Cure behavior and kinetic study of diglycidyl ether of bisphenol A with a tertiary amine salt by differential scanning calorimetry

2017 ◽  
Vol 58 (5) ◽  
pp. 784-792 ◽  
Author(s):  
Alejandra Ortiz Vélez ◽  
Samuel Siles Alvarado ◽  
Juan Ramón Avendaño-Gómez
Keyword(s):  
Differential Scanning Calorimetry ◽  
Bisphenol A ◽  
Kinetic Study ◽  
Tertiary Amine ◽  
Diglycidyl Ether ◽  
Amine Salt ◽  
Scanning Calorimetry ◽  
Cure Behavior

scholarly journals Novel Bio-Based Epoxy Thermosets Based on Triglycidyl Phloroglucinol Prepared by Thiol-Epoxy Reaction

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 337 ◽  
Author(s):  
Dailyn Guzmán ◽  
David Santiago ◽  
Àngels Serra ◽  
Francesc Ferrando
Keyword(s):  
Mechanical Properties ◽  
Thermal Analysis ◽  
Differential Scanning Calorimetry ◽  
Thermogravimetric Analysis ◽  
Bisphenol A ◽  
Diglycidyl Ether ◽  
Scanning Calorimetry ◽  
High Transparency ◽  
Epoxy Curing ◽  
Curing Agents

The pure trifunctional glycidyl monomer from phloroglucinol (3EPO-Ph) was synthesized and used as feedstock in the preparation of novel bio-based thermosets by thiol-epoxy curing. The monomer was crosslinked with different commercially available thiols: tetrafunctional thiol (PETMP), trifunctional thiol (TTMP) and an aromatic dithiol (TBBT) as curing agents in the presence of a base. As catalyst, two different commercial catalysts: LC-80 and 4-(N,N-dimethylamino) pyridine (DMAP) and a synthetic catalyst, imidazolium tetraphenylborate (base generator, BG) were employed. The curing of the reactive mixtures was studied by using DSC and the obtained materials by means of differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and dynamic mechanical thermal analysis (DMTA). The results revealed that only the formulations catalyzed by BG showed a latent character. Already prepared thermosetting materials showed excellent thermal, thermomechanical and mechanical properties, with a high transparency. In addition to that, when compared with the diglycidyl ether of bisphenol A (DGEBA)/PETMP material, the thermosets prepared from the triglycidyl derivative of phloroglucinol have better final characteristics and therefore this derivative can be considered as a partial or total renewable substitute of DGEBA in technological applications.

scholarly journals Effects of Different Montmorillonite Nanoclay Loading on Cure Behavior and Properties of Diglycidyl Ether of Bisphenol A Epoxy

2016 ◽  
Vol 2016 ◽  
pp. 1-12 ◽  
Author(s):  
Alfred Tcherbi-Narteh ◽  
Mahesh Hosur ◽  
Shaik Jeelani
Keyword(s):  
Reaction Mechanism ◽  
Bisphenol A ◽  
Reaction Rate Constant ◽  
Diglycidyl Ether ◽  
Scanning Calorimetry ◽  
Cure Reaction ◽  
Cure Behavior ◽  
Lower Shear ◽  
Primary Focus ◽  
Montmorillonite Nanoclay

The primary focus of this study was to understand the effects of different amounts of montmorillonite nanoclay (MMT) loading on viscosity, cure behavior, reaction mechanism, and properties of diglycidyl ether of bisphenol A (DGEBA) epoxy composites. Influence of 1–3 wt.% MMT on rheological and subsequent cure behavior of SC-15 epoxy resin was studied using nonisothermal and isothermal rheometry and differential scanning calorimetry (DSC). Rheological properties were influenced by different amounts of MMT at lower shear rates prior to and during curing. Cure reaction mechanism was unaffected by different MMT concentration; however heat and activation energy of reactions increased with increasing MMT loading. Samples with 2 wt.% MMT showed highest reaction rate constant, indicative of catalytic behavior. X-ray diffraction (XRD) and transmission electron microscope (TEM) revealed mainly intercalated microstructure throughout the MMT infused epoxy composite samples irrespective of the percent loading.

