the most resistant lithic fragments dominate the sandy detritus. The composition of the sediments indicates their origin from the recycled orogen, while their textural immaturity suggests a short transport distance. Most of the material was re-deposited from the underlying Upper Miocene sediments, originally of Alpine provenance. A lesser proportion originated from Palaeogene sediments, Triassic carbonate rocks, basic or acidic magmatic rocks and metamorphites. The Medvednica and Žumberak Mts. were the most important source areas, while a smaller proportion of the material could have come from the Moslavačka gora Mt. and Banovina region. The uniform composition of the Viviparus beds over the entire vertical distribution of the sediments clearly indicates that the source areas did not change during their deposition. A significant change from the texturally and compositionally mature Upper Miocene clastic detritus of alpine origin, to the texturally immature material of the Viviparus beds of local origin is a consequence of compression and inversion of the previously extensional basin resulting in the uplifting and erosion of the mountains within the SW part of the Pannonian Basin System.

Spatio-temporal variations of cave-air CO2 concentrations in two Croatian show caves: Natural vs. anthropogenic controls

Carbon dioxide (CO2) concentration (CDC) plays an important role in karst processes, governing both carbonate deposition and dissolution, affecting not only natural processes, but also human activities in caves adapted for tourism. Its variations due to various controlling parameters was observed from 2017 to 2021 in two Croatian show caves (Manita peć and Modrič) where we examined inter- and within-cave correlation of internal aerology regarding the sources, sinks and transport mechanism of CDC in a karst conduit setting. In both caves, the main sources of CO2 are: i) plant and microbial activity i.e. root respiration and organic matter decay within soil horizons and fractured epikarst, and ii) degassing from CO2-rich percolation water. The main sink of CO2 is dilution with outside air due to cave ventilation. Chimney-effect driven ventilation controlled by seasonal differences between surface and cave air temperatures shows winter (Tout<Tcave) and summer (Tout>Tcave ) ventilation regime, which are modulated by the geometry of cave passages, the transmissivity of the overlying epikarst, and occasionally by the external winds, especially the gusty north-eastern bora wind. In these terms, the Modrič Cave appears to be more confined and less ventilated, with a substantial CDC difference between the left (550-7200 ppm) and right (1475- >10,000 ppm) passages. The Manita peć Cave is, in contrast, ventilated almost year-round, having 7 months of CDC equilibrated with the outside atmosphere and the highest summer CDC values of ~1410 ppm. In both caves, at the current level of tourist use, anthropogenic CO2 flux is not a matter of concern for cave conservation. In turn, in the innermost part of the right Modrič Cave passage visitors’ health might be compromised, but the tourists are allowed only in the left passage. Speleothem growth rate, recognized as a useful palaeoenvironmental proxy for speleothem-based palaeoclimate studies, strongly depends on CDC variations, so the high CDCs recorded in the Modrič Cave indicate the potential periods with no speleothem deposition due to the hampered degassing of CO2 from the dripping groundwater. The opposite effect i.e. enhanced ventilation (that supports calcite precipitation) during the windy glacials/stadials, as well as substantial vegetational changes must also be taken into consideration when interpreting environmental records from spelean calcite.

Evaluation Of 3D small-scale lithological heterogeneities and pore distribution of the Boda Claystone Formation using X-Ray Computed Tomography images (CT)

