scholarly journals Chronos - take the pulse of our galactic neighbourhood

Author(s):  
Eric Michel ◽  
Misha Haywood ◽  
Benoit Famaey ◽  
Benoit Mosser ◽  
Reza Samadi ◽  
...  

AbstractUnderstanding our Galaxy’s structure, formation, and evolution will, over the next decades, continue to benefit from the wonderful large survey by Gaia, for astrometric, kinematic, and spectroscopic characterization, and by large spectroscopic surveys for chemical characterization. The weak link for full exploitation of these data is age characterization, and stellar age estimation relies predominantly on mass estimates. The ideas presented in this White Paper shows that a seismology survey is the way out of this situation and a natural complement to existing and planned surveys. These ideas are strongly rooted in the past decade’s experience of the so-called Seismology revolution, initiated with CoRoT and Kepler. The case of red giant stars is used here as the best current illustration of what we can expect from seismology for large samples, but premises for similar developments exist in various other classes of stars covering other ranges of age or mass. Whatever the star considered, the first information provided by stellar pulsations is always related to the mean density and thus to the mass (and age). In order to satisfy the need for long-duration and all-sky coverage, we rely on a new instrumental concept which decouples integration time and sampling time. We thus propose a long (~1 year) all-sky survey which would perfectly fit between TESS, PLATO, and the Rubin Observatory (previously known as LSST) surveys to offer a time domain complement to the current and planned astrometric and spectroscopic surveys. The fine characterization of host stars is also a key aspect for the interpretation and exploitation of the various projects -- anticipated in the framework of the Voyage 2050 programme -- searching for atmospheric characterization of terrestrial planets or, more specifically, looking for a signature of life, in distant planets.

Author(s):  
Marta Siczek ◽  
Marcin Zawadzki ◽  
Miłosz Siczek ◽  
Agnieszka Chłopaś-Konowałek ◽  
Paweł Szpot

Abstract Purpose The aim of the study was to present the spectroscopic characteristics and crystal structure of the etazene—a benzimidazole opioid, which appeared on the illegal drug market in Poland in the last weeks. Methods The title compound was analyzed by X-ray crystallography as well as gas and liquid chromatography combined with mass spectrometry. Spectroscopic techniques have also been used, such as nuclear magnetic resonance, infrared and ultraviolet-visible spectroscopies. Results We presented the identification and the broad chemical characterization of etazene, a synthetic opioid that has recently been introduced on the illegal drug market. Conclusions In this paper, we described single-crystal X-ray, chromatographic and spectroscopic characterization of a synthetic opioid that emerged on the new psychoactive substance (NPS) market in Poland. To the best of our knowledge, this is the first full characterization of etazene. Analytical data presented in the work can be helpful in identification and detection of the NPS in forensic and clinical laboratories.


2017 ◽  
Vol 12 (S330) ◽  
pp. 283-284
Author(s):  
Renata Ženovienė ◽  
Vilius Bagdonas ◽  
Arnas Drazdauskas ◽  
Rimvydas Janulis ◽  
Lukas Klebonas ◽  
...  

AbstractThe ESA-PLATO 2.0 mission will perform an in-depth analysis of the large part of the sky-sphere searching for extraterrestrial telluric-like planets. At the Molėtai Astronomical Observatory of Vilnius University, we started a spectroscopic and photometric survey of the northern sky fields that potentially will be targeted by the PLATO mission. We aim to contribute in developing the PLATO input catalogue by delivering a long-duration stellar variability information and a full spectroscopic characterization of brightest targets. First results of this survey are overviewed.


2012 ◽  
Vol 5 (7) ◽  
pp. 1753-1760 ◽  
Author(s):  
D. Scharffe ◽  
F. Slemr ◽  
C. A. M. Brenninkmeijer ◽  
A. Zahn

Abstract. Goal of the project CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrumented Container) is to carry out regular and detailed observations of atmospheric composition (particles and gases) at cruising altitudes of passenger aircraft, i.e. at 9–12 km. Continuous, fast measurement of CO is indispensable for the chemical characterization of encountered air masses, for the detection of plumes of polluted air and for studying troposphere-stratosphere transport. CO is measured by a commercial resonance fluorescence UV instrument modified for the use onboard passenger aircraft. Modifications were necessary to optimize the instrument reliability allowing unattended operation for several days. The instrument has a precision of 1–2 ppbv at an integration time of 1 s. The response time to reach 63.2% signal strength is 2 s. We describe the modifications of the instrument, the experiences made during its operation since December 2004, the quality control of CO measurements onboard CARIBIC, and suggest a regular service routine that guarantees long-term high-quality data.


