A Simple Analytical Theory for Interpreting Measured Total Pressure in Multiphase Flows

1998 ◽  
Vol 120 (2) ◽  
pp. 385-389 ◽  
Author(s):  
Abhijit Guha
Keyword(s):  
Total Pressure ◽  
Multiphase Flows ◽  
Practical Importance ◽  
Present Theory ◽  
Vapour Phase ◽  
Solid Particles ◽  
Analytical Theory ◽  
Nonequilibrium Processes ◽  
Measuring Device ◽  
Wide Range

This paper presents a simple, analytical theory for determining total pressure in multiphase flows, a subject of theoretical interest as well as of practical importance. It is shown here that the nonequilibrium processes occurring in the vicinity of a measuring device have a significant influence on the magnitude of flow velocity inferred from Pitot measurements. The present theory predicts that, depending on the size of the particles or droplets, the total pressure varies monotonically between the two limiting values: the frozen total pressure (when there is no interphase mass, momentum, and energy transfer in the decelerating flow toward the stagnation point) and the equilibrium total pressure (when the dispersed phase, either liquid droplets, or solid particles, is always at inertial and thermodynamic equilibrium with the continuous vapour phase). The presented analytical theory is a relation between nondimensional total pressure and Stokes number, representing particle size or inertia, and specifies the total pressure under different nonequilibrium conditions. One simple equation applies to diverse multiphase mixtures, solid particle laden gas as well as vapour-droplet mixtures, and at a wide range of flow conditions, both subsonic and supersonic. The associated issue of interpreting total temperature, and the relation between measured total pressure and entropy production in multiphase flows have been discussed at length by Guha (1998).

Substituent Effects on the Thermal Decomposition of Phosphate Esters on Ferrous Surfaces

2019 ◽  
Author(s):  
James Ewen ◽  
Carlos Ayestaran Latorre ◽  
Arash Khajeh ◽  
Joshua Moore ◽  
Joseph Remias ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Film Formation ◽  
Substituent Effects ◽  
Vapour Phase ◽  
Industrial Applications ◽  
Phosphate Esters ◽  
Antiwear Additives ◽  
Formation Mechanisms ◽  
Phosphate Ester ◽  
Wide Range

<p>Phosphate esters have a wide range of industrial applications, for example in tribology where they are used as vapour phase lubricants and antiwear additives. To rationally design phosphate esters with improved tribological performance, an atomic-level understanding of their film formation mechanisms is required. One important aspect is the thermal decomposition of phosphate esters on steel surfaces, since this initiates film formation. In this study, ReaxFF molecular dynamics simulations are used to study the thermal decomposition of phosphate esters with different substituents on several ferrous surfaces. On Fe<sub>3</sub>O<sub>4</sub>(001) and α-Fe(110), chemisorption interactions between the phosphate esters and the surfaces occur even at room temperature, and the number of molecule-surface bonds increases as the temperature is increased from 300 to 1000 K. Conversely, on hydroxylated, amorphous Fe<sub>3</sub>O<sub>4</sub>, most of the molecules are physisorbed, even at high temperature. Thermal decomposition rates were much higher on Fe<sub>3</sub>O<sub>4</sub>(001) and particularly α-Fe(110) compared to hydroxylated, amorphous Fe<sub>3</sub>O<sub>4</sub>. This suggests that water passivates ferrous surfaces and inhibits phosphate ester chemisorption, decomposition, and ultimately film formation. On Fe<sub>3</sub>O<sub>4</sub>(001), thermal decomposition proceeds mainly through C-O cleavage (to form surface alkyl and aryl groups) and C-H cleavage (to form surface hydroxyls). The onset temperature for C-O cleavage on Fe<sub>3</sub>O<sub>4</sub>(001) increases in the order: tertiary alkyl < secondary alkyl < primary linear alkyl ≈ primary branched alkyl < aryl. This order is in agreement with experimental observations for the thermal stability of antiwear additives with similar substituents. The results highlight surface and substituent effects on the thermal decomposition of phosphate esters which should be helpful for the design of new molecules with improved performance.</p>

A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland

2001 ◽  
pp. 159-166 ◽  
Author(s):  
Jens Konnerup-Madsen
Keyword(s):  
Nepheline Syenite ◽  
Subsequent Development ◽  
High Water ◽  
Vapour Phase ◽  
Low Carbon ◽  
Low Oxygen ◽  
Alkaline Complex ◽  
Hydrocarbon Gases ◽  
Wide Range ◽  
Water Contents

