Pressurized physical activation: A simple production method for activated carbon with a highly developed pore structure

Carbon ◽  
2021 ◽  
Author(s):  
Hyeonseok Yi ◽  
Koji Nakabayashi ◽  
Seong-Ho Yoon ◽  
Jin Miyawaki
2020 ◽  
Vol 38 (1-2) ◽  
pp. 60-76 ◽  
Author(s):  
Hong Zhao ◽  
Qiongfen Yu ◽  
Ming Li ◽  
Shengnan Sun

In this study, activated carbons without any chemical residue were prepared from walnut shells. The preparation method in a tube furnace included a pyrolysis carbonization process and a CO2 activation process. The influences of activation temperature and holding time on the specific surface area, yield, and pore structure were investigated. Adsorption performance of water vapor was also examined in details. Thermogravimetric analysis, N2 adsorption–desorption isotherm, and scanning electron microscope were used to characterize samples. The result shows that the activation energy at different heating rates varies from 30.16 to 64.86 kJ/mol. The highest water vapor adsorption capacity of the sample is 0.3824 g/g and it takes only 30 min to realize regeneration. And the maximum Brunauer–Emmett–Teller specific surface area of 1228 m2/g also occurs in this optimal preparation condition. CO2 physical activation method was found to have a positive effect on pore structure development of activated carbon for water vapor adsorption.


2001 ◽  
Vol 11 (PR3) ◽  
pp. Pr3-279-Pr3-286
Author(s):  
X. Dabou ◽  
P. Samaras ◽  
G. P. Sakellaropoulos

2020 ◽  
Vol 5 (3) ◽  
pp. 221
Author(s):  
Muhammad Azam ◽  
Muhammad Anas ◽  
Erniwati Erniwati

This study aims to determine the effect of variation of activation temperature of activated carbon from sugar palm bunches of chemically activatied with the activation agent of potassium silicate (K2SiO3) on the adsorption capacity of iodine and methylene blue. Activated carbon from bunches of sugar palmacquired in four steps: preparationsteps, carbonizationstepsusing the pyrolysis reactor with temperature of 300 oC - 400 oC for 8 hours and chemical activation using of potassium silicate (K2SiO3) activator in weight ratio of 2: 1 and physical activation using the electric furnace for 30 minutes with temperature variation of600 oC, 650 oC, 700 oC, 750 oC and 800 oC. The iodine and methyleneblue adsorption testedby Titrimetric method and Spectrophotometry methodrespectively. The results of the adsorption of iodine and methylene blue activated carbon from sugar palm bunches increased from 240.55 mg/g and 63.14 mg/g at a temperature of 600 oC to achieve the highest adsorption capacity of 325.80 mg/g and 73.59 mg/g at temperature of 700 oC and decreased by 257.54 mg/g and 52.03 mg/g at a temperature of 800 oCrespectively.However, it does not meet to Indonesia standard (Standard Nasional Indonesia/SNI), which is 750 mg/g and 120 mg/g respectively.


2021 ◽  
Vol 1774 (1) ◽  
pp. 012067
Author(s):  
H Yang ◽  
J Liu ◽  
B Pang ◽  
J Chi

2013 ◽  
Vol 798-799 ◽  
pp. 1123-1127
Author(s):  
Hua Lei Zhou ◽  
Qiong Qiong Zhu ◽  
Dong Hua Huang

The activated carbon with high surface area was prepared by KOH activation from anthracite and used as adsorbent for removal of Cr (VI) from aqueous solution. The pore structure and surface properties were characterized by N2 adsorption at 77K, transmission electron microscope (TEM) and Fourier transform infrared spectroscopy ( FTIR). Effect of pH and isotherms at different temperature were investigated. Results show that the prepared carbon is a microporous-and mesoporous-adsorbent with developed pore structure and abundant surface oxygen-containing groups. PH value of the solution plays key function on the adsorption. The chemical adsorption dominates the adsorption process. The activated carbon exhibits much higher Cr adsorption capacity than the commercial activated carbon at initial pH of ~3. The equilibrium adsorption data are fitted by both Freundlich model and Langmuir model well.


2003 ◽  
Vol 262 (1) ◽  
pp. 194-199 ◽  
Author(s):  
Kiyoshi Okada ◽  
Nobuo Yamamoto ◽  
Yoshikazu Kameshima ◽  
Atsuo Yasumori

2017 ◽  
Vol 29 (1) ◽  
pp. 9-13
Author(s):  
Masuma Sultana Ripa ◽  
Rafat Mahmood ◽  
Sabrina Khan ◽  
Easir A Khan

Adsorption separation of phenol from aqueous solution using activated carbon was investigated in this work. The adsorbent was prepared from coconut shell and activated by physical activation method. The coconut shell was first carbonized at 800°C under nitrogen atmosphere and activated by CO2 at the same temperature for one hour. The prepared activated carbon was characterized by Scanning Electron Microscope (SEM) and BET Surface Analyzer and by the determination of iodine number as well as Boehm titration. The iodine number indicates the degree of relative activation of the adsorbent. The equilibrium adsorption isotherm phenol from aqueous solution was performed using liquid phase batch adsorption experiments. The effect of experimental parameters including solution pH, agitation time, particle size, temperature and initial concentration was investigated. The equilibrium data was analyzed using Langmuir and Freundlich adsorption model to describe the adsorption isotherm and estimate the adsorption isotherm parameters. The results indicate the potential use of the adsorbent for removal of phenol from the aqueous solution.Journal of Chemical Engineering, Vol. 29, No. 1, 2017: 9-13


Sign in / Sign up

Export Citation Format

Share Document