This study was undertaken to quantify and evaluate the density and porosity characteristics of a Boda Claystone Formation (BCF) core sample using medical CT. Each voxel of the 3D CT volume was described with three variables: dry CT number, saturated CT number, and effective porosity. Disparity pore voxels were revealed using the genetic groups’ algorithm of data-mining techniques. The K-fold cross-validation algorithm has been applied to determine the number of the most stable cluster. The 3D spatial distributions of voxel-porosity by rock constituents, as well as the 3D distribution of porosity clusters by rock components, were found by Boolean function implementation. The terrigenous detrital fragments had the lowest porosity mean (0.16%) and highest coefficient variation value (1039.39%). While the Fine siltstone component had the highest porosity mean (3.39%) and lower coefficient of variation (134.99%). The difference in the variation of coefficient proportions is related to the outlier ratios in each rock component. Independently of both the rock types and the sedimentary structures, two clusters could be defined: one for the micro-porosity and one for the macro-porosity regimes. The former showed a continuous 3D spatial appearance, while the latter appeared in patches. These patches may also be connected, at least partly, to some local smectite aggregates. These clay minerals could lose their structured water content during vacuuming and swell when adsorbing water during sample saturation. In each rock type, the micro-porosity regime could be related to low-density rock fragments. The mean effective porosity of the micro-pore regime was about 0.02, which corresponds to the petrophysical core measurements. For the macro regimes, the average was 0.1.

Megabeds in Istrian Flysch as markers of synsedimentary tectonics within the Dinaric foredeep (Croatia)

Istrian Flysch was deposited during the Eocene in the Dinaric foredeep and is composed of hemipelagic marls and various gravity flow deposits. The latter are predominantly 5-40 cm thick turbidites, developed mostly as laminated and cross-rippled sandstone beds (Tb-e, Tc-e and Td-e Bouma sequences). In addition to the turbidites, there are deposits characterized by a significant thickness, occasionally more than 10 m, described as complex (bipartite) megabeds. The megabeds are composed of debrites in the lower part (Division I), and high-density turbidites in the upper part (Division II). The distinct clast composition of each megabed indicates that the lithoclasts were derived from tectonically active slopes and fault scarps along which collapses of the different parts of the Cretaceous to Palaeogene neritic carbonate succession, (that underlie the Flysch), occurred. The Division II deposits are well cemented, normally graded calcirudite/calcarenites composed mostly of orthophragminids, nummulitids, and red algae, originating from outer ramp environments. Redeposited marl, observed in the matrix of the debrites and as intraclasts in some megabeds, implies that the collapses along the synsedimentary fault scarps and steep slopes also occurred within the foredeep itself, during the rapid tectono-sedimentary evolution of the Dinaric foreland basin.

The preliminary inventory of coseismic ground failures related to December 2020 – January 2021 Petrinja earthquake series

The most recent major earthquake series struck near Petrinja (December 29th 2020 M 6.2), and triggered extensive ground failures in the wider area of Petrinja, Sisak and Glina. Coseismic ground failures including subsidence dolines, liquefaction and landslides have been documented over a large area by various experts and teams. These data are stored in the newly created inventory, which is openly presented in this paper. This inventory is administered and updated by the Croatian Geological Survey, and will be available online via a Web Map Service (WMS) (www.hgi-cgs.hr). The aim of the inventory is to not only provide data for the development of susceptibility maps and more detailed exploration for possible remediation measures, but also to define the priorities for immediate action. The earthquake triggered the rapid development of dropout dolines which endanger the local populations of the villages of Mečenčani and Borojevići. This is still an ongoing process in the vicinity of the houses and therefore in-situ exploration started immediately. Liquefaction related to alluvial sediments of the Sava, Kupa and Glina rivers occurred almost exclusively in loose and pure sands, and was accompanied by sand boils, subsidence and lateral spreading. Liquefaction also presents a greater hazard because settlement of houses and river embankments occurred. Lateral spreading caused failures of river flood embankments and natural river banks. According to the data known to date, the majority of the coseismic landslides were reactivated with minor displacements. Despite that, it has been recognised that houses at the edge, or in landslide colluvium suffered greater damage than other houses located outside the landslide impact zone.

