Surfactant assisted processing of carbon nanotube/polypropylene composites: Impact of surfactants on the matrix polymer

2010 ◽  
pp. n/a-n/a
Author(s):  
Julius Rausch ◽  
Rong-Chuan Zhuang ◽  
Edith Mäder
Keyword(s):  
Carbon Nanotube ◽  
Polypropylene Composites ◽  
Matrix Polymer ◽  
The Matrix ◽  
Surfactant Assisted

scholarly journals Tensile Properties of Polypropylene Filled with Nanoscale Calcium Carbonate Particles

2002 ◽  
Vol 11 (6) ◽  
pp. 096369350201100 ◽  
Author(s):  
Ming Qiu Zhang ◽  
Min Zhi Rong ◽  
Shun Long Pan ◽  
Klaus Friedrich
Keyword(s):  
Calcium Carbonate ◽  
Tensile Properties ◽  
Introduced Species ◽  
Tensile Testing ◽  
Filler Content ◽  
Polypropylene Composites ◽  
Matrix Polymer ◽  
Modification Effect ◽  
The Matrix ◽  
Positive Effect

To bring the positive effect of nanoscale calcium carbonate into play, macromolecular chains were introduced onto the particles by irradiation grafting polymerisation so that the hydrophobicity of the particles was increased and the loosen agglomerates became stronger. Tensile testing results demonstrated that polypropylene composites incorporated with the grafted nano-CaCO3 particles exhibited improved stiffness, strength and toughness at low filler content when proper grafting polymers are introduced. Species of grafting polymers adhered to the nanoparticles is an important factor affecting the modification effect of the matrix polymer. Therefore, composites performance can be purposely tailored accordingly.

scholarly journals Effect of Temperature on the Viscoelastic Properties of Carbon Nanotube Reinforced Polypropylene Composites

2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Jun Huang ◽  
Denis Rodrigue ◽  
Ling Dong
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Stress Distribution ◽  
Viscoelastic Properties ◽  
Volume Fraction ◽  
Axial Direction ◽  
Effect Of Temperature ◽  
Polypropylene Composites ◽  
The Matrix

Finite element method (FEM) is used to analyze the mechanical properties of carbon nanotubes (CNTs) reinforced polypropylene (PP) composites. Firstly, polypropylene is assumed as a viscoelastic material, while carbon nanotubes are assumed as linear elastic materials to study the effect of temperature on the mechanical properties of neat PP and CNT/PP nanocomposites. Secondly, to compare the viscoelastic properties of neat PP and CNT/PP nanocomposites, the relaxation time at a specific temperature is used to investigate the relaxation of the nanocomposites for fixed tensile displacements. Thirdly, the effect of CNT volume fraction on the viscoelastic properties of nanocomposites is studied at different temperatures. Finally, to better understand the stress distribution along the CNT axial direction, a single carbon nanotube is isolated in the matrix to compare the stress distribution with nonisolated CNTs.

scholarly journals Supramolecular ionic polymer/carbon nanotube composite hydrogels with enhanced electromechanical performance

2020 ◽  
Vol 9 (1) ◽  
pp. 478-488 ◽  
Author(s):  
Yun-Fei Zhang ◽  
Fei-Peng Du ◽  
Ling Chen ◽  
Ka-Wai Yeung ◽  
Yuqing Dong ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Ion Mobility ◽  
Artificial Muscles ◽  
Ionic Polymer ◽  
Composite Hydrogels ◽  
The Matrix ◽  
Electromechanical Performance ◽  
Carbon Nanotube Composite ◽  
Robotic Devices