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Konnerup-Madsen, J. (2001). A review of the composition and evolution of hydrocarbon gases during solidification of the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin, 190, 159-166. https://doi.org/10.34194/ggub.v190.5187 _______________ Fluid inclusions in minerals from agpaitic nepheline syenites and hydrothermal veins in the Ilímaussaq complex and in similar agpaitic complexes on the Kola Peninsula, Russia, are dominated by hydrocarbon gases (predominantly methane) and hydrogen. Such volatile compositions differ considerably from those of most other igneous rocks and their formation and entrapment in minerals reflects low oxygen fugacities and a wide range of crystallisation temperatures extending to a low-temperature solidus. Their composition reflects initial low carbon contents and high water contents of the magma resulting in the exsolution of a waterrich CO2–H2O dominated vapour phase. Fractionation of chlorides into the vapour phase results in high salinities and the subsequent development of a heterogeneous vapour phase with a highly saline aqueous-rich fraction and a methane-dominated fraction, with preferential entrapment of the latter, possibly due to different wetting characteristics. The light stable isotope compositions support an abiogenic origin for the hydrocarbons in agpaitic nepheline syenite complexes.

Legal aspects of the brand protection in Ukraine and world

2020 ◽  
pp. 133-143
Author(s):  
Ivanna Babetska
Keyword(s):  
Public Relations ◽  
Practical Importance ◽  
Legal Protection ◽  
Legal Regulation ◽  
Legal Aspects ◽  
Scientific Article ◽  
Protection Mechanism ◽  
Brand Protection ◽  
Wide Range ◽  
International Regulations

Purpose. The purpose of the scientific article is to establish the ratio of the meanings of the concepts "trademark", "brand" and "well-known" trademark and then to characterize their common and distinctive features. Indicate the gaps in current legislation and the need to refine certain rules in this aspect to determine the aspects of protection and protection of the brand. Methodology. The methodology includes a comprehensive analysis and generalization of the available scientific and theoretical material and the formulation of appropriate conclusions and recommendations. During the research, the following methods of scientific knowledge were used: terminological, dialectical, logical-semantic, logical-normative, system-structural. Results: in the course of the conducted study, the main and optional components of the brand are determined, which make it possible to determine the features of its legal protection. It has been proved that despite a fairly wide range of domestic and international regulations, there are certain shortcomings of the brand protection mechanism. Originality. The study found that a trademark differs from a brand in that a trademark is a designation that is only the basis of the brand, as for the trademark are not essential such properties of the designation as a certain level of information among consumers and quality as a basis. gaining a reputation; the concept of "brand" is an evaluative, conditional concept, and therefore its consolidation at the regulatory level is impractical. It is sufficient to establish the factors on the basis of which the trademark can be considered "well known". A "well-known" trademark is a designation that is familiar to a wide range of consumers through its use to designate certain goods. Practical importance. The results of the study can be used in law-making activities for the purpose of legal regulation of public relations in the sphere of legal protection of the brand.

Developing low-cost methane gas concentration measuring device

2021 ◽  
pp. 54-59
Author(s):  
Md. Mahidy Hossain ◽  
Nadim Khandaker
Keyword(s):  
Promising Result ◽  
Low Cost ◽  
Measurement Techniques ◽  
Health And Safety ◽  
Modern Science ◽  
Methane Content ◽  
Measuring Device ◽  
Methane Generation ◽  
Methane Gas ◽  
Wide Range

In every aspect of Engineering more advanced, efficient and progressive solutions are required. The modern age of science requires innovative minds. The field of environmental engineering is also advancing with modern science and technology innovations. Measuring of methane concentration and flow rate is nothing new, yet a complicated process. The need for more accurate measurement is a necessity in proper operation of bio digesters for methane generation. The traditional process of the measuring methane content in biogas is time consuming yet complicated. The need for development and application of methane measurement techniques is not only limited to biogas but has other monitoring value as well in other health and safety applications in built environments. Winsen Electronics and Hanwei Electronics are two of the leading sensor-manufactures of China who are providing a wide range of gas detecting sensors that are locally available in Bangladesh and yet has not been applied to methane content measurement in biogas operations. In This paper we are reporting on the application of a purpose-built propane, butane detector for methane gas detection within the range of accuracy for it to be applied in methane detection in a biogas stream. This paper, reports on application and calibration of the methane detecting sensor MQ-4 with promising result. Based on the study we postulate that the sensor can be used to detect methane for an on-line monitoring of many environmental, industrial purposes such as bio digesters, integrated waste management facility. The cost of fabrication of the sensor system is only $18 making it a viable sensor with respect to cost for application in Bangladesh.