Clay Minerals ◽  
2019 ◽  
Vol 54 (3) ◽  
pp. 245-254
Author(s):  
Mathilde Poirier ◽  
Jean-Eudes Boulingui ◽  
François Martin ◽  
Michel Mbina Mounguengui ◽  
Charles Nkoumbou ◽  
...  

AbstractThis research aims to characterize the mineralogical and crystal-chemical purity of two samples of natural talc (BTT6, BTT7) from the occurrence ‘Ecole1’ in the deposit of Minzanzala, southwest Gabon. X-ray diffraction and modal-composition calculations demonstrated the presence of quartz and Al–Fe-bearing phases (kaolinite and/or chlorite and/or Al–Fe oxyhydroxides) as accessory minerals in both ores. In contrast, the chemical and spectroscopic characterization of the talc component revealed remarkable chemical purity expressed by very low Fe contents. According to these results, the talc of Minzanzala might be used as a filler in a wide range of industrial applications, such as in cosmetics, paints, polymers or ceramics.


2019 ◽  
Vol 82 ◽  
pp. 225-232
Author(s):  
C. Gehan ◽  
B. Mosser ◽  
E. Michel

Red giant stars present mixed modes, which behave as pressure modes in the convective envelope and as gravity modes in the radiative interior. This mixed character allows to probe the physical conditions in their core. With the advent of long-duration time series from space-borne missions such as CoRoT and Kepler, it becomes possible to study the red giant core rotation. As more than 15 000 red giant light curves have been recorded, it is crucial to develop a robust and efficient method to measure this rotation. Such measurements of thousands of mean core rotation would open the way to a deeper understanding of the physical mechanisms that are able to transport angular momentum from the core to the envelope in red giants. In this work, we detail the principle of the method we developed to obtain automatic measurements of the red giant mean core rotation. This method is based on the stretching of the oscillation spectra and on the use of the so-called Hough transform. We finally validate this method for stars on the red giant branch, where overlapping rotational splittings and mixed-mode spacings produce complicated frequency spectra.


2012 ◽  
Vol 5 (2) ◽  
pp. 2681-2702 ◽  
Author(s):  
D. Scharffe ◽  
F. Slemr ◽  
C. A. M. Brenninkmejer ◽  
A. Zahn

Abstract. Goal of the project CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrumented Container) is to carry out regular and detailed observations of atmospheric composition (particles and gases) at cruising altitudes of passenger aircraft, i.e., at 9–12 km. Continuous, fast measurement of CO is indispensable for the chemical characterization of encountered air masses, for the detection of plumes of polluted air and for studying troposphere-stratosphere transport. CO is measured by a commercial resonance fluorescence UV instrument modified for the use onboard passenger aircraft. Modifications were necessary to optimize the instrument reliability allowing unattended operation for several days. The instrument has a precision of 1–2 ppbv at an integration time of 1 s. The response time to reach 66.6% signal strength is 2 s. We describe the modifications of the instrument, the experiences made during its operation since December 2004, the quality control of CO measurements onboard CARIBIC, and suggest a regular service routine that guarantees long-term high-quality data.


2014 ◽  
Vol 875-877 ◽  
pp. 1576-1580 ◽  
Author(s):  
Chao Wang ◽  
Chang Geun Yoo ◽  
Chen Xu Yu ◽  
Tae Hyun Kim

The most expensive and principal step in the process of converting cellulosic biomass into biorenewables and biofuel is the pretreatment during which lignin and cellulose crystalline structure is broken down. In this study, TiO2nanoparticles were utilized as photocatalyst in addition to alkaline (ammonia and sodium hydrate) treatment of corn stover biomass to improve delignification ability and reduce the energy and chemical loadings to make the process more environmentally friendly. Raman Spectroscopic imaging, as an accurate and rapid chemical characterization method, was utilized to investigate the molecular compositional and structural changes occurring during the pretreatment process in the corn stover biomass qualitatively. Lignin characteristic peaks at 1,600, 1,620 and 1,690 cm-1as well as cellulose characteristic peaks at 1,059 and 2,888 cm-1were identified through Raman Spectroscopic measurement as indicators of the effects of the pretreatment. Real-time quantitative analysis of these functional peaks revealed the molecular structural changes during delignification, potentially may lead to optimization of the processing parameters to reduce the processing cost in the future.


