Removal of Heavy Metals, Lead, Cadmium, and Zinc, Using Adsorption Processes by Cost-Effective Adsorbents

Author(s):  
Meng Xu ◽  
Gordon McKay
Clay Minerals ◽  
1999 ◽  
Vol 34 (3) ◽  
pp. 469-477 ◽  
Author(s):  
A. Garcia Sanchez ◽  
E. Alvarez Ayuso ◽  
O. Jimenez de Blas

AbstractThe adsorption by different silicate minerals of some heavy metals, present in industrial waste water, has been studied. These adsorbents (mainly clay minerals) are readily available, inexpensive materials and offer a cost-effective alternative to conventional treatment of wastes from the metal finishing industry. The results show that some mineral species are suitable for the purification of such residual waters down to the limits prescribed by current legislation concerning industrial wastes. The Langmuir model was found to describe such adsorption processes best. Sepiolite (Orera, Spain) has an adsorption capacity of 8.26 mg g-1 for Cd2+, the capacities depending on the metal adsorbed in the order: Cd2+ > Cu2+ > Zn2+ > Ni2+. This mineral shows the highest sorption capacity relative to the other minerals studied. Factors in the reaction medium such as pH and ionic strength influenced the adsorption process.


Author(s):  
Andrea Pérez-Vidal ◽  
Jorge Antonio Silva-Leal ◽  
Jaime Diaz-Gómez ◽  
Camilo J. Meneses-Torres ◽  
Juan E. Arias-Vallejo ◽  
...  

Abstract It has been demonstrated that the ceramic pot filters (CPFs) with impregnated colloidal silver are efficient for the removal of turbidity and pathogens for household water treatment. This investigation evaluated the efficiency of two filter models for the removal of chemical contaminants (Hg, Pb, As and phenolic compounds) during 175 days. The first model is a traditional CPF impregnated with colloidal silver and the second consists of the ceramic silver-impregnated pot plus a post-filtration column with granular activated carbon and zeolite (CPF + GAC-Z). The results of the CPF showed average efficiencies of 91.5% (Hg), 92% (Pb), 50.2% (As) and 78.7% (phenols). The CPF + GAC-Z showed similar efficiencies for the removal of heavy metals (92.5% Hg, 98.1% Pb and 52.3% As) and a considerably higher efficiency for the removal of phenols (96.4%). The As concentration of the filtered water in both systems was higher than the regulatory limit. The ceramic pot was responsible for the highest removal of chemical compounds. It can be concluded that the traditional CPF is a viable option for water supply treatment at the household level for the removal of chemical contaminants. The efficiency of this filter can be improved with the post-filtration column mainly for the removal of organic constituents.


2021 ◽  
Author(s):  
Athar Hussain ◽  
Sangeeta Madan ◽  
Richa Madan

Adsorption processes are extensively used in wastewater treatment for heavy metal removal. The most widely used adsorbent is activated carbon giving the best of results but it’s high cost limits its use. It has a high cost of production and regeneration. As the world today faces a shortage of freshwater resources, it is inevitable to look for alternatives that lessen the burden on existing resources. Also, heavy metals are toxic even in trace concentrations, so an environmentally safe method of their removal necessitated the requirement of low cost adsorbents. Adsorption is a cost-effective technique and gained recognition due to its minimum waste disposal advantage. This chapter focuses on the process of adsorption and the types of adsorbent available today. It also encompasses the low-cost adsorbents ranging from agricultural waste to industrial waste explaining the adsorption reaction condition. The cost-effectiveness, technical applicability and easy availability of raw material with low negative impact on the system are the precursors in selecting the adsorbents. The novelty of the chapter lies in covering a wide range of adsorbents with their efficiency in removal of heavy metals from wastewater.


Author(s):  
Ma. del Rosario Moreno Virgen ◽  
Omar Francisco González Vázquez ◽  
Virginia Hernández Montoya ◽  
Rigoberto Tovar Gómez

Processes ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 1379
Author(s):  
Rohit Kumar ◽  
Protima Rauwel ◽  
Erwan Rauwel

Heavy metal pollution of aquatic media has grown significantly over the past few decades. Therefore, a number of physical, chemical, biological, and electrochemical technologies are being employed to tackle this problem. However, they possess various inescapable shortcomings curbing their utilization at a commercial scale. In this regard, nanotechnology has provided efficient and cost-effective solutions for the extraction of heavy metals from water. This review will provide a detailed overview on the efficiency and applicability of various adsorbents, i.e., carbon nanotubes, graphene, silica, zero-valent iron, and magnetic nanoparticles for scavenging metallic ions. These nanoparticles exhibit potential to be used in extracting a variety of toxic metals. Recently, nanomaterial-assisted bioelectrochemical removal of heavy metals has also emerged. To that end, various nanoparticle-based electrodes are being developed, offering more efficient, cost-effective, ecofriendly, and sustainable options. In addition, the promising perspectives of nanomaterials in environmental applications are also discussed in this paper and potential directions for future works are suggested.


