The Principal Structural-Textural Groups of Spherical Mineral Aggregates

Author(s):  
Lev M. Lebedev
Keyword(s):  
Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.


2017 ◽  
Vol 16 (4) ◽  
pp. 897-903
Author(s):  
Paula Cojocaru ◽  
Florian Statescu ◽  
Gabriela Biali

Recycling ◽  
2021 ◽  
Vol 6 (1) ◽  
pp. 19
Author(s):  
Christina Makoundou ◽  
Kenth Johansson ◽  
Viveca Wallqvist ◽  
Cesare Sangiorgi

The substitution of mineral aggregates with crumb rubber (CR) from waste end-of-life tires (ELTs) in the asphalt concretes, has been considered a sustainable paving industry approach. The rubber has been used to construct pavements with proven enhanced resilience and improved durability. However, some issues related to the rubber’s surface adhesion or swelling may arise with these practices and generate complications (binder consumption, temperatures, mixing times). One possible solution to overcome the materials’ compatibility problems is to pre-treat the CR’s surface before its incorporation into the asphalt mixes to allow a surface functionalization that can enhance coverage and cohesion inside the mixes. The physical treatments using radiations-based beam are already exploited in the plastic recycling industries avoiding the use of chemicals in considerable amounts. Such treatments permit the recovering of large quantities of polymer-based materials and the enhancement of interfacial properties. This article provides an overview of existing surface treatments of polymers and especially rubber, including gamma ray, UV-ozone, microwaves, and plasma. Several studies have shown an overall improvement of the rubber surface’s reactive properties due to contaminant removal or roughness enhancement attributed to cross-linking or scission reactions occurring on the rubber’s surface layer. With those properties, the asphalt mixes’ phase stability properties are increased when the pre-treated rubber is incorporated. The treatments would permit to increase the CR quantities, yet reduce the layer stiffness, and improve the durability and the sustainability of future advanced road pavements.


2014 ◽  
Vol 57 ◽  
pp. 29-52 ◽  
Author(s):  
Harald G. Dill ◽  
Berthold Weber ◽  
Frank Melcher ◽  
Werner Wiesner ◽  
Axel Müller

Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 420 ◽  
Author(s):  
Hans-Jürgen Förster ◽  
Luca Bindi ◽  
Günter Grundmann ◽  
Chris Stanley

Cerromojonite, ideally CuPbBiSe3, represents a new selenide from the El Dragόn mine, Department of Potosí, Bolivia. It either occurs as minute grains (up to 30 µm in size) in interstices of hansblockite/quijarroite intergrowths, forming an angular network-like intersertal texture, or as elongated, thin-tabular crystals (up to 200 μm long and 40 μm wide) within lath-shaped or acicular mineral aggregates (interpreted as pseudomorphs) up to 2 mm in length and 200 μm in width. It is non-fluorescent, black, and opaque, with a metallic luster and black streak. It is brittle, with an irregular fracture, and no obvious cleavage and parting. In plane-polarized incident light, cerromojonite is grey to cream-white, and weakly pleochroic, showing no internal reflections. Between crossed polarizers, cerromojonite is weakly anisotropic, with rotation tints in shades of brown and grey. Lamellar twinning on {110} is common. The reflectance values in air for the COM standard wavelengths (R1 and R2) are: 48.8 and 50.3 (470 nm), 48.2 and 51.8 (546 nm), 47.8 and 52.0 (589 nm), and 47.2 and 52.0 (650 nm). Electron-microprobe analyses yielded a mean composition of: Cu 7.91, Ag 2.35, Hg 7.42, Pb 16.39, Fe 0.04, Ni 0.02, Bi 32.61, Se 33.37, total 100.14 wt %. The empirical formula (based on 6 atoms pfu) is (Cu0.89Hg0.11)Σ = 1.00(Pb0.56Ag0.16Hg0.15 Bi0.11Fe0.01)Σ = 0.99Bi1.00Se3.01. The ideal formula is CuPbBiSe3. Cerromojonite is orthorhombic (space group Pn21m), with a = 8.202(1) Å, b = 8.741(1) Å, c = 8.029(1) Å, V = 575.7(1) Å3, Z = 4. Calculated density is 7.035 g·cm−3. The five strongest measured X-ray powder diffraction lines (d in Å (I/I0) (hkl)) are: 3.86 (25) (120), 2.783 (100) (122), 2.727 (55) (212), 2.608 (40) (310), and 1.999 (25) (004). Cerromojonite is a new member of the bournonite group, representing the Se-analogue of součekite, CuPbBi(S,Se)3. It is deposited from strongly oxidizing low-T hydrothermal fluids at a fSe2/fS2 ratio >1, both as primary and secondary phase. The new species has been approved by the IMA-CNMNC (2018-040) and is named for Cerro Mojon, the highest mountain peak closest to the El Dragón mine.


2002 ◽  
Vol 8 (1) ◽  
pp. 31-44 ◽  
Author(s):  
Patricia Stoffyn-Egli ◽  
Kenneth Lee
Keyword(s):  

2016 ◽  
Vol 155 (3) ◽  
pp. 568-585 ◽  
Author(s):  
JOHN N. HOOKER ◽  
JOE CARTWRIGHT

AbstractA long-debated aspect of cone-in-cone structures is whether the mineral aggregates composing the structure precipitated with their conical form (primary cone-in-cone), or whether the cones formed after precipitation (secondary cone-in-cone). A calcite deposit from the Cretaceous of Jordan bears all the defining characteristics of the structure. Trace dolomite within the sample supports the primary cone-in-cone hypothesis. The host sediment is a biosiliceous mudstone containing abundant rhombohedral dolomite grains. Dolomite rhombohedra are also distributed throughout the calcite of the cone-in-cone. The rhombohedra within the calcite locally have dolomite overgrowths that are aligned with calcite fibres. Evidence that dolomite co-precipitated with calcite, and did not replace calcite, includes (i) preferential downward extension of dolomite overgrowths, in the presumed growth-direction of the cone-in-cone, from the dolomite grains on which they nucleate, and (ii) planar, vertical borders between dolomite crystals and calcite fibres. Because dolomite overgrows host-sediment rhombohedra and forms part of the cones, it follows that the host-sediment was incorporated into the growing cone-in-cone as the calcite precipitated, and not afterward. The host-sediment was not injected into the cone-in-cone along fractures, as the secondary-origin theory suggests. This finding implies that cone-in-cone in general does not form over multiple stages, and thus has greater potential to preserve the chemical signature of its original precipitation.


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