Extra Drag Force on a Circular Cylinder Due to the Presence of Solid Particles in Subsonic Compressible Flow

1991 ◽  
Author(s):  
Stanley B. Mellsen
Keyword(s):  
Compressible Flow ◽  
Incompressible Flow ◽  
Aerodynamic Drag ◽  
Collection Efficiency ◽  
Reynolds Numbers ◽  
Solid Particles ◽  
Circular Cylinders ◽  
Critical Mach Number ◽  
Wide Range ◽  
Inertia Parameters

Abstract The effect of particles, such as dust in air on aerodynamic drag of circular cylinders was calculated for compressible flow at critical Mach number and for incompressible flow. The effect of compressibility was found negligible for particles larger than about 10 μm, for which the air can be considered a continuum. Drag coefficient and collection efficiency are provided for a wide range of inertia parameters and Reynolds numbers for both compressible and incompressible flow.

The use of «coasorption» concept while describing the effect of coagulants on the wastewater aqua systems

2021 ◽  
pp. 33-39
Author(s):  
Е.В. Алексеев
Keyword(s):  
Wastewater Treatment ◽  
Industrial Wastewater ◽  
Practical Importance ◽  
Quantitative Relationship ◽  
Synthetic Dyes ◽  
Pollutant Concentrations ◽  
Wide Range ◽  
Complex Chemical Composition ◽  
The One ◽  
Raw Wastewater

Широкое распространение реагентного коагулирования в технологии очистки природных и промышленных сточных вод обусловлено, с одной стороны, сложностью химического состава и фазово-дисперсного состояния их аквасистем, с другой – многофакторностью действия на них коагулянтов. Рассмотрены основные механизмы взаимодействия коагулянтов и загрязняющих веществ на примере очистки промышленных сточных вод, содержащих органические вещества (поверхностно-активные вещества и синтетические красители). Физико-химическое понятие «коагуляция» отражает только один из механизмов действия коагулянтов на загрязнители. Принятые в настоящее время технологические показатели «доза коагулянта» и «удельная доза коагулянта» также не отражают многообразие взаимодействий загрязняющих веществ с солями коагулянтов и не привязаны к результату коагулирования. Это обусловливает трудность описания совокупного действия физико-химических процессов при добавлении коагулянтов в очищаемые воды и его количественной оценки. Решение проблемы возможно введением понятия «коасорбция», определяющего многофакторность взаимодействия коагулянтов с загрязняющими веществами в процессах очистки сточных вод коагулированием, и технологического показателя «удельная коасорбция», устанавливающего количественную взаимосвязь между величинами загрязняющих веществ в исходной и очищенной воде с дозой коагулянта. Графически представлены функции удельной коасорбции в форме изотерм коасорбции для двух типов поверхностно-активных веществ и синтетических красителей. На основании результатов анализа особенностей изотерм показано, что они отражают разные механизмы взаимодействия коагулянтов и загрязняющих веществ. Использование коасорбции как технологического понятия способствует выявлению механизмов взаимодействия загрязняющих веществ с коагулянтом и созданию наилучших условий для осуществления процесса коагулирования. Функциональное описание изотерм коасорбции позволяет экстраполировать результаты пробного коагулирования в широком интервале концентраций загрязняющих веществ. Практическое значение изотерм удельной коасорбции состоит в возможности определения доз реагентов при коагулировании воды по начальному содержанию загрязняющих веществ и требуемому в очищенных водах. The widespread use of chemical coagulation in purification of natural water and industrial wastewater is due, on the one hand, to the complex chemical composition and phase-disperse state of their aqua systems, and on the other hand, to the multifactorial effect of coagulants on them. The main mechanisms of interaction between coagulants and pollutants are considered through the example of industrial wastewater treatment containing organic substances (surfactants and synthetic dyes). The physicochemical term «coagulation» reflects only one of the mechanisms of the effect of coagulants on pollutants. The currently accepted process parameters «dose of coagulant» and «specific dose of coagulant» do not reflect the variety of interactions of pollutants with coagulant salts either, and are not linked to the result of coagulation. This makes it difficult to describe the collective effect of physicochemical processes while adding coagulants to the treated water and to quantify it. The solution to the problem is possible introducing the concept of «coasorption» that determines the multifactorial origin of the interaction of coagulants and pollutants in the processes of wastewater treatment by coagulation; and the process parameter «specific coasorption» that establishes a quantitative relationship between the concentrations of pollutants in raw wastewater and effluent with a dose of coagulant. The specific coasorption functions are graphically presented in the form of coasorption isotherms for two types of surfactants and synthetic dyes. Based on the results of the analysis of the features of the isotherms, it is shown that they reflect different mechanisms of interaction between coagulants and pollutants. The use of coasorption as a technological concept provides for identifying the mechanisms of interaction of pollutants with a coagulant and establishing the best conditions for the coagulation process. The functional description of the coasorption isotherms allows extrapolating the results of trial coagulation in a wide range of pollutant concentrations. The practical importance of specific coasorption isotherms provides for determining the dosages of chemicals during coagulation of water based on the initial concentration of pollutants and effluent standard.