AbstractElectroactive hydrogels have received increasing attention due to the possibility of being used in biomimetics, such as for soft robotics and artificial muscles. However, the applications are hindered by the poor mechanical properties and slow response time. To address these issues, in this study, supramolecular ionic polymer–carbon nanotube (SIPC) composite hydrogels were fabricated via in situ free radical polymerization. The polymer matrix consisted of carbon nanotubes (CNTs), styrene sulfonic sodium (SSNa), β-cyclodextrin (β-CD)-grafted acrylamide, and ferrocene (Fc)-grafted acrylamide, with the incorporation of SSNa serving as the ionic source. On applying an external voltage, the ions accumulate on one side of the matrix, leading to localized swelling and bending of the structure. Therefore, a controllable and reversible actuation can be achieved by changing the applied voltage. The tensile strength of the SIPC was improved by over 300%, from 12 to 49 kPa, due to the reinforcement effect of the CNTs and the supramolecular host–guest interactions between the β-CD and Fc moieties. The inclusion of CNTs not only improved the tensile properties but also enhanced the ion mobility, which lead to a faster electromechanical response. The presented electro-responsive composite hydrogel shows a high potential for the development of robotic devices and soft smart components for sensing and actuating applications.

Development of bamboo polymer composites with improved impact resistance

2021 ◽  
pp. 096739112110093
Author(s):  
RM Abhilash ◽  
GS Venkatesh ◽  
Shakti Singh Chauhan
Keyword(s):  
Impact Strength ◽  
Flexural Strength ◽  
Polymer Composites ◽  
Impact Resistance ◽  
Adverse Impact ◽  
Matrix Polymer ◽  
Bamboo Fibre ◽  
The Matrix ◽  
Major Criterion ◽  
Pp Composites

Reinforcing thermoplastic polymers with natural fibres tends to improve tensile and flexural strength but adversely affect elongation and impact strength. This limits the application of such composites where toughness is a major criterion. In the present work, bamboo fibre reinforced polypropylene (PP) composites were prepared with bamboo fibre content varying from 30% to 50% with improved impact resistance. Homopolymer and copolymer PP were used as the matrix polymer and an elastomer was used (10% by wt.) as an additive in the formulation. Copolymer based composites exhibited superior elongation and impact strength as compared to homopolymer based composites. The adverse impact of elastomer on tensile and flexural strength was more pronounced in homopolymer based composites. The study suggested that the properties of the bamboo composites can be tailored to suit different applications by varying reinforcement and elastomer percentage.

scholarly journals Fatigue Behaviour of Unidirectional Single-Walled Carbon Nanotube Reinforced Epoxy Composite under Tensile Load

2003 ◽  
Vol 12 (1) ◽  
pp. 096369350301200 ◽  
Author(s):  
Y. Ren ◽  
F. Li ◽  
H. M. Cheng ◽  
K. Liao
Keyword(s):  
Carbon Nanotube ◽  
Tensile Load ◽  
Fatigue Behaviour ◽  
Epoxy Composites ◽  
High Fracture Toughness ◽  
High Fracture ◽  
Single Walled Carbon Nanotube ◽  
Single Walled Carbon ◽  
Matrix Cracks ◽  
The Matrix

Tension-tension fatigue behaviour of unidirectional, aligned single-walled carbon nanotube (SWNT) rope reinforced epoxy composites were studied. While the slope of the stress-life (S-N) curve of the SWNTs in SWNT/epoxy composites obtained is flat, similar to those of carbon fibre reinforced epoxy composites, the fatigue strength of the former is at least twice that of the latter. Morphology of the fatigue fracture surface of SWNT reinforced epoxy involves matrix plastic deformation and SWNT-bridged matrix cracks. Evidence of good adhesion between SWNTs and epoxy was seen, and pullout length of SWNTs from the matrix is about 30 μm. Results suggest that carbon nanotubes can be used for fatigue resistant, high fracture toughness composites.

