Kinetic Study on Oxirane Cleavage of Epoxidized Palm Oil

2010 ◽  
Vol 88 (4) ◽  
pp. 517-521 ◽  
Author(s):  
Ruihua Guo ◽  
Chuanguo Ma ◽  
Shangde Sun ◽  
Yuxiang Ma
Keyword(s):  
Kinetic Study ◽  
Palm Oil ◽  
Epoxidized Palm Oil ◽  
Oxirane Cleavage

CATALYTIC CRACKING OF PALM OIL: KINETIC STUDY

Clean Air ◽  
2007 ◽  
Vol 8 (1) ◽  
pp. 65-79 ◽  
Author(s):  
Farouq Twaiq ◽  
Abdul Rahman Mohamed ◽  
Subhash Bhatia
Keyword(s):  
Kinetic Study ◽  
Palm Oil ◽  
Catalytic Cracking

Influence of N-Phenyl-p-Phenylenediamine Modified Epoxidized Palm Oil on Properties of Carbon Black Filled Natural Rubber Compound and Vulcanizate

2013 ◽  
Vol 844 ◽  
pp. 239-242 ◽  
Author(s):  
Supaporn Ieadsang ◽  
Anoma Thitithammawong ◽  
Charoen Nakason ◽  
Azizon Kaesaman
Keyword(s):  
Carbon Black ◽  
Natural Rubber ◽  
Palm Oil ◽  
Morphological Properties ◽  
Rubber Compound ◽  
Mixing Energy ◽  
Epoxidized Palm Oil ◽  
Curing Characteristics ◽  
Polycyclic Aromatic ◽  
Ft Ir

Modified epoxidized palm oil (pA-m-EPO) was prepared by a reaction of epoxidized palm oil (EPO) with n-phenyl-p-phenylenediamine. Chemical structure of the pA-m-EPO was characterized by using FT-IR spectrophotometer. Influence of the pA-m-EPO on bound rubber content, total mixing energy, Mooney viscosity and curing characteristics of carbon black filled natural rubber compound together with mechanical and morphological properties of carbon black filled natural rubber vulcanizates was later studied. Results showed that the NR compound and vulcanizate with using the pA-m-EPO gave inferior properties than those of using the aromatic oil. However, they provided better properties than those of the treated distillate aromatic extract (TDAE) excepting filler dispersion. Furthermore, the pA-m-EPO can be claimed as non-carcinogenic processing oil with low polycyclic aromatic hydrocarbons.

scholarly journals Kinetic study of the quenching reaction of singlet oxygen by α-, β-, γ-, δ-tocotrienols, and palm oil and soybean extracts in solution

2014 ◽  
Vol 78 (12) ◽  
pp. 2089-2101 ◽  
Author(s):  
Kazuo Mukai ◽  
Eri Ishikawa ◽  
Aya Ouchi ◽  
Shin-ichi Nagaoka ◽  
Tomomi Suzuki ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Kinetic Study ◽  
Palm Oil

Curing and Mechanical Properties of Bio-Based Hybrid Thermoset Resins from Unsaturated Polyester and Acrylated Epoxidized Palm Oil

2015 ◽  
Vol 1113 ◽  
pp. 23-27 ◽  
Author(s):  
Alireza Fakhari ◽  
Abdul Razak Rahmat ◽  
Mat Uzir Wahit ◽  
Amirali Khalili ◽  
Zyad Salem Alsagayar
Keyword(s):  
Mechanical Properties ◽  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Hybrid Systems ◽  
Palm Oil ◽  
Unsaturated Polyester ◽  
Thermoset Resins ◽  
Epoxidized Palm Oil ◽  
Flexural Tests ◽  
Scanning Electron

In this study a series of green thermoset resins have been produced from blending acrylated epoxidized palm oil (AEPO) and unsaturated polyester (UPE). The UPE/AEPO ratio was changed between 90/10 and 70/30 wt%. The curing behavior and morphology of hybrid systems were investigated by differential scanning calorimeter (DSC) and Scanning electron microscope (SEM). Moreover, studies on mechanical properties were performed by tensile and flexural tests. The results revealed that, these green thermoset resins exhibit thermo mechanical properties comparable to those of commercial unsaturated polyesters.

Epoxidation of Palm Oil Catalyzed by Titanium-Grafted Silica Catalyst

2013 ◽  
Vol 812 ◽  
pp. 30-37 ◽  
Author(s):  
Syed Ismail Sharifah Nafisah ◽  
Ahmad Faiza Mohd ◽  
Mohamed Rahmah ◽  
Yhaya Firdaus ◽  
Fauzi Roslinda ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Palm Oil ◽  
Batch Reactor ◽  
Sol Gel ◽  
Silica Content ◽  
Nmr Spectrum ◽  
Epoxidized Palm Oil ◽  
Epoxidation Reaction ◽  
Epoxy Groups ◽  
Scanning Electron

Epoxidation reaction is an important reaction in organic synthesis because the formed epoxides are intermediates that can be converted to a variety of products. Catalytic palm oil epoxidation using titanium-grafted silica, hydrogen peroxide, and peroxoformic acid was carried out at 60 °C in a fixed batch reactor. Titanium-grafted silica with different percentages of silica content was prepared through sol-gel hydrolysis and was utilized in epoxidation of palm oil. Titanium-grafted silica particles and Epoxidized palm oil were characterized by techniques such as Fourier Transform Infrared Spectroscopy (FTIR), Field Emission Scanning Electron Microscope (FESEM) and Nuclear Magnetic Resonance (NMR). The TiOSi bonds were detected at 960 cm-1in Ti-Si 0.5 and exhibited highest yield of epoxidized palm oil (EPO) in the epoxidation process which is 84% conversion of unsaturation in palm oil to epoxy groups. New peaks observed in the range of δ 2.4 ppm to 3.6 ppm in the NMR spectrum of EPO belong to protons of the epoxy cyclic ring group, CH-O-CH confirming successful epoxidation of palm oil using the prepared catalyst.

Effect of Epoxidized Palm Oil Loading on the Swelling and Mechanical Properties of SBR Vulcanizates

2013 ◽  
Vol 812 ◽  
pp. 236-240
Author(s):  
Mohd Zaki Nurul Ayunie ◽  
Ahmad Zafir Romli ◽  
M.A. Wahab ◽  
Mohd Hanafiah Abidin
Keyword(s):  
Tensile Strength ◽  
Carbon Black ◽  
Palm Oil ◽  
Crosslink Density ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Elongation At Break ◽  
Epoxidized Palm Oil ◽  
Opposite Trend ◽  
Styrene Butadiene

The effects of epoxidized palm oil (EPO) content in carbon black filled styrene butadiene rubber (SBR) on tensile strength, elongation at break and crosslink density were investigated. Five different loadings of EPO in parts per hundred rubbers (phr) were used to test the tensile strength of the carbon black filled SBR which showed a decreasing trend as the content of EPO in the vulcanizates increased. In contrast, elongation at break showed the opposite trend where the elongation at break increased as the content of the EPO increased. The SBR vulcanizates with the highest content of EPO gave the highest value of elongation at break which is 2393.56%. In the case of swelling index, it was found to increase as the amount of EPO increased.

Properties of epoxidized palm oil plasticized polytlactic acid

2010 ◽  
Vol 45 (7) ◽  
pp. 1942-1946 ◽  
Author(s):  
Emad A. Jaffar Al-Mulla ◽  
Wan Md. Zin Wan Yunus ◽  
Nor Azowa Bt Ibrahim ◽  
Mohd Zaki Ab. Rahman
Keyword(s):  
Palm Oil ◽  
Epoxidized Palm Oil
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