scholarly journals From long-lived batholith construction to giant porphyry copper deposit formation: petrological and zircon chemical evolution of the Quellaveco District, Southern Peru

2021 ◽  
Vol 176 (2) ◽  
Author(s):  
Chetan L. Nathwani ◽  
Adam T. Simmons ◽  
Simon J. E. Large ◽  
Jamie J. Wilkinson ◽  
Yannick Buret ◽  
...  
Keyword(s):  
High Pressure ◽  
Porphyry Copper ◽  
Marked Change ◽  
Crustal Thickening ◽  
Deposit Formation ◽  
Nazca Plate ◽  
Southern Peru ◽  
Porphyry Cu ◽  
Lower Crustal ◽  
Crustal Magma

AbstractPorphyry Cu ore deposits are a rare product of arc magmatism that often form spatiotemporal clusters in magmatic arcs. The petrogenetic evolution of igneous rocks that cover the temporal window prior to and during porphyry Cu deposit formation may provide critical insights into magmatic processes that are key in generating these systems. This study documents the magmatic evolution of the Palaeocene–Eocene Yarabamba Batholith, Southern Peru, that was incrementally assembled between ~ 67 and ~ 59 Ma and hosts three, nearly contemporaneous, giant porphyry Cu–Mo deposits that formed at 57–54 Ma (Quellaveco, Toquepala and Cuajone). Whole-rock geochemistry, U–Pb geochronology and zircon trace element chemistry are reported from Yarabamba rocks that span the duration of plutonic activity, and from six porphyry intrusions at Quellaveco that bracket mineralisation. A change in whole-rock chemistry in Yarabamba intrusive rocks to high Sr/Y, high La/Yb and high Eu/Eu* is observed at ~ 60 Ma which is broadly coincident with a change in vector of the converging Nazca plate and the onset of regional compression and crustal thickening during the first stage of the Incaic orogeny. The geochemical changes are interpreted to reflect a deepening of the locus of lower crustal magma evolution in which amphibole ± garnet are stabilised as early and abundant fractionating phases and plagioclase is suppressed. Zircons in these rocks show a marked change towards higher Eu/Eu* (> 0.3) and lower Ti (< 9 ppm) compositions after ~ 60 Ma. Numerical modelling of melt Eu systematics and zircon-melt partitioning indicates that the time series of zircon Eu/Eu* in these rocks can be explained by a transition from shallower, plagioclase-dominated fractionation to high-pressure amphibole-dominated fractionation at deep crustal levels from ~ 60 Ma. Our modelling suggests that any redox effects on zircon Eu/Eu* are subordinate compared to changes in melt composition controlled by the fractionating mineral assemblage. We suggest that growth and intermittent recharge of the lower crustal magma reservoir from ~ 60 Ma produced a significant volume of hydrous and metallogenically fertile residual melt which ascended to the upper crust and eventually generated the three giant porphyry Cu–Mo deposits at Quellaveco, Toquepala and Cuajone from ~ 57 Ma. Our study highlights the importance of high-pressure magma differentiation fostered by strongly compressive tectonic regimes in generating world-class porphyry Cu deposits.

Petrological and zircon chemical record of arc magma evolution from long-lived batholith construction to giant porphyry copper deposit formation 

2021 ◽  
Author(s):  
Chetan Nathwani ◽  
Adam Simmons ◽  
Simon Large ◽  
Jamie Wilkinson ◽  
Yannick Buret ◽  
...  
Keyword(s):  
High Pressure ◽  
Porphyry Copper ◽  
Marked Change ◽  
Crustal Thickening ◽  
Magma Evolution ◽  
Deposit Formation ◽  
Nazca Plate ◽  
Porphyry Cu ◽  
Lower Crustal ◽  
Crustal Magma

