scholarly journals Heavy metals pollution indexing, geospatial and statistical approaches of groundwater within Challawa and Sharada industrial areas, Kano City, North-Western Nigeria

2021 ◽  
Vol 3 (7) ◽  
Author(s):  
Hassan Hamidu ◽  
Falalu B. Halilu ◽  
Kwaya M. Yerima ◽  
Lawal M. Garba ◽  
Arabi A. Suleiman ◽  
...  

Abstract The present study focused on pollution status of groundwater in the industrial areas of Challawa and Sharada in Kano city based on pollution indices, statistical and spatial analyses. Twenty groundwater samples representing groundwater of the studied areas (Ten from each area) were analyzed for the presence of Cd, Cr, Ni, Fe, Mn and Zn using atomic absorption spectrophotometer. The result showed 95%, 5%, 60%, 15% and 25% of the analyzed water samples had detectable Cd, Cr, Ni, Fe, and Mn above the drinking water limits of both Nigerian standards for drinking water quality NSDWQ and World Health Organization (WHO) with Cd dominating other analyzed heavy metals in the groundwater. Evaluation of heavy metal pollution revealed a low polluted status based on the contaminant index (Cd), synthetic pollution index, heavy metals evaluation index, and heavy metal pollution index. Metal index categorized the groundwater as seriously polluted. The statistical evaluation gave strong and positive correlations between indices and a moderate one between the metallic ions. Component analysis revealed a strongly positive loading of Fe, Ni and Zn while Cd had a strong negative loading. Cr and Mn were positive and moderately loaded. Statistical analyses suggested both anthropogenic and geogenic sources for the heavy metals mainly from the industrial and agricultural practices and rock weathering processes, respectively. This study is expected to be a useful tool in the planning, monitoring and mitigation of pollution activities in the area. Article Highlights The pollution status of groundwater with respect to heavy metals was investigated in the Challawa and Sharada industrials zones in Kano city Nigeria The concentration of Cd, Fe, Ni, Cr Mn and Zn was determined using the AAS Different Pollution indices of HPI, HEI, SPI, Cd and MI were utilized to categorized the area as low, medium and highly polluted. Spatial and temporal distribution maps demarcated based on the metal concentrations and computed indices in the area. CA, PCA, and HCA were used to identified the geochemistry, relationship, sources and origin of heavy metals in groundwater. The study revealed zones with low to high-risk groundwater in terms of toxic heavy metals and pollution status.

Author(s):  
Josephine Ndjama George Mafany ◽  
Biram Eric Belmond Yvette Clarisse Mfopou Mewouo ◽  
Carine Tarkang Amina Aboubakar ◽  
Opportune Léonelle Apohkeng Dongmo Armel Zacharie Ekoa Bessa

An integrated pollution assessment index approach was used to assess the application of heavy metal pollution indices in the Ngoua watershed in southwestern (SW) Cameroon. The concentrations of Pb, Cr, Cu, Ni, Zn, Mo, Fe and Al in most of the water samples exceeded the maximum allowable concentration recommended by the World Health Organization (WHO). The Heavy Metal Evaluation Index (HEI) shows strong correlations with the Heavy Metal Pollution Index (HPI), Metal Index (MI) and the degree of contamination (Cd), and gives a better assessment of the pollution levels. Selected samples from the 10 sampling stations were classified as high polluted in Cd, MI and HPI in relation to the respective critical values. These values show comparable results to those of the HEI and indicate that about 88% of the samples with above average values were classified as highly contaminated and the remaining samples (12%) with below average values were classified as moderately contaminated. The Enrichment Factor (EF) analysis and the pollution indices reveal that the water quality is mainly controlled by natural and geogenic processes with major anthropogenic input. The current level of heavy metal distribution in the water of the Ngoua catchment is an environmental and health concern and requires special attention.