Curing Behavior of Epoxy Resin Mixed with Epoxypropoxypropyl Terminated Polydimethylsiloxane

2013 ◽  
Vol 677 ◽  
pp. 197-200
Author(s):  
Zheng Xi ◽  
Jin Dian Ding ◽  
Wen Jun Gan ◽  
Zhao Zhang
Keyword(s):  
Differential Scanning Calorimetry ◽  
Bisphenol A ◽  
Microphase Separation ◽  
Curing Kinetics ◽  
Diglycidyl Ether ◽  
Separation Mechanism ◽  
Scanning Calorimetry ◽  
Modified Epoxy ◽  
Epoxy Systems ◽  
Electronic Microscope

Diglycidyl ether of bisphenol A (DGEBA) and epoxypropoxypropyl terminated polydimethylsiloxane (ETDMS) were mixed in different proportion. The morphology of ETDMS modified epoxy systems was observed by scanning electronic microscope (SEM). Curing kinetics was also studied by differential scanning calorimetry (DSC). It was suggested that the formation of the microstructures followed reaction-induced microphase separation mechanism.

Study of the Cure of a Diglycidyl-Ether of Bisphenol-a (DGEBA) / Triethylenetetramine (TETA) Epoxy System by Non-Isothermal Differential Scanning Calorimetry (DSC)

2006 ◽  
Vol 514-516 ◽  
pp. 1094-1098
Author(s):  
Rosa Losada ◽  
José Luís Mier ◽  
Fernando Barbadillo ◽  
Ramón Artiaga ◽  
Angel Varela ◽  
...  
Keyword(s):  
Activation Energy ◽  
Differential Scanning Calorimetry ◽  
Bisphenol A ◽  
Inert Atmosphere ◽  
Diglycidyl Ether ◽  
Exothermic Peak ◽  
Heating Rates ◽  
Scanning Calorimetry ◽  
Reaction Heat ◽  
Marine Coatings

A diglycidyl-ether of bisphenol-A (DGEBA)/Triethylenetetramine (TETA) system was studied by non-isothermal differential scanning calorimetry (DSC) to establish its kinetics of cure. The DGEBA resin was Araldite GZ 601 X75 used in the marine coatings formulations. Previously, the optimum resin/hardener ratio was determined by the reaction heat measuring (.Hc) calculated from the curing exothermic peak. Tests at different heating rates (10, 15, 20, 25 and 30°C/min) under inert atmosphere were carried out in order to study the reaction kinetics. The activation energy of the cure (Ea) was obtained from these tests data by Borchardt-Daniels, autocatalytic, Duswalt and isoconversional Ozawa methods. Once the activation energy was determined, the master curves method was applied to find the kinetic model which best describes the measured DSC data. The Sestak-Berggren model SB (m,n) was found to be the most adequate for the system studied.

scholarly journals Preparation and Characterization of Green Epoxy Resin Composites and Its Use in Corrosion Resistance

2018 ◽  
Author(s):  
Abbas Hassan Faris
Keyword(s):  
Bisphenol A ◽  
Epoxy Resin ◽  
Electrolyte Solutions ◽  
Kraft Lignin ◽  
Diglycidyl Ether ◽  
Kraft Pulping ◽  
Palm Tree ◽  
Scanning Calorimetry ◽  
Ft Ir ◽  
Nano Titanium Dioxide

In this work, appropriate alternative for diglycidyl ether bisphenol A (DGEBA) was found to avoid the destructive effects of bisphenol A. Lignin, an aromatic compound from palm tree leaves, was used as a renewable material to synthesize a bio-based epoxy resin. Lignin extracted using Kraft pulping process. Kraft Lignin was epoxidized with epichlorohydrin in alkaline medium. Nano-titanium dioxide was used as filler with ratio of 10% to prepare the green epoxy composite. The structure of the Kraft lignin and lignin-based epoxy resin was proven via Infrared spectra (FT-IR) were recorded using solid KBr disk by testing Shimadzu (FT-IR-8300) spectrophotometer. The thermal properties of the curing process of lignin-based epoxy resin and composite were investigate using Differential scanning calorimetry (DSC) analysis. Potentiodynamic measurements data revealed that the anti-corrosion performance of the lignin based epoxy resin. The study demonstrates successful of epoxidation of Kraft lignin. In addition, lignin based eopxy resin showed effective inhibitor for carbon steel in 3.5 wt. % NaCl electrolyte solutions

