Changes in Dioxin Isomer Group Ratios in the Environment: An Update and Extension of the Present Theory

Author(s):  
D. I. Townsend
Keyword(s):  

The system of bands in the visible region of the emission spectrum of magnesium hydride is now well known. The bands with heads at λλ 5622, 5211, 4845 were first measured by Prof. A. Fowler, who arranged many of the strongest lines in empirical series for identification with absorption lines in the spectra of sun-spots. Later, Heurlinger rearranged these series in the now familiar form of P, Q and R branches, and considered them, with the OH group, as typical of doublet systems in his classification of the fine structure of bands. More recently, W. W. Watson and P. Rudnick have remeasured these bands, using the second order of a 21-foot concave grating, and have carried out a further investigation of the fine structure in the light of the present theory of band spectra. Their detection of an isotope effect of the right order of magnitude, considered with the general structure of the system, and the experimental work on the production of the spectrum, seems conclusive in assigning these bands to the diatomic molecule MgH. The ultra-violet spectrum of magnesium hydride is not so well known. The band at λ 2430 and the series of double lines in the region λ 2940 to λ 3100, which were recorded by Prof. Fowler in 1909 as accompanying the group of bands in the visible region, appear to have undergone no further investigation. In view of the important part played by hydride band spectra in the correlation of molecular and atomic electronic energy levels, it was thought that a study of these features might prove of interest in yielding further information on the energy states of the MgH molecule. The present paper deals with observations on the band at λ 2430; details of an investigation of the other features of the ultra-violet spectrum will be given in a later communication.


1971 ◽  
Vol 44 (1) ◽  
pp. 152-165 ◽  
Author(s):  
A. E. Oberth

Abstract The effect of loose chain ends on tensile properties and equilibrium swelling of crosslinked polyurethane rubbers is studied. As in plasticized elastomers, tensile strength and elastic modulus are reduced approximately by a factor (1−νE,P)2, where νE,P is the volume fraction of loose chain ends, plasticizer, or both. This effect is much larger than predicted by present theory. Also the equilibrium volume swelling ratio, V0/V, of rubbers having terminal chains or an equal volume of plasticizer is the same, provided they do not differ in crosslink density. However, the volume fraction of “network rubber” in the equilibrium swollen specimen, ν2, differs owing to the non-extractability of terminal chains. On this basis a method is proposed which allows experimental determination of the volume fraction of loose ends. Elastomers abounding in loose chain ends show markedly less long term stress relaxation. This effect is not clearly understood but is useful to detect the presence of non load-bearing network.


2019 ◽  
Vol 14 ◽  
pp. 155892501989564
Author(s):  
Ling Lin ◽  
Shao-Wen Yao

This article studies the ion release from an unsmooth inner surface of a hollow fiber. A fractal diffusion model is established using the fractal derivative, and the effect of the fractal dimension on the ion release is elucidated. The present theory provides a theoretical basis for the optimization of a hollow fiber contained silver ions for practical applications.


Author(s):  
Chen Sheng ◽  
Zhang Jian ◽  
Xiaodong Yu

This present study deals with a new mechanical device consisting of a set of safety membranes, which has been successfully applied in several middle and small hydropower stations in China instead of a surge tank. Safety membranes are installed on the penstock near the powerhouse as controlled weak points. When the pressure caused by load rejection rises to the preset explosive value, one or more membranes rupture, protecting the penstock and the unit from damage. The device is simple, reliable and economical. The method of characteristics is employed to establish numerical model of safety membranes to simulate their rupture behavior, which is then introduced to investigate how to determine the number and diameter of membranes from two aspects, large fluctuation and hydraulic disturbance. The results show that the diameter of the membranes depends on the negative pressure along pipeline under hydraulic disturbance while the number of the membrane depends on the maximum water hammer pressure under large fluctuation during load rejection of the unit. The conclusion of membrane selection can perfect the present theory of safety membranes, and provide the theoretical guidance and practical basis for membrane device design and safety operation.


2017 ◽  
Vol 6 (11) ◽  
pp. 83-106
Author(s):  
Diego Sandoval Sandoval ◽  
Georg Unger Vergara

El artículo problematiza los alcances del reconocimiento -y el menosprecio- en el análisis del conflicto socioambiental por vertederos públicos en la Araucanía, Chile. Aun cuando no se aprecian rasgos que permitan plantear el presente teórico del Reconocimiento como una teoría del conflicto, se percibe en la noción una herramienta valiosa para su crítica. Lo central del análisis estaría dado en el cómo se estructuran psicosocialmente las posturas de los individuos afectados por esta forma de injusticia. The article address the concept of recognition -and the concept of neglect- in the analysis of the socioenvironmental conflict related to public landfills in Araucanía, Chile. Even though we do not identify traits that allow us to understand the present theory of Recognition as a theory of conflict, we still see in the notion of recognition a valuable tool for understanding social conflicts. The central analysis would be focused on the psychosocial structuration of the position of those affected by this form of injustice.


