Fixed-angle rotary shear as a new method for tailoring electro-mechanical properties of templated graphene–polymer composites

2014 ◽  
Vol 100 ◽  
pp. 70-75 ◽  
Author(s):  
Nicholas Heeder ◽  
Abayomi Yussuf ◽  
Indrani Chakraborty ◽  
Michael P. Godfrin ◽  
Robert Hurt ◽  
...  
1994 ◽  
Vol 29 (9) ◽  
pp. 2406-2416 ◽  
Author(s):  
S. W. Shang ◽  
J. W. Williams ◽  
K. -J. M. Söderholm

2021 ◽  
Vol 5 (5) ◽  
pp. 130
Author(s):  
Tan Ke Khieng ◽  
Sujan Debnath ◽  
Ernest Ting Chaw Liang ◽  
Mahmood Anwar ◽  
Alokesh Pramanik ◽  
...  

With the lightning speed of technological evolution, the demand for high performance yet sustainable natural fibres reinforced polymer composites (NFPCs) are rising. Especially a mechanically competent NFPCs under various loading conditions are growing day by day. However, the polymers mechanical properties are strain-rate dependent due to their viscoelastic nature. Especially for natural fibre reinforced polymer composites (NFPCs) which the involvement of filler has caused rather complex failure mechanisms under different strain rates. Moreover, some uneven micro-sized natural fibres such as bagasse, coir and wood were found often resulting in micro-cracks and voids formation in composites. This paper provides an overview of recent research on the mechanical properties of NFPCs under various loading conditions-different form (tensile, compression, bending) and different strain rates. The literature on characterisation techniques toward different strain rates, composite failure behaviours and current challenges are summarised which have led to the notion of future study trend. The strength of NFPCs is generally found grow proportionally with the strain rate up to a certain degree depending on the fibre-matrix stress-transfer efficiency. The failure modes such as embrittlement and fibre-matrix debonding were often encountered at higher strain rates. The natural filler properties, amount, sizes and polymer matrix types are found to be few key factors affecting the performances of composites under various strain rates whereby optimally adjust these factors could maximise the fibre-matrix stress-transfer efficiency and led to performance increases under various loading strain rates.


Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1468
Author(s):  
Ummu Raihanah Hashim ◽  
Aidah Jumahat ◽  
Mohammad Jawaid

Basalt fibre (BF) is one of the most promising reinforcing natural materials for polymer composites that could replace the usage of glass fibre due to its comparable properties. The aim of adding nanofiller in polymer composites is to enhance the mechanical properties of the composites. In theory, the incorporation of high strength and stiffness nanofiller, namely graphene nanoplatelet (GNP), could create superior composite properties. However, the main challenges of incorporating this nanofiller are its poor dispersion state and aggregation in epoxy due to its high surface area and strong Van der Waals forces in between graphene sheets. In this study, we used one of the effective methods of functionalization to improve graphene’s dispersion and also introducing nanosilica filler to enhance platelets shear mechanism. The high dispersive silica nanospheres were introduced in the tactoids morphology of stacked graphene nanosheets in order to produce high shear forces during milling and exfoliate the GNP. The hybrid nanofiller modified epoxy polymers were impregnated into BF to evaluate the mechanical properties of the basalt fibre reinforced polymeric (BFRP) system under tensile, compression, flexural, and drop-weight impact tests. In response to the synergistic effect of zero-dimensional nanosilica and two-dimensional graphene nanoplatelets enhanced the mechanical properties of BFRP, especially in Basalt fibre + 0.2 wt% GNP/15 wt% NS (BF-H0.2) with the highest increment in modulus and strength to compare with unmodified BF. These findings also revealed that the incorporation of hybrid nanofiller contributed to the improvement in the mechanical properties of the composite. BF has huge potential as an alternative to the synthetic glass fibre for the fabrication of mechanical components and structures.


2021 ◽  
pp. 009524432110290
Author(s):  
Mukaddes Sevval Cetin ◽  
Ozan Toprakci ◽  
Omer Suat Taskin ◽  
Abdullah Aksu ◽  
Hatice Aylin Karahan Toprakci

This study focuses on the fabrication and characterization of vermiculite-filled flexible polymer composites. Exfoliated vermiculite was incorporated into triblock thermoplastic elastomer copolymer, styrene- b-(ethylene- co-butylene)- b-styrene (SEBS), at various levels from 1 to 15 wt% by a high shear mixer. The composite films were obtained by the combination of solvent casting and compression molding. The morphological, structural, thermal, and mechanical properties and contact angle of the composites were determined. Some micro-morphological differences were observed between the samples and the difference was assumed to be caused by high shear mixing and filler concentration. High shear mixing was found effective in terms of the detachment of vermiculite layers at all concentrations. However, at low filler loading, that behavior was more obvious. At 1 wt% filler concentration, mechanical properties increased that was probably caused by good filler-matrix interaction stemmed from smaller particle size. At higher vermiculite concentrations, fillers found to show agglomerations that led to a decrease in mechanical strength and strain at break. Elastic and secant modulus showed an increasing trend. Contact angle measurements were carried out to determine the oleophilic character of the samples. An increase in the vermiculite content resulted in higher oleophilic character and the lowest contact angle was obtained at 15 wt% VMT loading. In addition to these, thermal stability, thermal dimensional stability and flame retardancy were improved by the incorporation of VMT. 15 wt% vermiculite-filled sample showed the best performance in terms of thermal stability and flame retardancy.


2013 ◽  
Vol 592-593 ◽  
pp. 647-650 ◽  
Author(s):  
Małgorzata Lenart

Cement – polymer composites are nowadays widely used in repair systems not only in case of concrete or reinforced concrete constructions but also in masonry. Polymers addition for example already at 5% m.c. modifies the structure of the cement – polymer composite in a way that many of the mechanical properties such as flexural strength, tensile strength or adhesion to substrates are improved. The paper presents the results of tests such as flexural, compressive or adhesion strength to ceramic substrate of hardened cement mortars with different composition, as well as selected cement mortars modified by two polymers: polyvinyl alcohol and styrene – butadiene polymer dosed at 5 % m.c. Four types of cement mortars modified by lime (component used in historical constructions as well as in contemporary masonry mortars) are also examined for comparison.


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