Planktonic foraminiferal biostratigraphy and lithology of the Upper Cretaceous (upper Campanian-Maastrichtian) and Palaeogene succession of the Palmyrides (Syria)

An upper Campanian to upper Oligocene stratigraphic succession has been examined from six deep exploration wells in the Palmyrides area of Syria. Most of the sedimentary succession contains rich and well to moderately preserved planktonic foraminiferal assemblages that enable successful age determination. The upper Campanian and Maastrichtian planktonic fauna is highly diverse with domination of warm water taxa such as Globotruncana aegyptiaca, Gansserina gansseri, Globotruncanella havanensis, Globotruncanita angulata and Pseudotextularia elegans. The most dramatic turnover occurred across the Cretaceous/Palaeocene boundary when most planktonic foraminiferal species became extinct. The oldest Palaeocene planktonic foraminiferal assemblage, rich in the number of specimens, but not very diverse, includes the following species: Eoglobigerina eobulloides, Globanomalina archeocompressa, Chiloguembelina morsei, Woodringina claytonensis and Parasubbotina pseudobulloides. The late Palaeocene is marked by origination of the morozovellids, acarininids and globanomalinids, while the early Eocene is characterized by a tropical assemblage, dominated by muricate species, and by intensive speciation of Acarinina and Subbotina in the latest part. Most of these species continue into the middle Eocene and become a significant component of the planktonic community. The middle Eocene is characterized by intensive speciation and domination of warm water genera such as Acarinina, Morozovelloides, and to a lesser degree Turborotalia, Globigerinatheka and Hantkenina. The middle/late Eocene boundary is marked by double extinction of the last muricate taxa Acarinina mcgowrani and Morozovelloides crasssatus, which indicate a variable climate, water column instability, and loss of surface habitats. In contrast, Turborotalia and Globigerinateheka become more important in the late Eocene. The Eocene/Oligocene boundary is marked by the extinction of most warm water taxa including Turborotalia cerroazulensis group, Hantkenina, Globigerinatheka and some subbotinids. The beginning of the early Oligocene is indicated by the domination of cool water taxa such as Dentoglobigerina, Globorotaloides, Tenuitella and Chiloguembelina. Speciation of the spinose surface dweller Ciperoella ciperoensis group reflects warming in the late Oligocene. The combined observations of lithology with the diversity and composition of planktonic foraminifera assemblages indicate that the Palmyrides area in Syria was a Tethyan bioprovince with a tropical to subtropical climate from the late Campanian to the end of the Eocene with deposition in deep sea environments (upper bathyal to outer shelf). In contrast, Oligocene deposits and their microfossil content suggest temperate to warm climate conditions and sedimentation in middle to inner shelf environments.

Lithostratigraphy and Sedimentological Characteristics of the Calciturbidites of the Babadağ Formation-Tavas Nappe (SW Turkey)

The Lycian Nappes contain slices of ophiolites and sedimentary rocks of various ages that crop out in SW Turkey. They evolved and were emplaced under the effect of the Late Cretaceous-Miocene compressional regime. The Tavas Nappe is part of the Lycian Nappes and contains Jurassic-Eocene sediments. The Babadağ Formation, forming the middle part of the Tavas Nappe, is composed of limestone at the base and various sized calciturbidites with chert intercalations in the upper part. The Standard Microfacies Classification (SMF of FLÜGEL, 2004) indicates that the entire unit was deposited mainly in a deep-shelf environment (Facies Zone – FZ-2), deep-sea (FZ-1), toe of slope (FZ-3) and on the continental slope (FZ-4). Calcite and quartz dominate the bulk mineralogy of the calciturbidites with higher SiO2 and CaO weight percentages than other major oxides. Additionally, the presence of Na2O, K2O, Al2O3, MgO, TiO2 and Fe2O3 is associated with the local sediment input. Tectonism and sea level fluctuations were the main triggering factors of the changes in the original depositional environment of the Babadağ Formation. Additionally, grain size and the amount of sediment input control the calciturbidite type and extension. Si enriched water circulation and Si and Ca substitution were responsible for the abundant chert formation during diagenesis of the units. Post depositional tectonic activities during transportation and emplacement of the nappes resulted in calcite filled cracks that cut both the calciturbidites and cherts. Study of the different nappe slices provides valuable information about syn- and post- depositional changes of the lithostratigraphic units.

