Bubbles in liquids with phase transition—part 2: on balance laws for mixture theories of disperse vapor bubbles in liquid with phase change

2013 ◽  
Vol 26 (4) ◽  
pp. 521-549 ◽  
Author(s):  
Wolfgang Dreyer ◽  
Maren Hantke ◽  
Gerald Warnecke
Keyword(s):  
Phase Transition ◽  
Phase Change ◽  
Balance Laws ◽  
Vapor Bubbles ◽  
Mixture Theories

Temperature Effect on the Two-Dimensional Phase Transition Kinetics of Adenine Adsorbed at the Hg Electrode/Aqueous Solution Interface

2003 ◽  
Vol 68 (8) ◽  
pp. 1407-1419 ◽  
Author(s):  
Claudio Fontanesi ◽  
Roberto Andreoli ◽  
Luca Benedetti ◽  
Roberto Giovanardi ◽  
Paolo Ferrarini
Keyword(s):  
Phase Transition ◽  
Aqueous Solution ◽  
Phase Change ◽  
Temperature Effect ◽  
Transition Rate ◽  
Effect Of Temperature ◽  
Two Dimensional ◽  
Solution Interface ◽  
Phase Transition Kinetics ◽  
Kinetics Of

The kinetics of the liquid-like → solid-like 2D phase transition of adenine adsorbed at the Hg/aqueous solution interface is studied. Attention is focused on the effect of temperature on the rate of phase change; an increase in temperature is found to cause a decrease of transition rate.

scholarly journals Combining Switchable Phase‐Change Materials and Phase‐Transition Materials for Thermally Regulated Smart Mid‐Infrared Modulators

2021 ◽  
pp. 2100417
Author(s):  
Xinrui Lyu ◽  
Andreas Heßler ◽  
Xiao Wang ◽  
Yunzhen Cao ◽  
Lixin Song ◽  
...  
Keyword(s):  
Phase Transition ◽  
Phase Change ◽  
Phase Change Materials ◽  
Mid Infrared

Sunlight-Activated Phase Change Materials for Controlled Heat Storage and Triggered Release

2021 ◽  
Author(s):  
Yuran Shi ◽  
Mihael Gerkman ◽  
Qianfeng Qiu ◽  
Shuren Zhang ◽  
Grace G. D. Han
Keyword(s):  
Phase Transition ◽  
Solar Radiation ◽  
Phase Change ◽  
Latent Heat ◽  
Photon Energy ◽  
Organic Phase ◽  
Phase Change Materials ◽  
Heat Storage ◽  
Triggered Release

We report the design of photo-responsive organic phase change materials that can absorb filtered solar radiation to store both latent heat and photon energy via simultaneous phase transition and photo-isomerization....

Preparation of PVA/PEG Phase Change Composite Nanofibers by Electrospinning

2011 ◽  
Vol 306-307 ◽  
pp. 37-40 ◽  
Author(s):  
Da Hui Sun ◽  
Tian Yu Xu ◽  
Yong Jia Liu ◽  
Mei Zhang
Keyword(s):  
Phase Transition ◽  
Phase Change ◽  
Composite Nanofibers ◽  
Diameter Distribution ◽  
Weight Percentage ◽  
Weight Content ◽  
Reversible Phase Transition ◽  
Change Characteristics ◽  
Micro Morphology ◽  
Reversible Phase

Phase change PVA / PEG composite nanofibers were prepared by electrospinning, micro-morphology of PVA / PEG fibers with different weight content were analyzed, the phase change characteristics were also analyzed. The result showed that well distributed composite nanofibers which composed by PVA/PEG blend solution can be obtained by electrospinning.PVA fibreforming were influenced because of the existence of PEG, including bond, irregular block, small rough, uneven diameter distribution in fibers. PVA/PEG blend solution of 4:6 weight content was well fibreforming compared with other different weight content.The continuity of spinneret flow in electrospinning would directly affected by polymer solution consentrition and viscosity. Further research about which and the influence in fibers diameter and morphology will be explored. Composite nanofibers possessed reversible phase transition characteristics,Tm Essentially unchanged ,Tcwere related to the weight percentage of PEG/PVA, at the same time, the enthalpy will increase along with the gradually increase in weight percentage of PEG.

Synthesis and Study of Microcapsules with Beeswax Core and Phenol-Formaldehyde Shell Using the Taguchi Method

2021 ◽  
Vol 7 (1) ◽  
pp. 1
Author(s):  
Tejashree Amberkar ◽  
Prakash Mahanwar
Keyword(s):  
Phase Transition ◽  
Transition Temperature ◽  
Taguchi Method ◽  
Phase Change ◽  
Phase Change Material ◽  
Surfactant Concentration ◽  
Phenol Formaldehyde ◽  
Processing Parameters ◽  
Agitation Speed ◽  
Change Material

Phenol-formaldehyde shelled phase change material microcapsules (MPCMs) were fabricated and their processing parameters were analyzed with the Taguchi method. Core to shell ratio, surfactant concentration and speed of mixing are the parameters that were optimized in five levels. The optimized values for the surfactant concentration, core to shell ratio and agitation speed were 3%, 1:1 and 800 rpm, respectively. The obtained microcapsules were spherical in shape. The melting enthalpy of the MPCMs synthesized with optimized processing parameters was 148.93 J/g in 35–62 °C. The obtained temperature range of phase transition temperature can be used for storing different food articles such as chocolate and hot served foods.