2017 ◽  
Vol 14 (3-4) ◽  
Author(s):  
Nusreta Djonlagic

In this study the results of a 15-year long monitoring survey on heavy metals in water at Lake Modrac were assessed using pollution indices of heavy metals, such as Heavy metal pollution index HPI, Heavy metal evaluation index HEI and the Degree of contamination CD. The results of the survey on heavy metal pollution of sediment conducted in 2015 were used as input data for the following pollution indices: Concentration factor , Pollution load index PLI, Enrichment factor EF, Index of geo-accumulation Igeo, Ecological risk factor , Potential ecological risk index to the water-body, RI. The results showed a good correlation and the lake sediment was characterized as polluted. Enrichment factors and indices of geo-accumulation of heavy metals were indicated as very high enriched in the sediment, and have been identified as an anthropogenic source of pollution. Cumulative presence in the sediment is assessed through the pollution index, RI, and has been assessed as moderate ecological risk to the lake water-body. The application of pollution indices presents a valuable tool in assessing the long-term pollution status of Lake Modrac.


2021 ◽  
Vol 16 (7) ◽  
pp. 1349-1357
Author(s):  
Majeed Mattar Ramal ◽  
Arkan Dhari Jalal ◽  
Uday Hatem Abdulhameed

This study goals to assess the concentrations of specified Heavy Metals (HMs) and quality of taps drinking water of Ramadi city, western Iraq. Heavy Metal Pollution Indices like heavy metal pollution index (HMPI ), heavy metal evaluation index (HMEI) and contamination degree (CD) were applied to assess the supplied water. The average concentrations of Lead (Pb), Nickel (Ni), Chromium (Cr), Arsenic (As) and Cadmium (Cd) in most stations exceed the maximum admissible concentration, while Iron (Fe) in most of stations was within the maximum admissible concentration according to local and global guidelines. (HMPI ) values of most stations were exceed the maximum critical value of 100. (HMEI) values of most stations were exceed the value of 10 recommended for drinking water. (CD) values of most stations were exceed the value of 1 recommended for drinking water. The pollution origins were assessed using principal component analysis (PCA) and clustering analysis (CA). The results indicate that contamination comes from anthropogenic causes being the most common and lithogenic sources being the least common. The present concentration of (HMs) in taps water is causing health and environmental problems, water with high (HMs) concentrations would need to be treated before being supplied to consumers.


Water ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 1801
Author(s):  
Valentina Andreea Calmuc ◽  
Madalina Calmuc ◽  
Maxim Arseni ◽  
Catalina Maria Topa ◽  
Mihaela Timofti ◽  
...  

It is a well–known fact that heavy metal pollution in sediments causes serious problems not only in the Danube basin, but also in the large and small adjacent river streams. A suitable method for assessing the level of heavy metals and their toxicity in sediments is the calculation of pollution indices. The present research aims to assess heavy metal pollution in the Lower Danube surface sediments collected along the Danube course (between 180 and 60 km) up to the point where the Danube River flows into the Danube Delta Biosphere Reserve (a United Nations Educational, Scientific and Cultural Organization – UNESCO, protected area). In addition, this monitored area is one of the largest European hydrographic basins. Five heavy metals (Cd, Ni, Zn, Pb, Cu) were analyzed in two different seasons, i.e., the autumn of 2018 and the spring of 2019, using the Inductively Coupled Plasma Mass Spectrometry (ICP– MS) technique. Our assessment of heavy metal pollution revealed two correlated aspects: 1. a determination of the potential risks of heavy metals in sediments by calculating the Potential Ecological Risk Index (RI), and 2. an evaluation of the influence of anthropogenic activities on the level of heavy metal contamination in the surface sediments, using three specific pollution indices, namely, the Geo–Accumulation Index (Igeo), the Contamination Factor (CF), and the Pollution Load Index (PLI). The results of this pioneering research activity in the region highlighted the presence of moderate metal (Ni and Cd) pollution and a low potential ecological risk for the aquatic environment.


