Segregation at Interphase Boundaries

1968 ◽  
pp. 455-480
Author(s):  
G. Bruggeman ◽  
E. B. Kula
Keyword(s):  
Interphase Boundaries

Modeling of pressure losses on friction in three-layer laminar flows

2003 ◽  
Vol 3 ◽  
pp. 208-219
Author(s):  
A.M. Ilyasov
Keyword(s):  
Pressure Loss ◽  
Gas Flow ◽  
Mutual Influence ◽  
Fluid Model ◽  
Immiscible Liquid ◽  
Laminar Flows ◽  
Pressure Losses ◽  
Flow Parameters ◽  
Interphase Boundaries ◽  
Closing Relations

In this paper we propose a model for determining the pressure loss due to friction in each phase in a three-layer laminar steady flow of immiscible liquid and gas flow in a flat channel. This model generalizes an analogous problem for a two-layer laminar flow, proposed earlier. The relations obtained in the final form for the pressure loss due to friction in liquids can be used as closing relations for the three-fluid model. These equations take into account the influence of interphase boundaries and are an alternative to the approach used in foreign literature. In this approach, the wall and interphase voltages are approximated by the formulas for a single-phase flow and do not take into account the mutual influence of liquids on the loss of pressure on friction in phases. The distribution of flow parameters in these two models is compared.

Monte Carlo Modeling of Interphase Boundaries in Cu-Ag and Cu-Ag-Au Alloys

1990 ◽  
Vol 205 ◽  
Author(s):  
P. Bacher ◽  
P. Wynblatt
Keyword(s):  
Monte Carlo Simulation ◽  
Monte Carlo ◽  
Binary System ◽  
Ternary Alloy ◽  
Embedded Atom Method ◽  
Misfit Dislocations ◽  
Monte Carlo Modeling ◽  
Embedded Atom ◽  
Composition And Structure ◽  
Interphase Boundaries

AbstractMonte Carlo simulation, in conjunction with the embedded atom method, has been used to model the composition and structure of a semicoherent (001) interphase boundary separating coexisting Cu-rich and Ag-rich phases in a binary Cu-Ag alloy. The results are compared with earlier simulations of the same boundary in a Cu-Ag-Au alloy, in which Au was found to segregate to the interface, and the boundary was found to be unstable with respect to break-up into {111} facets. The boundary in the binary system is also unstable to faceting, but displays both {100} as well as {111} facets. It is concluded that Au segregation in the ternary alloy plays an important role in stabilizing the {111} facets. The interplay between the misfit dislocations present at the interface, and the compositional features of the boundary are also discussed.

Diffusion of Zinc in Two-Phase Mg-Al Alloy

2007 ◽  
Vol 263 ◽  
pp. 189-194
Author(s):  
Ivo Stloukal ◽  
Jiří Čermák
Keyword(s):  
Diffusion Coefficient ◽  
Diffusion Coefficients ◽  
Effective Diffusion ◽  
Residual Activity ◽  
Diffusion Path ◽  
Al Alloy ◽  
Serial Sectioning ◽  
Two Phase ◽  
Interphase Boundaries ◽  
The Mean

Coefficient of 65Zn heterodiffusion in Mg17Al12 intermetallic and in eutectic alloy Mg - 33.4 wt. % Al was measured in the temperature region 598 – 698 K using serial sectioning and residual activity methods. Diffusion coefficient of 65Zn in the intermetallic can be written as DI = 1.7 × 10-2 m2 s-1 exp (-155.0 kJ mol-1 / RT). At temperatures T ≥ 648 K, where the mean diffusion path was greater than the mean interlamellar distance in the eutectic, the effective diffusion coefficient Def = 2.7 × 10-2 m2 s-1 exp (-155.1 kJ mol-1 / RT) was evaluated. At two lower temperatures, the diffusion coefficients 65Zn in interphase boundaries were estimated: Db (623 K) = 1.6 × 10-12 m2 s-1 and Db (598 K) = 4.4 × 10-13 m2 s-1.

