Saturated vapor and liquid densities of pure substances

1965 ◽  
Vol 43 (3) ◽  
pp. 137-142 ◽  
Author(s):  
Ronald G. Barile ◽  
George Thodos
Keyword(s):  
Saturated Vapor ◽  
Pure Substances

scholarly journals Description of the liquid-vapor phase equilibrium line of pure substances within the bounds of scale theory based on the Clapeyron equation

2021 ◽  
Vol 2057 (1) ◽  
pp. 012113
Author(s):  
S V Rykov ◽  
I V Kudryavtseva ◽  
V A Rykov ◽  
E E Ustyuzhanin
Keyword(s):  
Phase Equilibrium ◽  
Saturated Vapor ◽  
Average Diameter ◽  
Saturation Line ◽  
Equilibrium Line ◽  
Modern Theory ◽  
Clapeyron Equation ◽  
Scale Theory ◽  
Pure Substances ◽  
Phase Equilibrium Line

Abstract On the basis of the Clapeyron equation and the scale theory, expressions are developed for the “apparent” heat of vaporization r * = r * (T), vapor ρ- = ρ- (T) and liquid ρ+ = ρ+ (T) branches of the saturation line of individual substances for the range of state parameters from the triple point (pt,Tt,ρt ) to the critical (pc,Tc,ρc ). The peculiarity of the proposed approach to the description of the saturation line is that all exponents of the components of the equations ρ- = ρ- (T) and ρ+ = ρ+ (T) are universal up to the universality of the critical indices α, β and Δ. In this case, the order parameter ds = (ρ+ − ρ-)/(2ρc) and the average diameter df = (ρ+ + ρ-)/(2ρc) − 1 of the saturation line satisfy the saturation line model [2β,1−α], which follows from the modern theory of critical phenomena. The method is tested on the example of describing the phase equilibrium line of refrigerant R1233zd(E) in the range from Tt = 195.15 K to Tc = 439.57 K. It is found that in the temperature range [Tt,Tc ], the developed system of the mutually consistent equations ps = ps (T), r * = r * (T), ρ- = ρ- (T) and ρ+ = ρ+ (T) allows describing the data on the saturated vapor pressure ps and densities ρ- and ρ+ on the saturation line within the experimental uncertainty of these data.

Scanning electron microscopy of plant cells using a variable-pressure SEM and cryogenic techniques

1993 ◽  
Vol 51 ◽  
pp. 260-261
Author(s):  
M. Yamada ◽  
K. Ueda ◽  
K. Kuboki ◽  
H. Matsushima ◽  
S. Joens
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Saturated Vapor ◽  
Plant Cells ◽  
Variable Pressure ◽  
Specimen Preparation ◽  
Operating Pressure ◽  
Vapor Pressures ◽  
Low Temperature Microscopy ◽  
Scanning Electron

Use of variable Pressure SEMs is spreading among electron microscopists The variable Pressure SEM does not necessarily require specimen Preparation such as fixation, dehydration, coating, etc which have been required for conventional scanning electron microscopy. The variable Pressure SEM allows operating Pressure of 1˜270 Pa in specimen chamber It does not allow microscopy of water-containing specimens under a saturated vapor Pressure of water. Therefore, it may cause shrink or deformation of water-containing soft specimens such as plant cells due to evaporation of water. A solution to this Problem is to lower the specimen temperature and maintain saturated vapor Pressures of water at low as shown in Fig. 1 On this technique, there is a Published report of experiment to have sufficient signal to noise ratio for scondary electron imaging at a relatively long working distance using an environmental SEM. We report here a new low temperature microscopy of soft Plant cells using a variable Pressure SEM (Hitachi S-225ON).