PeerJ ◽  
2021 ◽  
Vol 9 ◽  
pp. e11853
Author(s):  
Xingyong Zhang ◽  
Qixin Wu ◽  
Shilin Gao ◽  
Zhuhong Wang ◽  
Shouyang He

Heavy metals are released into the water system through various natural processes and anthropogenic activities, thus indirectly or directly endangering human health. The distribution, source, water quality and health risk assessment of dissolved heavy metals (V, Mn, Fe, Co, Ni, Zn, As, Mo, Sb) in major rivers in Wuhan were analyzed by correlation analysis (CA), principal component analysis (PCA), heavy metal pollution index (HPI), hazard index (HI) and carcinogenic risk (CR). The results showed that the spatial variability of heavy metal contents was pronounced. PCA and CA results indicated that natural sources controlled Mn, Fe, Co, Ni and Mo, and industrial emissions were the dominant factor for V, Zn and Sb, while As was mainly from the mixed input of urban and agricultural activities. According to the heavy metal pollution index (HPI, ranging from 23.74 to 184.0) analysis, it should be noted that As and Sb contribute most of the HPI values. The health risk assessment using HI and CR showed that V and Sb might have a potential non-carcinogenic risk and As might have a potential carcinogenic risk to adults and children in the study area (CR value exceeded target risk 10−4). At the same time, it was worth noting that As might have a potential non-carcinogenic risk for children around QLR (HI value exceeded the threshold value 1). The secular variation of As and Sb should be monitor in high-risk areas. The results of this study can provide important data for improving water resources management efficiency and heavy metal pollution prevention in Wuhan.


Author(s):  
Mahsa Jahangiri-rad ◽  
Mohsen Shariati ◽  
Mahdieh Yaaghoubi ◽  
Ali Haghmoradkhani ◽  
Abbas Akbarzadeh

Introduction: Inappropriate management of mining activities may bring about water pollution and pose a heavy complication on aquatic ecosystem and humans. The study aimed to evaluate the effect of Qorveh gold mining activities on the quality of nearby groundwater. Materials and Methods: The concentration of seven eco-toxic metals along with some general hydrochemical parameters were investigated for 27 sampling stations in the study area using Atomic Absorption Spectrometry (AAS) and conventional hydrochemical methods. The analysis results were further applied to compute pollution indices, namely heavy metal pollution index (HPI) for irrigation purposes. Results: The main elements were within the World Health Organization (WHO) and Iranian National Water Standards (INWS) for irrigation water quality, except for NH4+ in some sampling points. The concentration of heavy metals followed the order Cu > Zn > Pb > Hg > Cd > As. The contents of Hg, As, Cd, and Cu in most sites were higher than the recommended values. Except for two stations, the value of HPI based on the mean concentration was found to be far beyond the critical pollution index value of 100, suggesting that the area is highly polluted with some heavy metals. Conclusion: Elevated concentration of trace elements found in groundwater of this area represented the release of harmful elements from gold mining activities on surrounding environment.


2017 ◽  
Vol 9 (2) ◽  
pp. 1139-1145
Author(s):  
Singla Chetan ◽  
Sanjay T. Satpute ◽  
Garg Sunil

The objective of the study was to reveal the seasonal variations in the groundwater quality with respect to heavy metals contamination near Buddha Nullah in Ludhiana district. To get the extent of trace metals contamination, groundwater samples from tube wells were randomly collected from 16 different points on both sides along the course of Buddha Nullah from areas of Bhamian Kalan, Khasi Kalan and Wallipur Kalan villages of Ludhiana district during first fortnight of June (Pre-monsoon), first fortnight of November (Post-monsoon) and first fortnight of January (Winter season) during the year 2013-14. The concentrations of toxic and heavy metals such as metalloids B, As, Pb; alkaline earth metals Mg, Ca; alkali metals Na, K; transition metals Cr, Mn, Fe, Cu, Zn, Cd and nonmetal S were determined. The heavy metal pollution index (HPI) was calculated. Most of the parameters were found within permissible limit of BIS, 2004. The average values of concentration of Ca, Cr, Mn, As and Pb for pre-monsoon season was higher than average concentration of post-monsoon and winter season. Overall HPI calculated based on the mean concentration of the heavy metals was found to be 18.11, 15.32 and 16.10 for pre-monsoon, post-monsoon and winter season, respectively, which was below the critical pollution index value of 100. The study recommended proper treatment to the sewage water which is being discharged into the Buddha Nullah.