Azomethine ether-based potential curing agent for epoxy resin (diglycidyl ether of bisphenol A): Synthesis and characterization

2020 ◽  
pp. 009524432092857
Author(s):  
Fozia Noreen ◽  
Ahtaram Bibi ◽  
Naila Khalid ◽  
Imran Ullah Khan
Keyword(s):  
Spectral Analysis ◽  
Bisphenol A ◽  
Light Emission ◽  
Condensation Reaction ◽  
Stokes Shift ◽  
Green Light ◽  
Diglycidyl Ether ◽  
Proton Nuclear Magnetic Resonance ◽  
Curing Agent ◽  
Scanning Calorimetry

Novel azomethine ether-based compounds (A: N-((4-(9-(4-(phenylimino)methyl)phenoxy)nonyloxy)benzylidene)bezenamine and B: N-((4-(9-(4-(p-hydroxyphenylimino)methyl)phenoxy)nonyloxy)benzylidene)-4-hydroxybenzenamine) were synthesized by condensation reaction of dialdehyde, 4,4-(1,9-nonandiyle)bis(oxy)dibenzaldehyde with aromatic amines. Structures of synthesized compounds were successfully characterized by Fourier transform infrared (FTIR), ultraviolet–visible, proton nuclear magnetic resonance imaging and photoluminescence (PL) spectroscopy. The PL spectral analysis revealed that emission maxima of compounds A and B are at 475 and 500 nm, respectively, indicate blue and green light emission with large Stokes shift range (Δ λ ST, 109–138 nm). Two series of polymers: one azomethine-based polymers (C1–C5) and other without azomethine (H1–H4) were prepared by curing diglycidyl ether of bisphenol A with a synthesized curing agent (B) and commercial curing agent, respectively, in various proportions. The structural characterization of the resulting polymers was carried out by FTIR spectral analysis. Thermal properties revealed that azomethine-based polymers (C1–C5) were thermally stable up to 400°C as compared to H1–H4. The glass transition temperature of the polymers, determined by differential scanning calorimetry, was in the range 121–123°C.

Chemical Exchange Reactions in Blends of the Biodegradable Polyester with poly(hydroxy ether of bisphenol-A)

2014 ◽  
Vol 953-954 ◽  
pp. 1246-1249 ◽  
Author(s):  
Chean Cheng Su ◽  
Chern Hwa Chen ◽  
Neng Lang Shih ◽  
Yin Shuo Li
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Differential Scanning Calorimetry ◽  
Bisphenol A ◽  
Chemical Exchange ◽  
Exchange Reactions ◽  
Scanning Calorimetry ◽  
Butylene Succinate ◽  
Butylene Terephthalate ◽  
Before And After ◽  
Hydroxy Ether

Compatibilization via transreactions in blends of poly (butylene succinate-co-butylene terephthalate) [P(BS-co-BT)] with poly (hydroxy ether of bisphenol-A) (phenoxy) were investigated. Analyses were based on characterization using differential scanning calorimetry (DSC) and solid-state nuclear magnetic resonance (NMR). They revealed that the P(BS-co-BT)/phenoxy blend had a phase morphology that could be homogenized only following annealing at high temperatures. As-blended P(BS-co-BT)/phenoxy (50/50 composition) exhibited immiscible phases with two distinct Tgs, but the initially phase separated blends finally merged to form a homogeneous phase with a single Tgupon heating and annealing for 60 min at 280 °C. Chemical exchange reactions upon heat-annealing were likely to have caused the phase homogenization in the P(BS-co-BT)/phenoxy blend. NMR was performed on blend samples before and after they were heated to 280 °C, but the similarity of bonds made obtaining straight results difficult. Results of this study demonstrate phase homogenization can be brought only upon heat-annealing in the P(BS-co-BT)/phenoxy blend.

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