Calculation of Equilibrium Constant for Dimerization of Heavy Water Molecules in Saturated Vapor

2015 ◽  
Vol 60 (3) ◽  
pp. 263-267
Author(s):  
L.A. Bulavin ◽  
◽  
S.V. Khrapatyi ◽  
V.M. Makhlaichuk ◽  
Keyword(s):  
Equilibrium Constant ◽  
Heavy Water ◽  
Saturated Vapor ◽  
Water Molecules

scholarly journals Density Measurements of an Air-Like Binary Mixture over the Temperature Range from 100 K to 298.15 K at Pressures up to 8.0 MPa

2021 ◽  
Vol 42 (9) ◽  
Author(s):  
Nils von Preetzmann ◽  
Reiner Kleinrahm ◽  
Philipp Eckmann ◽  
Giuseppe Cavuoto ◽  
Markus Richter
Keyword(s):  
Binary Mixture ◽  
Saturated Vapor ◽  
Saturation Pressure ◽  
Transmission Error ◽  
Magnetic Suspension ◽  
Mixture Component ◽  
Liquid Region ◽  
Force Transmission ◽  
Temperature Range ◽  
Combined Uncertainty

AbstractDensities of an air-like binary mixture (0.2094 oxygen + 0.7906 nitrogen, mole fractions) were measured along six isotherms over the temperature range from 100 K to 298.15 K at pressures up to 8.0 MPa, using a low-temperature single-sinker magnetic suspension densimeter. The measurements were carried out at T = (100, 115, and 130) K in the homogeneous gas and liquid region, and at T = (145, 220, and 298.15) K in the supercritical region (critical temperature TC = 132.35 K); in total, we present results for 52 (T, p) state points. The relative expanded combined uncertainty (k = 2) of the experimental densities was estimated to be between 0.03 % and 0.13 %, except for four values near the critical point. The largest error is caused by the magnetic suspension coupling in combination with the mixture component oxygen, which is strongly paramagnetic; the resulting force transmission error is up to 1.1 %. However, this error can be corrected with a proven correction model to an uncertainty contribution in density of less than 0.044 %. Due to a supercritical liquefaction procedure and the integration of a special VLE-cell, it was possible to measure densities in the homogeneous liquid phase without changing the composition of the liquefied mixture. Moreover, saturated liquid and saturated vapor densities were determined at T = (100, 115, and 130) K by extrapolation of the experimental single-phase densities to the saturation pressure. The new experimental results were compared with the mixture model of Lemmon et al. for the system (nitrogen + argon + oxygen) and the GERG-2008 equation of state.

Influence of Na-Al-Fe-P glass alteration in hot non-saturated vapor on leaching of vitrified radioactive wastes in water

2018 ◽  
Vol 508 ◽  
pp. 212-218 ◽  
Author(s):  
Victor I. Malkovsky ◽  
Sergey V. Yudintsev ◽  
Elizaveta V. Aleksandrova
Keyword(s):  
Saturated Vapor ◽  
Radioactive Wastes

scholarly journals Using CO2 as a Cooling Fluid for Power Plants: A Novel Approach for CO2 Storage and Utilization

2021 ◽  
Vol 11 (11) ◽  
pp. 4974
Author(s):  
Tran X. Phuoc ◽  
Mehrdad Massoudi
Keyword(s):  
Power Plant ◽  
Power Plants ◽  
Saturated Vapor ◽  
Co2 Storage ◽  
Storage Container ◽  
Cooling Fluid ◽  
Capital Costs ◽  
Dry Air ◽  
Novel Approach ◽  
Power Plant Cooling