&lt;p&gt;Porphyry Cu ore deposits are a rare product of arc magmatism that often form spatiotemporal clusters in magmatic arcs. The petrogenetic evolution of igneous rocks that cover the temporal window prior to and during porphyry Cu deposit formation may provide critical insights into magmatic processes that are key in generating these systems. This study documents the magmatic evolution of the Palaeocene-Eocene Yarabamba Batholith, Southern Peru, that was incrementally assembled between ~67 and ~59 Ma and hosts three, nearly contemporaneous, giant porphyry Cu-Mo deposits that formed at 57-54 Ma (Quellaveco, Toquepala and Cuajone). Whole-rock geochemistry, U-Pb geochronology and zircon trace element chemistry are reported from Yarabamba rocks that span the duration of plutonic activity, and from six porphyry intrusions at Quellaveco that bracket mineralisation. A change in whole-rock chemistry in Yarabamba intrusive rocks to high Sr/Y, high La/Yb and high Eu/Eu* is observed at ~60 Ma which is broadly coincident with a change in vector of the converging Nazca plate and the onset of regional compression and crustal thickening during the first stage of the Incaic orogeny. The geochemical changes are interpreted to reflect a deepening of the locus of lower crustal magma evolution in which amphibole &amp;#177; garnet are stabilised as early and abundant fractionating phases and plagioclase is suppressed. Zircons in these rocks show a marked change towards higher Eu/Eu* (&gt;0.3) and lower Ti (&lt;9 ppm) compositions after ~60 Ma. Numerical modelling of melt Eu systematics and zircon-melt partitioning indicates that the time series of zircon Eu/Eu* in these rocks can be explained by a transition from shallower, plagioclase-dominated fractionation to high-pressure amphibole-dominated fractionation at deep crustal levels from ~60 Ma. Our modelling suggests that any redox effects on zircon Eu/Eu* are subordinate compared to changes in melt composition controlled by the fractionating mineral assemblage. We suggest that growth and intermittent recharge of the lower crustal magma reservoir from ~60 Ma produced a significant volume of hydrous and metallogenically fertile residual melt which ascended to the upper crust and eventually generated the three giant porphyry Cu-Mo deposits at Quellaveco, Toquepala and Cuajone from ~57 Ma. Our study highlights the importance of high-pressure magma differentiation fostered by strongly compressive tectonic regimes in generating world-class porphyry Cu deposits.&lt;/p&gt;

Mesozoic Metallogenesis of Peru: A Reality Check on Geodynamic Models

SEG Discovery ◽  
2021 ◽  
pp. 15-24
Author(s):  
Dave Shatwell
Keyword(s):  
Iron Oxide ◽  
Porphyry Copper ◽  
Oceanic Lithosphere ◽  
Ocean Basin ◽  
Gold Deposits ◽  
Late Triassic ◽  
Peruvian Andes ◽  
Southern Peru ◽  
Porphyry Cu ◽  
Back Arc

Abstract The Andean Cordillera is generally regarded as the product of easterly subduction of oceanic lithosphere below South America since the Late Triassic, but recent syntheses have challenged this paradigm. In one model, W-dipping oceanic subduction pulls the continent west until it collides with a ribbon continent that now forms the coastal region and Western Cordillera of the Peruvian Andes. A second model involves westerly oceanic subduction until 120 to 100 Ma, without the involvement of a ribbon continent, to explain deep, subducted slabs revealed by mantle tomographic images. Both assume that “Andean-style” E-dipping subduction did not exist during the Jurassic and Early Cretaceous. Another model, also involving mantle tomography, assumes that a back-arc basin opened inboard of the trench between 145 and 100 Ma, displacing the E-dipping subduction zone offshore without changing its polarity. This article examines the implications of these hypotheses for southern Peruvian metallogenesis during the Mesozoic, when marginal basins opened and closed and were thrust eastward and then were intruded, between 110 and ~50 Ma, by a linear belt of multiple plutons known as the Coastal Batholith. The earliest mineralization in southern Peru is located on the coast and comprises major iron oxide and minor porphyry copper deposits emplaced between 180 and 110 Ma. This was followed by Cu-rich iron oxide copper-gold deposits and a large Zn-rich volcanogenic massive sulfide (VMS) deposit between 115 and 95 Ma, then minor porphyry Cu deposits at ~80 Ma. A second episode of localized VMS mineralization followed at 70 to 68 Ma, then a group of at least five giant porphyry Cu-Mo deposits in southernmost Peru formed between 62 and 53 Ma. The conventional model of Andean-style subduction, which explains many features of Mesozoic Andean metallogenesis in terms of changing plate vectors and velocities, is a poor fit with mantle tomographic anomalies that are thought to record the paleopositions of ancient trenches. A ribbon-continent model requires some plutons of the Coastal Batholith to have been separated from others by an ocean basin. West-dipping oceanic subduction does not account for Jurassic mineralization and magmatism in southern Peru. A model involving a back-arc basin that opened inboard of the existing trench, forcing E-dipping subduction to retreat offshore between 145 and 100 Ma, seems to best explain the metallogenic and tomographic data.