Multiscale Modeling of Dynamic Characteristics of Carbon Nanotube Reinforced Nanocomposites

NANO ◽  
2016 ◽  
Vol 11 (07) ◽  
pp. 1650083 ◽  
Author(s):  
Sachin O. Gajbhiye ◽  
S. P. Singh
Keyword(s):  
Carbon Nanotube ◽  
Dynamic Characteristics ◽  
Matrix Material ◽  
Three Dimensional ◽  
Vacancy Defect ◽  
Nanocomposite Material ◽  
Phase Lag ◽  
Rate Dependent ◽  
Carbon Carbon Bond ◽  
The Matrix

A unique atomic structure of carbon nanotube unveils outstanding properties. This makes it potentially highly valued reinforcing material to strengthen composite materials. The methodology is established in this research paper to investigate the static and dynamic characteristics of the nanocomposites. Repol polypropylene H110MA is used as a matrix material along with the different percentages of single-walled carbon nanotubes (SWCNTs). A concept of representative volume element (RVE) is considered to study the various properties of the nanocomposite material. The carbon–carbon bond of nanotube is modeled using Tersoff–Brenner potential and represented by space frame element. The matrix material properties are tested in the laboratory which are further used to model it and represented by three-dimensional continuum elements. The interaction between nanotube and polymer matrix is modeled using “Lennard–Jones 6-12” potential represented by nonlinear spring elements. The effect of reinforcement, chirality, % volume of SWCNT, atomic vacancy defect and Stone–Wales defect on the properties of nanocomposite are investigated. To see the effect of reinforcement, the eigenvalues of the RVE are extracted for different boundary conditions. The viscoplastic behavior of the matrix material is considered and the rate-dependent characteristics of the nanocomposite are studied. The damping property of the nanocomposite material is also investigated based on the phase lag between stress and strain field by applying harmonic strain at different frequencies.

Preparation of Polypropylene Composites with High Levels of Coir Short Fiber for Use in Products by Injection

2015 ◽  
Vol 668 ◽  
pp. 28-38 ◽  
Author(s):  
Claudio Roberto Passatore ◽  
Alcides Lopes Leão ◽  
Derval dos Santos Rosa
Keyword(s):  
Sessile Drop ◽  
Short Fiber ◽  
Polymeric Matrix ◽  
Coir Fiber ◽  
Polypropylene Composites ◽  
The Matrix ◽  
Hydrophilic Character ◽  
High Level ◽  
Thermal Stability Of ◽  
Vegetable Fiber

The main objective of this investigation was to study the properties of composites of polypropylene (PP) containing different proportions (20, 40 and 60% wt%) of coir short fiber (natural vegetable fiber) without treatment of fibers, for use in products by injection with applications in the automotive industries, construction and other segments. Samples were prepared in a only stage using a high intensity thermokinetic mixer (K-Mixer). Additives were used in the mass fraction of 3 wt% compatibilizer (PP-g-MA), 2.2 wt% processing additive and 0.12 wt% thermal antioxidant. The composites were characterized by tensile test according to ASTM D638-10. The surface properties of the polymeric matrix with additives were studied by determining the contact angle (CA) in a sessile drop tensiometer and the carbonyl index (CI) by Fourier-transform infrared spectroscopy (FTIR). Thermal properties of the PP and the composition were evaluated by thermogravimetric test, and the interface of the fiber and the matrix in the composites were evaluated using images from scanning electron microscopy (SEM). The CA analysis showed that the PP matrix with additives has become less hydrophobic and the FTIR and the CI that there was a better stabilization of the PP with additives. There was an increase in thermal stability of the composites for all fiber content, which was up to 15 °C above PP for coir fiber composites. In the Young's modulus values showed that the inclusion of fibers reinforced the polymeric matrix and increased the stiffness of the composites, especially in composites containing 60% (wt%) in which the values were ~1.7 times greater than the polypropylene. Images of micrographs showed the interaction of the fiber in the matrix and that despite the hydrophilic character of the fibers and hydrophobic character of the PP, the composites showed non-homogeneous interfaces. These findings confirm the feasibility of using high level of coir fiber in polypropylene composites even without pretreatment of the fibers and the preparation of samples by injection.

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