scholarly journals Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions

2016 ◽  
Vol 2 (7) ◽  
pp. e1600320 ◽  
Author(s):  
Mukul D. Tikekar ◽  
Lynden A. Archer ◽  
Donald L. Koch
Keyword(s):  
Elastic Solid ◽  
Present Theory ◽  
Metal Electrode ◽  
Mitigation Strategies ◽  
Factors Affecting ◽  
Wide Range ◽  
Current Densities ◽  
Morphological Instabilities ◽  
The Stability

Ion transport–driven instabilities in electrodeposition of metals that lead to morphological instabilities and dendrites are receiving renewed attention because mitigation strategies are needed for improving rechargeability and safety of lithium batteries. The growth rate of these morphological instabilities can be slowed by immobilizing a fraction of anions within the electrolyte to reduce the electric field at the metal electrode. We analyze the role of elastic deformation of the solid electrolyte with immobilized anions and present theory combining the roles of separator elasticity and modified transport to evaluate the factors affecting the stability of planar deposition over a wide range of current densities. We find that stable electrodeposition can be easily achieved even at relatively high current densities in electrolytes/separators with moderate polymer-like mechanical moduli, provided a small fraction of anions are immobilized in the separator.

scholarly journals Universities’ Intellectual Capital Report: The Formation Concept, Analytical Capabilities under Stakeholders Management Decisions-Making

2020 ◽  
Vol 7 (6) ◽  
pp. 40-54
Author(s):  
A. A. Vakhrushina ◽  
M. A. Vakhrushina
Keyword(s):  
Intellectual Capital ◽  
Practical Importance ◽  
Economic Life ◽  
Effective Management ◽  
Ministry Of Education ◽  
Systematic Analysis ◽  
Accounting Systems ◽  
Management Accounting Systems ◽  
Wide Range ◽  
Russian Universities

The modern trends in the socio-economic life, educational and research spheres lead to the increased attention of universities to the more effective management of available resources, as well as high-quality and relevant disclosure of information in their public reporting to the interested parties. Under the circumstances, the intellectual capital (IC) components become key objects in the management accounting systems, and the IC report may become one of the main engines to achieve the transparent information which can raise the interest of stakeholders. The analysis of this practice clarified the discussion points and helped to develop conceptual guidelines for the preparation of the IC report for Russian universities. There have been used the following methods to solve the problem, such as quantitative-systematic analysis, semantic grouping of results and logical relationships. The developed methodology for analyzing the report on IC universities has a certain practical importance. Such methodology also includes methods of financial and management analysis. The formulated recommendations are intended for a wide range of stakeholders, the leadership of the Russian Ministry of Education and Science and higher education institutions.

scholarly journals MODELING COMPUTATIONAL FLUID DYNAMICS OF MULTIPHASE FLOWS IN ELBOW AND T-JUNCTION OF THE MAIN GAS PIPELINE