Lineaments Revisited

SEG Discovery ◽  
2000 ◽  
pp. 1-20
Author(s):  
JEREMY P. RICHARDS
Keyword(s):  
Large Scale ◽  
Mineral Exploration ◽  
Porphyry Copper ◽  
Regional Scale ◽  
Tectonic Events ◽  
Magma Reservoirs ◽  
Magma Supply ◽  
Magmatic History ◽  
Lithospheric Stress ◽  
Crustal Magma

ABSTRACT Large-scale crustal lineaments are recognized as corridors (up to 30 km wide) of aligned geological, structural, geomorphological, or geophysical features that are distinct from regional geological trends such as outcrop traces. They are commonly difficult to observe on the ground, the scale of the features and their interrelationships being too large to map except at a regional scale. They are therefore most easily identified from satellite imagery and geophysical (gravity, magnetic) maps. Lineaments are believed to be the surface expressions of ancient, deep-crustal or trans-lithospheric structures, which periodically have been reactivated as planes of weakness during subsequent tectonic events. These planes of weakness, and in particular their intersections, may provide high-permeability channels for ascent of deeply derived magmas and fluids. Optimum conditions for magma penetration are provided when these structures are placed under tension or transtension. In regions of subduction-related magmatism, porphyry copper and related deposits may be generated along these lineaments because the structures serve to focus the ascent of relatively evolved magmas and fluid distillates from deep-crustal magma reservoirs. However, lineament intersections can only focus such activity where a magma supply exists, and when lithospheric stress conditions permit. A comprehensive understanding of regional tectono-magmatic history is therefore required to interpret lineament maps in terms of their prospectivity for mineral exploration.

Crustal velocity structure from SAREX, the Southern Alberta Refraction Experiment

2002 ◽  
Vol 39 (3) ◽  
pp. 351-373 ◽  
Author(s):  
Ron M Clowes ◽  
Michael JA Burianyk ◽  
Andrew R Gorman ◽  
Ernest R Kanasewich
Keyword(s):  
Velocity Structure ◽  
Data Interpretation ◽  
Crustal Thickening ◽  
Tectonic Zone ◽  
Crustal Layer ◽  
Crustal Velocity ◽  
Crustal Velocity Structure ◽  
Southern Alberta ◽  
Magmatic Underplating ◽  
Lower Crustal

Lithoprobe's Southern Alberta Refraction Experiment, SAREX, extends 800 km from east-central Alberta to central Montana. It was designed to investigate crustal velocity structure of the Archean domains underlying the Western Canada Sedimentary Basin. From north to south, SAREX crosses the Loverna domain of the Hearne Province, the Vulcan structure, the Medicine Hat block (previously considered part of the Hearne Province), the Great Falls tectonic zone, and the northern Wyoming Province. Ten shot points along the profile in Canada were recorded on 521 seismographs deployed at 1 km intervals. To extend the line, an additional 140 seismographs were deployed at intervals of 1.25–2.50 km in Montana. Data interpretation used an iterative application of damped least-squares inversion of traveltime picks and forward modeling. Results show different velocity structures for the major blocks (Loverna, Medicine Hat, and Wyoming), indicating that each is distinct. Wavy undulations in the velocity structure of the Loverna block may be associated with internal crustal deformation. The most prominent feature of the model is a thick (10–25 km) lower crustal layer with high velocities (7.5–7.9 km/s) underlying the Medicine Hat and Wyoming blocks. Based on data from lower crustal xenoliths in the region, this layer is interpreted to be the result of Paleoproterozoic magmatic underplating. Crustal thickness varies from 40 km in the north to almost 60 km in the south, where the high-velocity layer is thickest. Uppermost mantle velocities range from 8.05 to 8.2 km/s, with the higher values below the thicker crust. Results from SAREX and other recent studies are synthesized to develop a schematic representation of Archean to Paleoproterozoic tectonic development for the region encompassing the profile. Tectonic processes associated with this development include collisions of continental blocks, subduction, crustal thickening, and magmatic underplating.

