scholarly journals Comprehensive assessment of groundwater quality using heavy metal pollution indices and geospatial technique: A case study from Wanaparthy watershed of upper Krishna River basin, Telangana, India.

Author(s):  
Suantak Paolalsiam Vaiphei ◽  
Rama Mohan Kurakalva

Abstract The present study is to characterize groundwater quality using heavy metal pollution indices and geospatial variations. A total of 58 samples from hand pump/submersible bore wells were collected from the Wanaparthy watershed of the upper Krishna River basin according to the grid size (5*6 km 2 ). The heavy metals concentration in groundwater samples are found in the order of Zn(38.67%)> B(32.67%)> Ba(13.59%)> As(8.49%)> Hg(3.71%)> Cr(1.28%)> Ni(0.52%)> Cd(0.47%). Among these heavy metals, arsenic (22.4%) and mercury (5.1%) were found above the permissible limits of WHO drinking water guideline values. A positive correlation between pH versus B/Ba/Hg, TH versus EC/TDS, and B versus Ba indicates the presence of metals due to chemical reaction (rock-water interaction). Arsenic correlation with EC/TDS/TH indicates artificial intervention. Drainage network analysis enumerates high concentration of parameters at near or joining to upper order of drainage system, which might be due to input of runoff water (interaction of variable rocks composition) and later stage infiltration to subsurface and reached to an aquifer. Heavy metal pollution index (HPI) showed 86.2% of samples are in the category of low class, whereas 12.1% of samples fall within medium class. According to metal index (MI) classification, 12.1% samples are in very pure, 24.14% samples are pure, while the remaining 63.8% samples are in the slightly to strongly affect category. This study suggested the main source of heavy metals in groundwater might be from the dominant granitoid rocks because the area is mostly devoid of industrialization.

Water ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 1801
Author(s):  
Valentina Andreea Calmuc ◽  
Madalina Calmuc ◽  
Maxim Arseni ◽  
Catalina Maria Topa ◽  
Mihaela Timofti ◽  
...  

It is a well–known fact that heavy metal pollution in sediments causes serious problems not only in the Danube basin, but also in the large and small adjacent river streams. A suitable method for assessing the level of heavy metals and their toxicity in sediments is the calculation of pollution indices. The present research aims to assess heavy metal pollution in the Lower Danube surface sediments collected along the Danube course (between 180 and 60 km) up to the point where the Danube River flows into the Danube Delta Biosphere Reserve (a United Nations Educational, Scientific and Cultural Organization – UNESCO, protected area). In addition, this monitored area is one of the largest European hydrographic basins. Five heavy metals (Cd, Ni, Zn, Pb, Cu) were analyzed in two different seasons, i.e., the autumn of 2018 and the spring of 2019, using the Inductively Coupled Plasma Mass Spectrometry (ICP– MS) technique. Our assessment of heavy metal pollution revealed two correlated aspects: 1. a determination of the potential risks of heavy metals in sediments by calculating the Potential Ecological Risk Index (RI), and 2. an evaluation of the influence of anthropogenic activities on the level of heavy metal contamination in the surface sediments, using three specific pollution indices, namely, the Geo–Accumulation Index (Igeo), the Contamination Factor (CF), and the Pollution Load Index (PLI). The results of this pioneering research activity in the region highlighted the presence of moderate metal (Ni and Cd) pollution and a low potential ecological risk for the aquatic environment.


2021 ◽  
Author(s):  
Concepcion Pla ◽  
Javier Valdes-Abellan ◽  
Miguel Angel Pardo ◽  
Maria Jose Moya-Llamas ◽  
David Benavente

<p>The impervious nature of urban areas is mostly responsible for urban flooding, runoff water pollution and the interception of groundwater recharge. Green infrastructure and sustainable urban drainage systems combine natural and artificial measures to mitigate the abovementioned problems, improving stormwater management and simultaneously increasing the environmental values of urban areas. The actual rate of urban growth in many urban areas requires the enhancement and optimization of stormwater management infrastructures to integrate the territorial development with the natural processes. Regarding the quality of runoff stormwater, heavy metals are critical for their impact on human health and ecological systems, even more if we consider the cumulative effect that they produce on biota. Thus, innovative stormwater management approaches must consider new solutions to deal with heavy metal pollution problems caused by runoff. In this study, we propose the employment of Arlita<sup>®</sup> and Filtralite<sup>®</sup>, two kind of lightweight aggregates obtained from expanded clays, to remove heavy metal concentration from runoff stormwater. Laboratory experiments were developed to evaluate the removal rate of different heavy metals existent in runoff stormwater. The lightweight aggregates acted as filter materials in column experiments to quantify their removal capacity. In addition, batch tests were also developed to evaluate the exhaustive capacity of the materials. Results from the study confirmed the efficiency of the selected lightweight aggregates to reduce the heavy metals concentration by up to 90% in urban stormwater runoff.</p>