2019 ◽  
Vol 797 ◽  
pp. 3-12 ◽  
Author(s):  
Terri Zhuan Ean Lee ◽  
Siong Fong Sim

Previous studies have evidenced that coconut copra is a potential biosorbent for removal of dissolved organic carbon from peat swamp runoff attaining an average removal of 96 %. The capability of coconut copra in removing heavy metals including cadmium (Cd), chromium (Cr) and nickel (Ni) is scarcely reported. In this paper, response surface methodology was applied to evaluate the optimum conditions for removal of Cd, Cr and Ni from aqueous solution using raw coconut copra. Batch adsorption experiments were conducted according to inscribed central composite design. Response surface models further identified the optimum dosage, pH and contact time for Cd removal is 1.5 g, pH 11 and 60 min, Cr removal is 0.1 g, pH 8.48 and 60 min while Ni removal is 0.1 g, pH 11 and 15 min. Bimodality is observed in response surface graphs, implying the possible existence of two equilibrium phase during the adsorption process. Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models were employed to describe the adsorption behaviour. Results revealed that raw coconut copra can remove 4.55 mg/g of Cd, 8.71 mg/g of Cr and 26.46 mg/g of Ni. The adsorption processes are physical adsorption.


2018 ◽  
Vol 2 (1) ◽  
Author(s):  
Lakshmi Prasanna Koduru

Heavy metals are one of the primary contaminants in the environment [1]. Exposure to heavy metals, even at trace levels, is believed to be a high health risk for humans [2,3]. Heavy metals are naturally occurring throughout the earth’s crust [4]. But most of the environmental contamination results from the anthropogenic activities such as mining and smelting operations, industry, and domestic and agricultural use of metals and metalcontaining compounds. Migration of these contaminants into non-contaminated areas as dust or leachates through the soil and spreading of heavy metals containing sewage sludge are a few examples of events contributing towards contamination of the ecosystems [5]. Hence, water is the one of the major routes through which heavy metals and radionuclides may enter the human body [6,7]. The sources of water pollution are shown in Figure 1. The conventional wastewater purification techniques including chemical coagulation, photo degradation, precipitation, flocculation, activated sludge, membrane separation and ion exchange are limited to the removal of heavy metals at trace levels [7-9]. However, adsorption is one of the best methods for the purification of water, owing to its low cost and easy handling of materials [7,10-12]. Moreover, adsorption approaches using commercial activated carbon, micro-filtration and membrane techniques are effective, but their use is limited by the complicated installation process involved coupled with the high maintenance costs of the systems [7,13]. Hence, these drawbacks have necessitated the search for an alternative method which is inexpensive, renewable and cost-effective for the removal of heavy metals from aqueous solutions. Many scientific groups have prepared graphene or graphene oxide (GO) based hybrid nanocomposites for various potential applications [14-17]. The study of literature survey and stability of the GO-based nanocomposites prompted us to survey on graphene oxide and reduced graphene oxide-based inverse spinel nickel ferrite nanocomposites for the removal of heavy metals and radionuclides from water with the purpose of reducing their environmental impact


2020 ◽  
Vol 4 (1) ◽  
pp. 08-10
Author(s):  
Nurhaliza Said Mohd ◽  
Rabiatul Manisah Mohamed

Accumulation of heavy metals in water is of particularly important because it can impact upon human health through possible contamination of food. The use of banana peel was investigated. Hydrothermal carbonization (HTC) was chosen as alternative process. The objective of this project is to synthesize banana peel hydrochars adsorbent via HTC process and to evaluate the heavy metals adsorption performance of banana peel hydrochars adsorbent. Conventional methods in removal of heavy metals require high operational cost, need highly skilled labour, and generate sludge at the end of the operation. Compared to other techniques, banana peel absorbent is a cost- effective adsorbent, easy to operate, environmentally safe and no health risk for the operator. Besides, large quantity of banana peel waste contributes to its significant disposal problem. Thus, this study is expected to solve problems of banana peel, by preparing banana peel adsorbent through hydrothermal carbonization. There are three phases in this project, phase 1 which is synthesis of banana peel based on hydrochars, banana peel was chopped the peels into small pieces. It was then soaked in KOH solution for 2hours and transferred into PTFE and heat for 2hours at 230°C. For phase 2, physico-chemical characterization of banana peels hydrochars by using FTIR. The result obtained shown that all of the content in banana peels will activate the surface of banana peel to enhance the adsorption of the heavy metals. For the final phase, by using AAS, the initial and final concentration of the metals was tested to determine the removal of heavy metals by the prepared hydrochars. The results showed that the removal capacity of the hydrochars increased when the initial concentration of the metals increased. From the research, it can be concluded that, as the initial concentration of the metals higher, the ability of the hydrochars to remove the metals also higher and stronger.


2020 ◽  
Vol 179 ◽  
pp. 263-271 ◽  
Author(s):  
Sohail Ayub ◽  
Asif Ali Siddique ◽  
Md. S. Khursheed ◽  
Ahmad Zarei ◽  
Izhar Alam ◽  
...  

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