Macro- and microstructural analysis of the Zhujiafang ductile shear zone, Hengshan Complex: Tectonic nature and geodynamic implications of the evolution of Trans−North China orogen

2020 ◽  
Author(s):  
Lingchao He ◽  
Jian Zhang ◽  
Guochun Zhao ◽  
Changqing Yin ◽  
Jiahui Qian ◽  
...  
Keyword(s):  
Shear Zone ◽  
North China ◽  
Shear Zones ◽  
Crustal Thickening ◽  
Slip Systems ◽  
High Grade ◽  
Ductile Shear Zone ◽  
Crustal Rocks ◽  
Ductile Shear ◽  
Lower Crustal

In worldwide orogenic belts, crustal-scale ductile shear zones are important tectonic channels along which the orogenic root (i.e., high-grade metamorphic lower-crustal rocks) commonly experienced a relatively quick exhumation or uplift process. However, their tectonic nature and geodynamic processes are poorly constrained. In the Trans−North China orogen, the crustal-scale Zhujiafang ductile shear zone represents a major tectonic boundary separating the upper and lower crusts of the orogen. Its tectonic nature, structural features, and timing provide vital information into understanding this issue. Detailed field observations showed that the Zhujiafang ductile shear zone experienced polyphase deformation. Variable macro- and microscopic kinematic indicators are extensively preserved in the highly sheared tonalite-trondhjemite-granodiorite (TTG) and supracrustal rock assemblages and indicate an obvious dextral strike-slip and dip-slip sense of shear. Electron backscattered diffraction (EBSD) was utilized to further determine the crystallographic preferred orientation (CPO) of typical rock-forming minerals, including hornblende, quartz, and feldspar. EBSD results indicate that the hornblendes are characterized by (100) &lt;001&gt; and (110) &lt;001&gt; slip systems, whereas quartz grains are dominated by prism &lt;a&gt; and prism &lt;c&gt; slip systems, suggesting an approximate shear condition of 650−700 °C. This result is consistent with traditional thermobarometry pressure-temperature calculations implemented on the same mineral assemblages. Combined with previously reported metamorphic data in the Trans−North China orogen, we suggest that the Zhujiafang supracrustal rocks were initially buried down to ∼30 km depth, where high differential stress triggered the large-scale ductile shear between the upper and lower crusts. The high-grade lower-crustal rocks were consequently exhumed upwards along the shear zone, synchronous with extensive isothermal decompression metamorphism. The timing of peak collision-related crustal thickening was further constrained by the ca. 1930 Ma metamorphic zircon ages, whereas a subsequent exhumation event was manifested by ca. 1860 Ma syntectonic granitic veins and the available Ar-Ar ages of the region. The Zhujiafang ductile shear zone thus essentially record an integrated geodynamic process of initial collision, crustal thickening, and exhumation involved in formation of the Trans−North China orogen at 1.9−1.8 Ga.

scholarly journals Geological and Chronological Constraints on the Long-Lived Eocene Yulong Porphyry Cu-Mo Deposit, Eastern Tibet: Implications for the Lifespan of Giant Porphyry Cu Deposits

2017 ◽  
Vol 112 (7) ◽  
pp. 1719-1746 ◽  
Author(s):  
Jia Chang ◽  
Jian-Wei Li ◽  
David Selby ◽  
Jia-Cheng Liu ◽  
Xiao-Dong Deng
Keyword(s):  
Early Stage ◽  
Porphyry Copper ◽  
Copper Deposit ◽  
Granite Porphyry ◽  
Radiometric Dating ◽  
Time Interval ◽  
Porphyry Cu ◽  
Economic Significance ◽  
Vein Formation ◽  
Porphyry Cu Deposit