Application of high-resolution remote sensing technology for the iron ore deposits of the West Kunlun Mountains in China

This study focuses on the iron ore of Taxkorgan and Heiqia in the West Kunlun mountains as a case study, for the application of WorldView−2 and IKONOS remote sensing images as major data sources in the fabrication of a standard image map and in the adoption of image enhancement methods to extract information on the ore-controlling factors and mineralization, to interpret remote sensing for the mineral resources in these areas. ASTER, WorldView−2, and IKONOS data were applied for the extraction of alteration anomaly information. With an appropriate amount of field sampling and verification tests, this was used to establish a remote sensing geology prospecting model, that would provide the basis for future remote sensing of metallogenic belts in West Kunlun in the hope of discovering similar minerals. Survey results showed four additional iron ore mineralization belts could be delineated in the Taxkorgan area. A comparative analysis conducted for part of the field confirmation and the known mineral deposits indicated good reliability. In Heiqia, a siderite-haematite mineralization zone was observed with copperlead- zinc formation, 60-km in length and 200–500 m wide, which includes several mineralized bodies. The ore bodies, appear as stratoid, lenticular, or podiform morphologies and were located in the transition site from clastic to carbonate rocks of the D segment in the Wenquangou Group. The ore bodies generally occur within 40°–50° strike and 68°–81° dip, in accordance to the strata. The length of the single body varies from several hundred metres to more than 9500 m. Its exposed thickness on the surface ranges from 2–50 m, and the general thickness was approximately 15 m. The surface ore minerals were mainly haematite and limonite, with a small amount of siderite. Therefore, high-resolution remote sensing technology is suitable for iron ore geological and mineral remote sensing surveying. It is advantageous in both high-ground resolution of optical characteristics and a certain spectral recognition capability, and is effective not only for information extraction from a large area, but also for recognition of local mineralization outcrops. Therefore, high-resolution remote sensing technology is valuable for popularization.

Application of an airborne hyper-spectral survey system CASI/SASI in the gold-silver-lead-zinc ore district of Huaniushan, Gansu, China

The airborne hyper-spectral survey system CASI/SASI, which has an integrated system for gathering both image an spectral data, is at the cutting edge developments in the remote-sensing field. It can be used to directly identify surface objects based on diagnostic spectral characteristics. In this paper, the CASI/SASI were used in the Huaniushan gold-silver-lead-zinc ore district–Gansu to produce a lithologic map, identify altered minerals, and map the mineralized-alteration zones. Radiometric correction, radiometric calibration, atmospheric correction (spectral reconstruction), and geometric corrections were carried out in ENVI to pre-process the measured data. A FieldSpec ® Pro FR portable spectrometer was used to obtain the spectral signatures of all types of rock samples, ore deposits, and mineralized-alteration zones. We extracted and analyzed the spectral characteristics of typical alteration minerals. On the basis of hyper-spectral data, ground-spectral data processing, and comparative analysis of the measured image spectrum, we used the spectral-angle-mapping (SAM) and mixture-tuned matchedfiltering (MTMF) methods to perform hyperspectral-alteration mineral mapping of wall rock and mineralized-alteration-zone hyperspectral identification. Hyperspectral- remote- sensing geological- classification maps were produced as well as distribution maps of all kinds of alteration minerals and mineralized-alteration zones. Based on geological comprehensive analysis and field investigations, the range of mineral alteration was proven to be the same as shown by the remote-sensing imagery. Indications are that airborne hyperspectral- remote-sensing -image CASI/SASI offer good application results and show a promising potential as a tool in geological investigations. The results will provide the basis for hyperspectral remote-sensing prospecting in the same or similar unexplored areas.