2020 ◽  
Vol 7 (2) ◽  
pp. 198
Author(s):  
Oluwafunso Oladipo Awosusi ◽  
Adeshina Luqman Adisa

Heavy metal pollution has been a source of health problems in humans. These metals are persistent, toxic, non-degradable and often take a long time to be eliminated from the body. This study is, therefore, designed to assess heavy metal pollution of River Basin in Nigeria. Seventy stream sediment samples were systematically collected from an area, approximately 400km2, latitude 7O 00’ and 7O 15’N and longitude 5O 11’ and 5O 19’E. The pollution status of the sediments by heavy metals were assessed by Enrichment Factor (EF), Pollution Load Index (PLI) and Geo-accumulation Index (Igeo). The concentrations of the heavy metals were also compared with United States Environmental Protection Agency (USEPA) Sediment quality guidelines (SQG). The samples were dried in the laboratory, disaggregated, sieved to minus 80 (<177 microns) mesh size using nylon sieve. The sieved samples were, then, digested and the concentrations of As, Co, Fe, Mn, Ni, Pb, V and Zn were determined by Wavelength Dispersive X-ray Fluorescence Spectrometry (WD-XRFS). Results revealed that the mean concentrations of the heavy metals are in the order V>Zn>Pb>As>Ni>Co>Fe>Mn. Furthermore, the mean concentration of lead exceeded both the average world shale and the USEPA SQG values. However, the mean concentration of cobalt, nickel, manganese and zinc were lower than the average world shale values for these elements. The Enrichment Factor (EF) revealed that cobalt was moderately enriched while arsenic and lead were significantly enriched in the sediments. On the basis of the geoaccumulation index, the stream sediments were largely uncontaminated except at some sites that were moderately to strongly contaminated by As and Pb.  


2019 ◽  
Vol 9 ◽  
pp. 100245 ◽  
Author(s):  
Ali Rezaei ◽  
Hossein Hassani ◽  
Sara Hassani ◽  
Nima Jabbari ◽  
Seyedeh Belgheys Fard Mousavi ◽  
...  

2017 ◽  
Vol 14 (3-4) ◽  
Author(s):  
Nusreta Djonlagic

In this study the results of a 15-year long monitoring survey on heavy metals in water at Lake Modrac were assessed using pollution indices of heavy metals, such as Heavy metal pollution index HPI, Heavy metal evaluation index HEI and the Degree of contamination CD. The results of the survey on heavy metal pollution of sediment conducted in 2015 were used as input data for the following pollution indices: Concentration factor , Pollution load index PLI, Enrichment factor EF, Index of geo-accumulation Igeo, Ecological risk factor , Potential ecological risk index to the water-body, RI. The results showed a good correlation and the lake sediment was characterized as polluted. Enrichment factors and indices of geo-accumulation of heavy metals were indicated as very high enriched in the sediment, and have been identified as an anthropogenic source of pollution. Cumulative presence in the sediment is assessed through the pollution index, RI, and has been assessed as moderate ecological risk to the lake water-body. The application of pollution indices presents a valuable tool in assessing the long-term pollution status of Lake Modrac.


2020 ◽  
Vol 81 (2) ◽  
pp. 3-12
Author(s):  
Tanya Vasileva

Ground waters may undergo a process of contamination in various ways, but the presence and amount of heavy metals in them can be indicative of their purity and usage. Apart from that, the heavy metals are among the most widely spread pollutants in nature, and their presence in groundwater indicates the existence of natural or anthropogenic sources of contamination. Ground waters polluted with heavy metals can also be very toxic and harmful to human health, and very damaging to the environment as well. In this article, the concentrations of eight toxic heavy metals (Fe, Mn, Cu, Al, Ni, Pb, Zn, Cr) were analyzed in the ground waters of the Mesta River Basin. A number of data for the concentrations of those heavy metals were used in order to calculate the following two indices describing groundwater purity: the Heavy Metal Pollution Index (HPI), and the Metal Index (MI). Both indices describe the overall quality of groundwater in direct relationship to the sum total of heavy metal concentrations. On one hand, minimal concentrations of heavy metals are necessary for the faultless functioning of organisms and indispensable to various biochemical processes, but on the other hand, in high concentrations, they might lead to dysfunctions in the cells of healthy organisms, and problems within their enzyme system. And these effects are entirely dependent upon the nature of the heavy metals involved. The research carried out so far shows that, according to HPI, about 65% of the shallow ground waters in the Mesta River Basin can be classified as being of excellent quality. The values obtained for the HPI are in the range of 3 to 64 (id est under the critical value of 100), or the groundwater is not contaminated with heavy metals. The MI varies within the range of 0.3 to 2.6, and therefore the groundwater from the zones with active water exchange can be characterized as being of slight to medium poor quality (41%), and the groundwater within Class II (or classified as pure with values of MI between 0.3 and 1.0) comprise approximately 59% of the overall catchment area.