Local decomposition of solid solutions, nanostructures and optical materials with negative refractive index

2016 ◽  
Vol 30 (07) ◽  
pp. 1650088
Author(s):  
Valeriy M. Ishchuk ◽  
Vladimir Sobolev
Keyword(s):  
Refractive Index ◽  
Electric Conductivity ◽  
Solid Solutions ◽  
Lead Zirconate Titanate ◽  
Perovskite Structure ◽  
Optical Materials ◽  
Negative Refractive Index ◽  
Lead Zirconate ◽  
The State ◽  
Interphase Boundaries

In this paper, a possibility of use of the controlled decomposition of solid solutions of oxides with perovskite structure in the state of coexisting domains of the antiferroelectric (AFE) and ferroelectric (FE) phases for manufacturing materials with the negative refractive index is demonstrated. The lead zirconate titanate-based solid solutions are considered as an example of substances suitable for creation of such materials. Manufactured composites constitute a dielectric AFE matrix with a structure of conducting interphase boundaries separating domains of the FE and AFE phases. The electric conductivity of the interphase boundaries occurs as a result of the local decomposition of the solid solutions in the vicinity of these boundaries. The decomposition process and consequently the conductivity of the interphase boundaries can be controlled by means of external influences.

Elastic Properties of Steps at Interphase Boundaries

1991 ◽  
Vol 238 ◽  
Author(s):  
G. J. Shiflet
Keyword(s):  
Energy Density ◽  
Elastic Properties ◽  
Mathematical Analysis ◽  
Strain Energy ◽  
Chemical Processes ◽  
Diffusion Kinetics ◽  
Interphase Boundaries ◽  
Kinetics Of ◽  
Maximum Stresses

ABSTRACTStresses are introduced in crystals at interphase boundaries where steps improve the registry of atoms. A model and mathematical analysis based on an approach previously taken by van der Merwe and Shiflet1–4 of the problem incorporating a coherent step are presented. Computed distributions of stresses, strains, dilatation and energy density in the form of contours and nets are given for a coherent monatomic step. It is concluded that the maximum stresses are quite large and the fields decay fairly rapidly with distance from the steps, the gradient of dilatation around steps will significantly affect diffusion kinetics of impurities and the strain energy seems too low to significantly enhance chemical processes.

Expressions for the effective diffusivity in materials with interphase boundaries

2004 ◽  
Vol 819 ◽  
Author(s):  
Irina V. Belova ◽  
Graeme E. Murch
Keyword(s):  
Polycrystalline Material ◽  
Effective Diffusivity ◽  
Poor Agreement ◽  
Two Phase ◽  
Interphase Boundaries ◽  
Long Time ◽  
Simulation Results ◽  
The Individual ◽  
Individual Grains ◽  
Good Agreement

AbstractWe address the problem of calculating the long-time-limit effective diffusivity in stable two- phase polycrystalline material. A phenomenological model is used where the high diffusivity interphase boundaries are treated as connected “coatings” of the individual grains. Derivation of expressions for the effective diffusivity with segregation is made along Maxwell lines. Monte Carlo simulation using lattice-based random walks is used to test the validity of the expressions. It is shown that for the case analysed the derived expressions for the effective diffusivity are in very good agreement with simulation results. The equivalent of the Hart equation is also derived. It is shown to be in poor agreement with simulation results.

scholarly journals Determination of Segregation Influence on the Motion of the Interphase Boundaries During Cellular Precipitation

2016 ◽  
Vol 37 (12) ◽  
pp. 1619-1632
Author(s):  
Yu. O. Lyashenko ◽  
◽  
S. I. Derevyanko ◽  
O. A. Shmatko ◽  
◽  
...  
Keyword(s):  
Cellular Precipitation ◽  
Interphase Boundaries

Microhardness Enhancement in Fully Dense Fe-Based Nanophase Metallic Alloys

1995 ◽  
Vol 400 ◽  
Author(s):  
L. He ◽  
E. Ma
Keyword(s):  
Grain Size ◽  
High Energy ◽  
Metallic Alloys ◽  
Full Density ◽  
Strengthening Effect ◽  
Two Phase ◽  
Grain Sizes ◽  
Sinter Forging ◽  
Interphase Boundaries ◽  
Energy Ball

AbstractNano-grained Fe-29Al-2Cr intermetallic and Fe-Cu two-phase composites have been consolidated to full density from powders produced by high-energy ball milling, using a sinter forging procedure developed recently in our laboratory. Grain sizes remained within nanophase range (<100 nm) after consolidation. Microhardness tests of Fe-29Al-2Cr samples consolidated to different density levels indicate a significant strengthening effect due to nanoscale grain size and a monotonic microhardness increase with decreasing residual porosity. Fully dense Fe-Cu composites exhibit enhanced microhardness as compared with rule-of-mixtures predictions, which may be attributable to interface strengthening at fcc-bcc interphase boundaries.

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