2018 ◽  
Vol 13 (3) ◽  
pp. 360-373
Author(s):  
FATIMAH OYENIKE OJO ◽  
TUKURA BITRUS WOKHE ◽  
MADU PASCAL CHIMA

Seasonal concentrations of eight total and bioavailable heavy metals (Cr, Cu, Cd, Zn, Mn, Ni, Pb an Fe), along with some physico chemical properties of soil in vegetable farms around the rock quarry in Durumi, Abuja was assessed to know the level of heavy metal pollution of the soil. Control and actual soil samples were collected from depths of 0.0 -5.0cm and 5.0 - 10.0cm during dry and rainy seasons. Heavy metal concentrations varied inconsistently in samples and control. Dry season levels of Zn(5.20mg/kg), Mn(19.44mg/kg), Ni(1.69mg/kg) and Pb(4.56mg/kg) and rainy season levels of Zn (0.26mg/kg), Pb(22.53mg/kg) at soil depth of 0.0 - 5.0cm, and dry season levels of Zn(1.19mgkg) and Ni(1.62mg/kg) along with rainy season levels of Cr (0.44mg/kg), Cd (0.06mg/kg), Zn(0.09mg/kg) and Fe(6.74mg/kg) at soil depth of 5.0 -10.0cm were all higher in samples than controls. However, seasonal mean total heavy metals in the soil samples were lower than the Maximum Allowable Limits (mg/Kg) for World Health Organization (WHO) and Food and Agriculture Organization (FAO). During dry season, heavy metals that indicated anthropogenic content, had anthropogenic levels that ranged in the order: Cd(16.67%) < Cu(54.17%)


2021 ◽  
Author(s):  
Suantak Paolalsiam Vaiphei ◽  
Rama Mohan Kurakalva

Abstract The present study is to characterize groundwater quality using heavy metal pollution indices and geospatial variations. A total of 58 samples from hand pump/submersible bore wells were collected from the Wanaparthy watershed of the upper Krishna River basin according to the grid size (5*6 km 2 ). The heavy metals concentration in groundwater samples are found in the order of Zn(38.67%)> B(32.67%)> Ba(13.59%)> As(8.49%)> Hg(3.71%)> Cr(1.28%)> Ni(0.52%)> Cd(0.47%). Among these heavy metals, arsenic (22.4%) and mercury (5.1%) were found above the permissible limits of WHO drinking water guideline values. A positive correlation between pH versus B/Ba/Hg, TH versus EC/TDS, and B versus Ba indicates the presence of metals due to chemical reaction (rock-water interaction). Arsenic correlation with EC/TDS/TH indicates artificial intervention. Drainage network analysis enumerates high concentration of parameters at near or joining to upper order of drainage system, which might be due to input of runoff water (interaction of variable rocks composition) and later stage infiltration to subsurface and reached to an aquifer. Heavy metal pollution index (HPI) showed 86.2% of samples are in the category of low class, whereas 12.1% of samples fall within medium class. According to metal index (MI) classification, 12.1% samples are in very pure, 24.14% samples are pure, while the remaining 63.8% samples are in the slightly to strongly affect category. This study suggested the main source of heavy metals in groundwater might be from the dominant granitoid rocks because the area is mostly devoid of industrialization.


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