Transport ◽  
2019 ◽  
Vol 34 (1) ◽  
pp. 19-29 ◽  
Author(s):  
Yaroslav Doroshenko ◽  
Julia Doroshenko ◽  
Vasyl Zapukhliak ◽  
Lyubomyr Poberezhny ◽  
Pavlo Maruschak
Keyword(s):  
Natural Gas ◽  
Multiphase Flows ◽  
Linear Part ◽  
Erosive Wear ◽  
Gas Pipeline ◽  
Solid Particles ◽  
Ansys Fluent ◽  
Gas Main ◽  
Discrete Phase ◽  
Main Gas Pipeline

The research was performed in order to obtain the physical picture of the movement of condensed droplets and solid particles in the flow of natural gas in elbows and T-junctions of the linear part of the main gas pipeline. 3D modeling of the elbow and T-junction was performed in the linear part of the gas main, in particular, in places where a complex movement of multiphase flows occurs and changes its direction. In these places also occur swirls, collisions of discrete phases in the pipeline wall, and erosive wear of the pipe wall. Based on Lagrangian approach (Discrete Phase Model – DPM), methods of computer modeling were developed to simulate multiphase flow movement in the elbow and T-junction of the linear part of the gas main using software package ANSYS Fluent R17.0 Academic. The mathematical model is based on solving the Navier–Stokes equations, and the equations of continuity and discrete phase movement closed with Launder–Sharma (k–e) two-parameter turbulence model with appropriate initial and boundary conditions. In T-junction, we simulated gas movement in the run-pipe, and the passage of the part of flow into the branch. The simulation results were visualized in postprocessor ANSYS Fluent R17.0 Academic and ANSYS CFD-Post R17.0 Academic by building trajectories of the motion of condensed droplets and solid particles in the elbow and T-junction of the linear part of the gas main in the flow of natural gas. The trajectories were painted in colors that match the velocity and diameter of droplets and particles according to the scale of values. After studying the trajectories of discrete phases, the locations of their heavy collision with the pipeline walls were found, as well as the places of turbulence of condensed droplets and solid particles. The velocity of liquid and solid particles was determined, and the impact angles, diameters of condensed droplets and solid particles in the place of collision were found. Such results provide possibilities for a full and comprehensive investigation of erosive wear of the elbow and T-junction of the linear part of the gas main and adjacent sections of the pipeline, and for the assessment of their strength and residual life.

A mixed contact model for an immersed collision between two solid surfaces

2008 ◽  
Vol 366 (1873) ◽  
pp. 2205-2218 ◽  
Author(s):  
Fu-Ling Yang ◽  
Melany L Hunt
Keyword(s):  
Surface Deformation ◽  
Elastohydrodynamic Lubrication ◽  
Solid Particles ◽  
Solid Surfaces ◽  
Additional Energy ◽  
Collision Model ◽  
Dry Granular Flow ◽  
Wide Range ◽  
The Impact ◽  
Surrounding Liquid

Experimental evidence shows that the presence of an ambient liquid can greatly modify the collision process between two solid surfaces. Interactions between the solid surfaces and the surrounding liquid result in energy dissipation at the particle level, which leads to solid–liquid mixture rheology deviating from dry granular flow behaviour. The present work investigates how the surrounding liquid modifies the impact and rebound of solid spheres. Existing collision models use elastohydrodynamic lubrication (EHL) theory to address the surface deformation under the developing lubrication pressure, thereby coupling the motion of the liquid and solid. With EHL theory, idealized smooth particles are made to rebound from a lubrication film. Modified EHL models, however, allow particles to rebound from mutual contacts of surface asperities, assuming negligible liquid effects. In this work, a new contact mechanism, ‘mixed contact’, is formulated, which considers the interplay between the asperities and the interstitial liquid as part of a hybrid rebound scheme. A recovery factor is further proposed to characterize the additional energy loss due to asperity–liquid interactions. The resulting collision model is evaluated through comparisons with experimental data, exhibiting a better performance than the existing models. In addition to the three non-dimensional numbers that result from the EHL analysis—the wet coefficient of restitution, the particle Stokes number and the elasticity parameter—a fourth parameter is introduced to correlate particle impact momentum to the EHL deformation impulse. This generalized collision model covers a wide range of impact conditions and could be employed in numerical codes to simulate the bulk motion of solid particles with non-negligible liquid effects.

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