Crystals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 553
Author(s):  
Sabrine Hermi ◽  
Mohammed G. Althobaiti ◽  
Abdullah A. Alotaibi ◽  
Abdulhadi H. Almarri ◽  
Wataru Fujita ◽  
...  

The chemical preparation, crystal structure, Hirshfeld surface analysis and spectroscopic characterization of the novel cadmium (II) 2,5-dichloro-p-phenylendiaminium decachlorotricadmate(II) hexahydrate complex, (C6H8Cl2N2)2[Cd3Cl10]·6H2O, has been reported. The atomic arrangement can be described as built up by an anionic framework, formed by edge-sharing [CdCl6]2− octahedra in linear polymeric chains spreading along the a-axis, while the organic cations surround these latters. The inspection of the Hirshfeld surface analysis helps to discuss the strength of hydrogen bonds and to quantify the inter-contacts, which reveal that H…Cl/Cl…H (38.9%), H…H (13.9%), and Cd…Cl/Cl…Cd (12.4%) are the main interactions that govern the crystal packing of the studied structure. SEM/EDXwas carried out and the powder XRD confirmed the good crystallinity of the material. FT-IR and the DFT calculation reveal the good correlation between the experimental and the theoretical wavenumbers. The HOMO-LUMO energy gap was used to predict the electric conductivity of the compound. Finally, the thermal TGA/DTA analysis shows stability until 380 K.


2020 ◽  
Author(s):  
Sulaiman C T ◽  
Deepak M ◽  
Madhavankutty T S ◽  
Anandan E M ◽  
Indira Balachandran

Abstract Background: Severe acute respiratory syndrome coronavirus-2, the causative agent of coronavirus disease 2019 (COVID-19) is the global health crisis. There are no existing solutions to COVID 19 as yet. Ayush Kwath Churnam (AKC) is an Ayurvedic medicine promoted by Ministry of AYUSH, Government of India for the enhancement of body immunity in Covid-19 scenario and promoted many AYUSH clinics all over the country with an aim of enhancing immunity of the people to resist SARS Cov-2.Methods: In this study, chemical evaluation of AKC has been done by High Performance Thin Layer Chromatography (HPTLC) and Liquid Chromatography Mass Spectroscopic (LC-MS) analysis. Chemical characterization of AKC was carried out by Electro Spray chemical Ionization (ESI) in both positive and negative mode using Quadrupole Time-of-Flight (Q-TOF) mass spectroscopy. Results: Data processing of molecular ions obtained by mass fragmentation led to the identification of several phytoconstituents belonging to various classes of compounds such as alkaloids, phenolics, flavonoids and isoflavones. Conclusion: The study concluded that AKC contains variety of phytochemicals with numerous biological properties like immunomodulatory, anti-inflammatory and antioxidant activities.


2018 ◽  
Vol 616 ◽  
pp. A94 ◽  
Author(s):  
M. Vrard ◽  
T. Kallinger ◽  
B. Mosser ◽  
C. Barban ◽  
F. Baudin ◽  
...  

Context. The space-borne missions CoRoT and Kepler have provided photometric observations of unprecedented quality. The study of solar-like oscillations observed in red giant stars by these satellites allows a better understanding of the different physical processes occurring in their interiors. In particular, the study of the mode excitation and damping is a promising way to improve our understanding of stellar physics that has, so far, been performed only on a limited number of targets. Aims. The recent asteroseismic characterization of the evolutionary status for a large number of red giants allows us to study the physical processes acting in the interior of red giants and how they are modified during stellar evolution. In this work, we aim to obtain information on the excitation and damping of pressure modes through the measurement of the stars’ pressure mode widths and amplitudes and to analyze how they are modified with stellar evolution. The objective is to bring observational constraints on the modeling of the physical processes behind mode excitation and damping. Methods. We fit the frequency spectra of red giants with well-defined evolutionary status using Lorentzian functions to derive the pressure mode widths and amplitudes. To strengthen our conclusions, we used two different fitting techniques. Results. Pressure mode widths and amplitudes were determined for more than 5000 red giants. With a stellar sample two orders of magnitude larger than previous results, we confirmed that the mode width depends on stellar evolution and varies with stellar effective temperature. In addition, we discovered that the mode width depends on stellar mass. We also confirmed observationally the influence of the stellar metallicity on the mode amplitudes, as predicted by models.


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