To our knowledge, the potential use of CO2 as a heat-transmitting fluid for cooling applications in power plants has not been explored very extensively. In this paper, we conduct a theoretical analysis to explore the use of CO2 as the heat transmission fluid. We evaluate and compare the thermophysical properties of both dry air and CO2 and perform a simple analysis on a steam-condensing device where steam flows through one of the flow paths and the cooling fluid (CO2 or air) is expanded from a high-pressure container and flows through the other. Sample calculations are carried out for a saturated-vapor steam at 0.008 MPa and 41.5 °C with the mass flow rate of 0.01 kg/s. The pressure of the storage container ranges from 1 to 5 MPa, and its temperature is kept at 35 °C. The pressure of the cooling fluid (CO2 or dry air) is set at 0.1 MPa. With air as the heat-removing fluid, the steam exits the condensing device as a vapor-liquid steam of 53% to 10% vapor for the container pressure of 1 to 5 MPa. With CO2 as the heat-removing fluid, the steam exits the device still containing 44% and 7% vapor for the container pressure of 1 MPa and 2 MPa, respectively. For the container pressure of 3 MPa and higher, the steam exits the device as a single-phase saturated liquid. Thus, due to its excellent Joule–Thomson cooling effect and heat capacity, CO2 is a better fluid for power plant cooling applications. The condensing surface area is also estimated, and the results show that when CO2 is used, the condensing surface is 50% to 60% less than that when dry air is used. This leads to significant reductions in the condenser size and the capital costs. A rough estimate of the amount of CO2 that can be stored and utilized is also carried out for a steam power plant which operates with steam with a temperature of 540 °C (813 K) and a pressure of 10 MPa at the turbine inlet and saturated-vapor steam at 0.008 MPa at the turbine outlet. The results indicate that if CO2 is used as a cooling fluid, CO2 emitted from a 1000 MW power plant during a period of 250 days could be stored and utilized.

scholarly journals Light Output, Thermal Properties, and Reliability of Using Glass Phosphors in WLED Packages

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 239
Author(s):  
Chin-Chuan Huang ◽  
Tsung-Han Weng ◽  
Chun-Liang Lin ◽  
Yan-Kuin Su
Keyword(s):  
Thermal Properties ◽  
Yttrium Aluminum Garnet ◽  
Saturated Vapor ◽  
Light Output ◽  
Junction Temperature ◽  
Color Temperature ◽  
Light Emitting ◽  
Chromaticity Coordinate ◽  
White Light Emitting Diodes ◽  
Color Rendering

White-light-emitting diodes (WLED) based on yttrium aluminum garnet (YAG) phosphors sintered with glass (PiG) and with silicone (PiS) are compared in terms of their light properties, temperature properties and reliability.The complete YAG phosphor was doped with an encapsulant traditional WLED (PiS WLED), and the WLED was covered with PiG (PiG WLED). PiG was made by sintering glass powder and YAG phosphor at the ratio of 87:13 (%), and the correlated color temperature (CCT) was 5564 K. The CCT of the PiG WLED with the YAG doping concentration of 8.5 wt.% approximated 5649 K. The initial light output of the PiG WLED was 6.4% lower than that of the PiS WLED. Under 1008 h and 350 mA aging, PiG WLED and PiS WLED’ light output, CCT and color rendering index variation rates were all within 1%. In the saturated vapor-pressure test, no sample exhibited red ink infiltration, light nor peeling between the encapsulant and the lead-frame. Compared with that of the PiS WLED, the junction temperature of the PiG WLED reduced from 88.4 °C to 81.3 °C. Thermal resistance dropped from 37.4 °C/W to 35.6 °C/W. The PiG WLED presented a better CIE (Commission Internationale de l’Eclairage) 1931 chromaticity coordinate (x,y) concentration and thermal properties than the PiS WLED.

scholarly journals Study on a Quaternary Working Pair of CaCl2-LiNO3-KNO3/H2O for an Absorption Refrigeration Cycle

Entropy ◽  
2019 ◽  
Vol 21 (6) ◽  
pp. 546 ◽  
Author(s):  
Yiqun Li ◽  
Na Li ◽  
Chunhuan Luo ◽  
Qingquan Su
Keyword(s):  
Heat Capacity ◽  
Crystallization Temperature ◽  
Saturated Vapor Pressure ◽  
Saturated Vapor ◽  
Specific Enthalpy ◽  
Refrigeration Cycle ◽  
Absorption Refrigeration ◽  
Evaporation Temperature ◽  
Corrosion Rates ◽  
Specific Entropy