scholarly journals The Effect of Channel Length on Phase Transition of Phase Change Memory

2018 ◽  
Vol 7 (3.11) ◽  
pp. 25
Author(s):  
M S. A.Aziz ◽  
F H. M.Fauzi ◽  
Z Mohamad ◽  
R I. Alip
Keyword(s):  
Phase Transition ◽  
Silicon Carbide ◽  
Phase Change ◽  
Pulse Width ◽  
Crystalline State ◽  
Phase Change Memory ◽  
Amorphous State ◽  
Channel Length ◽  
Change Memory

The phase transition of germanium antimony tellurium (GST) and the temperature of GST were investigated using COMSOL Multiphysic 5.0 software. Silicon carbide was using as a heater layer in the separate heater structure of PCM. These simulations have a different channel of SiC. The temperature of GST and the phase transition of GST can be obtained from the simulation. From the simulation, the 300 nm channel of SiC can change the GST from amorphous to crystalline state at 0.7V with 100 ns pulse width. The 800 nm channel of SiC can change the GST from amorphous to crystalline state at 1.1V with 100 ns pulse width. Results demonstrated that the channel of SIC can affecting the temperature of GST and the GST changes from amorphous state to crystalline state. As the channel of SiC decreased, the temperature of GST was increased and the GST was change to crystalline state quickly.  

Preparation and properties of shape-stabilized phase change material cellulose benzoate-g-polyoxyethylene (2) hexadecyl ether with potential for thermal energy storage

2018 ◽  
Vol 89 (8) ◽  
pp. 1512-1521
Author(s):  
Na Han ◽  
Wenxin Zhang ◽  
Xiufang Wang ◽  
Xingxiang Zhang ◽  
Wei Li ◽  
...  
Keyword(s):  
Phase Transition ◽  
Energy Storage ◽  
Phase Change ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Solid Phase ◽  
Resonance Spectroscopy ◽  
Thermal Reliability ◽  
Scanning Calorimetry ◽  
Chemical Structures

It is a worldwide challenge to efficiently use renewable resources to solve the current energy shortage. The existing cellulose-based material is incapable of proper power storage. In this study, a series of cellulose benzoate-g-polyoxyethylene (2) hexadecyl ether (CB-g-E2C16) solid–solid phase change materials were synthesized with cellulose as the skeleton and polyoxyethylene (2) hexadecyl ether (E2C16) as a functional side chain. The skeleton cellulose and benzoyl chloride restrict the free movement of the molecular chains of E2C16 above the phase transition temperature, leading to a solid–solid phase change. Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy were performed to investigate the chemical structures. The thermal energy-storage properties, thermal reliability and thermal stability of the CB-g-E2C16 were investigated by differential scanning calorimetry and thermogravimetry (TG) methods. The analysis results indicated that the E2C16 chains were successfully grafted onto the cellulose benzoate (CB) backbone and the copolymers exhibited typical solid–solid phase transition behavior. The enthalpy and degree of substitution of graft copolymers CB-g-E2C16 could be adjusted by changing the feeding ratio of the raw materials, reaction temperature and post-processing methods of CB. TG analysis results showed that the CB-g-E2C16 copolymers possessed good thermostability and they keep their stability up to 278℃. Compared with pure cellulose, CB-g-E2C16 copolymers could be dissolved in dimethyl sulfoxide and most of them could be dissolved in N, N-dimethylformamide.

Preparation and characterization of phase-change energy storage nonwoven fabric

2021 ◽  
pp. 152808372110417
Author(s):  
Zhou Zhao ◽  
Ningning Tong ◽  
Hong Song ◽  
Yan Guo ◽  
Jinmei Wang
Keyword(s):  
Phase Transition ◽  
Thermal Stability ◽  
Energy Storage ◽  
Phase Change ◽  
Nonwoven Fabric ◽  
Scanning Calorimetry ◽  
Change Material ◽  
Stretching Process ◽  
Thermal Stability Of

In this work, a phase-change energy storage nonwoven fabric was made of polyurethane phase-change material (PUPCM) by a non-woven melt-blown machine. Polyethylene glycol 2000 was used as the phase transition unit and diphenyl-methane-diisocyanate as the hard segment to prepare PUPCM. Thermal stability of the PUPCM was evaluated through thermal stability analysis. The performance of pristine PUPCM was determined by Fourier transform infrared spectroscopy and differential scanning calorimetry to analyze the spinning technology of spinning temperature and the stretching process. Phase-change energy storage nonwoven fabric (413.22 g/m2) was prepared, and the morphology, solid–solid exothermic phase transition, mechanical properties, and the structures were characterized. The enthalpy of solid–solid exothermic phase transition reached 60.17 mJ/mg (peaked at 23.14°C). The enthalpy of solid–solid endothermic phase transition reached 67.09 mJ/mg (peaked at 34.34°C). The strength and elongation of phase-change energy storage nonwoven fabric were found suitable for garments and tent fabrics.

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