1973 ◽  
Vol 17 (02) ◽  
pp. 61-71
Author(s):  
H. S. Chen ◽  
C. C. Mei

Exciting forces and moments due to plane incident waves on a stationary platform are studied in this paper. The platform is a vertical cylinder with a finite draft and elliptical cross section. The mathematical solution to the diffraction problem is obtained on the basis of the linearized long wave approximation. Numerical results via Mathieu functions are presented for a shiplike body with beam-to-length ratio Various draft-to-depth ratios and angles of incidence are considered. Results have been checked with the limiting case of a circular cylinder for the long-wave length range. Aside from its own practical interest, the present theory provides a basis for comparison with other approximate theories of slender-body type and serves as a prelude to the corresponding calculations for arbitrary wavelengths.


1961 ◽  
Vol 3 (30) ◽  
pp. 1133-1151 ◽  
Author(s):  
R. Haefeli

AbstractStarting from Glen’s flow law for ice and from a series of assumptions based in part on observations in Greenland and in the Jungfraujoch, the velocity distribution (horizontal velocity component) and surface configuration is derived for a strip-shaped ice sheet in a stationary state. For the choice n = 3 − 4 of the exponent in the power-law flow relation, there is extensive agreement between the theoretically calculated surface profile and the east-west profile measured through “Station Centrale” by Expéditions Polaires Françaises. The corresponding theoretical solution for a circular ice sheet is also given. As a first application of this theory, an attempt is made to calculate the average rate of accumulation in Antarctica from its surface profile (assumed circular in plan) and from the flow-law parameters derived from the Greenland Ice Sheet. It is also shown that a change in accumulation has only a small influence on the total ice thickness of an ice sheet. A method of calculating approximately the age of ice in an ice sheet, based on the foregoing theory, is illustrated by applying it to the Greenland Ice Sheet. After comparing the present theory with that of Nye, a general expression for the surface profile of an ice sheet with constant accumulation is set up and discussed by means of comparison with two profiles through Antarctica.


Author(s):  
Epifanio G. Virga

For nearly two centuries, the dynamics of chains have offered examples of paradoxical theoretical predictions. Here, we propose a theory for the dissipative dynamics of one-dimensional continua with singularities which provides a unified treatment for chain problems that have suffered from paradoxical solutions. These problems are duly solved within the present theory and their paradoxes removed—we hope.


This paper considers the two-dimensional flow past a circular cylinder immersed in a uniform stream, when the cylinder rotates about its axis so fast that separation in suppressed. The solution of the flow in the boundary layer on the cylinder is obtained in the form of a power series in the ratio of the stream velocity to the cylinder's peripheral velocity, and expressions are deduced for the value of the circulation and the torque on the cylinder. The terms calculated explicitly are sufficient to give reliable numerical values over the whole range of rotational speeds for which the postulate of non-separating flow is justifiable. The previously accepted theory, due to Prandtl, predicted that the circulation should not exceed a certain limit, while the present theory indicates that the circulation increases indefinitely with increase of rotaional speed. Strong arguments against the older theory are put forward, but the experimental evidence available is inconclusive.


1998 ◽  
Vol 120 (2) ◽  
pp. 385-389 ◽  
Author(s):  
Abhijit Guha

This paper presents a simple, analytical theory for determining total pressure in multiphase flows, a subject of theoretical interest as well as of practical importance. It is shown here that the nonequilibrium processes occurring in the vicinity of a measuring device have a significant influence on the magnitude of flow velocity inferred from Pitot measurements. The present theory predicts that, depending on the size of the particles or droplets, the total pressure varies monotonically between the two limiting values: the frozen total pressure (when there is no interphase mass, momentum, and energy transfer in the decelerating flow toward the stagnation point) and the equilibrium total pressure (when the dispersed phase, either liquid droplets, or solid particles, is always at inertial and thermodynamic equilibrium with the continuous vapour phase). The presented analytical theory is a relation between nondimensional total pressure and Stokes number, representing particle size or inertia, and specifies the total pressure under different nonequilibrium conditions. One simple equation applies to diverse multiphase mixtures, solid particle laden gas as well as vapour-droplet mixtures, and at a wide range of flow conditions, both subsonic and supersonic. The associated issue of interpreting total temperature, and the relation between measured total pressure and entropy production in multiphase flows have been discussed at length by Guha (1998).


Sign in / Sign up

Export Citation Format

Share Document