Crystalline glaze is a kind of art glaze with excellent decorative performance, the existing crystalline glaze mainly willemite crystalline glaze, systems on a single track. In this paper, the use of crystalline glaze raw materials for glass, ZnO and coke gemstones, CuO as coloring agents, using ortho- gonal to determine the formula, this paper researched that added TiO2 to the willemite crystalline glaze crystal phase composition as well as the amount of TiO2 and processing conditions on the preparation of crystalline glaze crystal flower morphology impact. The results show that under the conditions of 1250°C melting 1130°C crystallization process crystal spontaneous growth in crystalline glaze can be able to cover the entire glazed, shape of crystals was feathered, cross growth, the number of crystal increased with crystallization temperature, glaze was smooth and shiny sense. XRD and optical microscopy analysis showed that the precipitation of crystals was the long column of rutile, crystal distributed equality, under a polarizing microscope in purple, green and black, with strong aesthetic values.