Abstract The Yulong porphyry Cu-Mo deposit, the third largest porphyry Cu deposit in China, contains proven reserves of > 6.5 million metric tons (Mt) Cu and 0.4 Mt Mo. Previous radiometric dating studies have provided numerous ages for this deposit, but the timing and duration of the process governing the deposition of Cu and Mo remains not well constrained. In this paper, we first document multiple stages of mineralization and hydrothermal alteration associated with distinct magmatic pulses at Yulong by field and textural relationships, and then present high-precision molybdenite Re-Os ages of 14 quartz-molybdenite ± chalcopyrite veins representing these stages to precisely constrain the timing and duration of Cu-Mo mineralization. The ore-hosting Yulong composite stock consists of three successive porphyry intrusions: (1) monzonitic granite porphyry (MGP), (2) K-feldspar granite porphyry (KGP), and (3) quartz albite porphyry (QAP). The vein formation, Cu-Mo mineralization, and ore-related alteration are grouped into early, transitional, and late stages with respect to the intrusive history. The first two porphyry intrusions are followed by cyclical sequences of veining that are mainly associated with potassic alteration and have formed (1) ME vein/USTT, (2) EBE/T veins, (3) A1E/T veins, (4) A2E/BT veins, and (5) A3E/T veins. A2E/BT and A3E/T veins of the early and transitional stages are dominated by quartz and chalcopyrite ± pyrite, respectively, and represent the main Cu-Mo mineralization events. More than 80% of Cu and Mo at Yulong were deposited in the early stage with the remainder being formed in the transitional stage. The late-stage pyrite-quartz veins (DL), which are characterized by sericitic alteration halos, postdate the intrusion of QAP dikes and have no economic significance. Molybdenite Re-Os ages of A2E and BT veins indicate that sulfide deposition at Yulong was episodic over a prolonged history lasting over 5.13 ± 0.23 m.y. (1σ). However, the bulk Cu-Mo ores formed in a shorter time interval of 1.36 ± 0.24 m.y. (1σ) with most Cu precipitated in a more restricted timespan of 0.82 ± 0.24 m.y. (1σ) in the early stage. These results, combined with geochronologic data from porphyry copper deposits elsewhere, confirm that multiple magmatic-hydrothermal pulses with a lifespan of tens to hundreds of thousands of years are sufficient to form a giant porphyry copper deposit. Factors such as metal concentration, volume, and focusing efficiency of ore-forming fluids could have played important roles in producing a giant porphyry Cu deposit regardless of a short- or long-lived magmatic-hydrothermal system.

scholarly journals Elevated magma fluxes deliver high-Cu magmas to the upper crust

Geology ◽  
2020 ◽  
Vol 48 (10) ◽  
pp. 957-960
Author(s):  
Daniel Cox ◽  
Sebastian F.L. Watt ◽  
Frances E. Jenner ◽  
Alan R. Hastie ◽  
Samantha J. Hammond ◽  
...  
Keyword(s):  
Small Proportion ◽  
Ore Deposits ◽  
Crustal Evolution ◽  
Upper Crust ◽  
Convergent Margins ◽  
Ore Genesis ◽  
Porphyry Cu ◽  
Show Evidence ◽  
Lower Crustal ◽  
Garnet Fractionation

Abstract Porphyry Cu-Au ore deposits are globally associated with convergent margins. However, controls on the processing and distribution of the chalcophile elements (e.g., Cu) during convergent margin magmatism remain disputed. Here, we show that magmas feeding many Chilean stratovolcanoes fractionate sulfides with a high-Cu/Ag ratio early in their crustal evolution. These magmas show evidence of lower-crustal garnet and amphibole crystallization, and their degree of sulfide fractionation and Cu depletion increase with both crustal thickness and the extent of garnet fractionation. However, samples from a small proportion of volcanoes with elevated eruptive fluxes depart from this Cu-depleting trend, instead erupting Cu-rich magmas. This implies that at these atypical sites, elevated magma productivity and crustal throughput, potentially facilitated by “pathways” exploiting major crustal fault systems, enable rapid magma transit, avoiding lower-crustal Cu-depleting sulfide fractionation and potentially playing an important role in porphyry ore genesis.

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