Water ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1545
Author(s):  
Chao Shen ◽  
Jiaqi Zhao ◽  
Guangwu Xie ◽  
Yulai Wang ◽  
Qiang Chen ◽  
...  

Rapid urbanization has destroyed urban water systems and led to blackened and odorous rivers. The heavily polluted rivers are always facing eutrophication and heavy metal pollution, while the combined effects of these environmental factors on the microbial diversity and distribution of the river microbial communities have not been adequately reported, especially the archaeal communities. In this study, we investigated the community structure and microbial distribution of sediment archaeal communities from an urban blackened and odorous river basin of the Zhang river, in Nanling, China. Results showed that the archaeal community from the eight sediment sites have average values of Shannon and Chao1 at 3.4921 and 232.7202, respectively. The community diversity and richness were different among samples. Halobacterota and Euryarchaeota were the most abundant phylum and Crenarchaeota also took up a considerable amount of the archaeal community. To reveal the main environmental drivers of the distribution of archaeal communities in sediment, the environmental physicochemical factors (total nitrogen, total phosphorus, oxidation/reduction potential, nitrate nitrogen, ammonia nitrogen, pH and total organic carbon) and heavy metals (Cr, Ni, Cu, Zn, As, Cd, Pb and Hg) in sediment were determined. A redundancy analysis (RDA) revealed that Eh was the most prominent influencing factor, and As was the most influential heavy metal on the microbial distribution of archaeal communities. Furthermore, a variance partitioning analysis (VPA) was used to identify the impacts of physicochemical factors and heavy metals on the archaeal community distribution. Results showed that heavy metals have higher effects on archaeal community distribution than physicochemical factors. The present study suggested that the heavy metal pollution should be paid more attention in the microbial distribution in heavily polluted urban rivers, and also should be taken into consideration for improving the efficacies of ecological evaluation and remediation.


2021 ◽  
Vol 3 (7) ◽  
Author(s):  
Hassan Hamidu ◽  
Falalu B. Halilu ◽  
Kwaya M. Yerima ◽  
Lawal M. Garba ◽  
Arabi A. Suleiman ◽  
...  

Abstract The present study focused on pollution status of groundwater in the industrial areas of Challawa and Sharada in Kano city based on pollution indices, statistical and spatial analyses. Twenty groundwater samples representing groundwater of the studied areas (Ten from each area) were analyzed for the presence of Cd, Cr, Ni, Fe, Mn and Zn using atomic absorption spectrophotometer. The result showed 95%, 5%, 60%, 15% and 25% of the analyzed water samples had detectable Cd, Cr, Ni, Fe, and Mn above the drinking water limits of both Nigerian standards for drinking water quality NSDWQ and World Health Organization (WHO) with Cd dominating other analyzed heavy metals in the groundwater. Evaluation of heavy metal pollution revealed a low polluted status based on the contaminant index (Cd), synthetic pollution index, heavy metals evaluation index, and heavy metal pollution index. Metal index categorized the groundwater as seriously polluted. The statistical evaluation gave strong and positive correlations between indices and a moderate one between the metallic ions. Component analysis revealed a strongly positive loading of Fe, Ni and Zn while Cd had a strong negative loading. Cr and Mn were positive and moderately loaded. Statistical analyses suggested both anthropogenic and geogenic sources for the heavy metals mainly from the industrial and agricultural practices and rock weathering processes, respectively. This study is expected to be a useful tool in the planning, monitoring and mitigation of pollution activities in the area. Article Highlights The pollution status of groundwater with respect to heavy metals was investigated in the Challawa and Sharada industrials zones in Kano city Nigeria The concentration of Cd, Fe, Ni, Cr Mn and Zn was determined using the AAS Different Pollution indices of HPI, HEI, SPI, Cd and MI were utilized to categorized the area as low, medium and highly polluted. Spatial and temporal distribution maps demarcated based on the metal concentrations and computed indices in the area. CA, PCA, and HCA were used to identified the geochemistry, relationship, sources and origin of heavy metals in groundwater. The study revealed zones with low to high-risk groundwater in terms of toxic heavy metals and pollution status.


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