When compared with LiBr/H2O, an absorption refrigeration cycle using CaCl2/H2O as the working pair needs a lower driving heat source temperature, that is, CaCl2/H2O has a better refrigeration characteristic. However, the crystallization temperature of CaCl2/H2O solution is too high and its absorption ability is not high enough to achieve an evaporation temperature of 5 °C or lower. CaCl2-LiNO3-KNO3(15.5:5:1)/H2O was proposed and its crystallization temperature, saturated vapor pressure, density, viscosity, specific heat capacity, specific entropy, and specific enthalpy were measured to retain the refrigeration characteristic of CaCl2/H2O and solve its problems. Under the same conditions, the generation temperature for an absorption refrigeration cycle with CaCl2-LiNO3-KNO3(15.5:5:1)/H2O was 7.0 °C lower than that with LiBr/H2O. Moreover, the cycle’s COP and exergy efficiency with CaCl2-LiNO3-KNO3(15.5:5:1)/H2O were approximately 0.04 and 0.06 higher than those with LiBr/H2O, respectively. The corrosion rates of carbon steel and copper for the proposed working pair were 14.31 μm∙y−1 and 2.04 μm∙y−1 at 80 °C and pH 9.7, respectively, which were low enough for engineering applications.

scholarly journals Effects of nanoparticles on hydraulic cavitation

2018 ◽  
Vol 240 ◽  
pp. 03004
Author(s):  
Min-rui Chen ◽  
Jin-yuan Qian ◽  
Zan Wu ◽  
Chen Yang ◽  
Zhi-jiang Jin ◽  
...  
Keyword(s):  
Vapor Pressure ◽  
Saturated Vapor Pressure ◽  
Saturated Vapor ◽  
Geometric Model ◽  
Pressure Ratio ◽  
Perforated Plate ◽  
Significant Parameter ◽  
Operation Conditions ◽  
Small Bubbles ◽  
Crucial Condition

When liquids flowing through a throttling element, such as a perforated plate, the velocity increases and the pressure decreases. If the pressure is below the saturated vapor pressure, the liquid will vaporize into small bubbles, which is called hydraulic cavitation. In fact, vaporization nucleus is another crucial condition for vaporizing. The nanoparticles contained in the nanofluids play a significant role in vaporization of liquids. In this paper, the effects of the nanoparticles on hydraulic cavitation are investigated. Firstly, a geometric model of a pipe channel equipped with a perforated plate is established. Then with different nanoparticle volume fractions and diameters, the nanofluids flowing through the channel is numerically simulated based on a validated numerical method. The operation conditions, such as the temperature and the pressure ratio of inlet to outlet, are the considered variables. As a significant parameter, cavitation numbers under different operation conditions are achieved to investigate the effects of nanoparticles on hydraulic cavitation. Meanwhile, the contours are extracted to research the distribution of bubbles for further investigation. This study is of interests for researchers working on hydraulic cavitation or nanofluids.

Correlation of Melting Results for Both Pure Substances and Impure Substances

1986 ◽  
Vol 108 (3) ◽  
pp. 649-653 ◽  
Author(s):  
E. M. Sparrow ◽  
G. A. Gurtcheff ◽  
T. A. Myrum
Keyword(s):  
Solid Phase ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram ◽  
Vertical Tube ◽  
Step Change ◽  
Pure Substance ◽  
Characteristic Temperatures ◽  
Pure Substances ◽  
T Values ◽  
Melting Experiments

Melting experiments were performed encompassing both pure and impure substances. The pure substances included n-octadecane paraffin and n-eicosane paraffin, while the impure substances were mixtures synthesized from the pure paraffins. The experiments were carried out in a closed vertical tube whose wall was subjected to a step-change increase in temperature to initiate the melting. For each impure substance, supplementary measurements were made of two characteristic temperatures: the temperature T** at which melting of the solid phase first begins and the lowest temperature T* at which the melting can go to completion. For a pure substance, T** = T*. The time-dependent melting results for all the investigated substances, both pure and impure, were well correlated as a function of FoSte**(Gr**)1/8 alone, where the ** signifies the presence of T** in the temperature difference which appears in Ste and Gr. This correlation enables melting rates for impure substances to be determined from melting rates for pure substances. The T** values needed for the implementation of the correlation can be obtained from simple experiments, obviating the need for the complete equilibrium phase diagram.

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