Particle morphology of mineral filler and its effects on the asphalt binder-filler interfacial interaction

2022 ◽  
Vol 321 ◽  
pp. 126292
Author(s):  
Baodong Xing ◽  
Yubing Du ◽  
Chen Fang ◽  
Huadong Sun ◽  
Yuchao Lyu ◽  
...  
Keyword(s):  
Asphalt Binder ◽  
Particle Morphology ◽  
Interfacial Interaction ◽  
Mineral Filler

scholarly journals Rheological and Interaction Analysis of Asphalt Binder, Mastic and Mortar

Materials ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 128 ◽  
Author(s):  
Meng Chen ◽  
Barugahare Javilla ◽  
Wei Hong ◽  
Changluan Pan ◽  
Martin Riara ◽  
...  
Keyword(s):  
Phase Change ◽  
Interaction Analysis ◽  
Asphalt Binder ◽  
Asphalt Mixtures ◽  
Physical Interaction ◽  
Fine Aggregate ◽  
Mineral Filler ◽  
Asphalt Mastic ◽  
Fine Aggregates ◽  
Asphalt Mortar

This paper investigated the rheological properties of asphalt binder, asphalt mastic and asphalt mortar and the interaction between asphalt binder, mineral filler and fine aggregates. Asphalt binder, mastic and mortar can be regarded as the binding phase at different scales in asphalt concrete. Asphalt mastic is a blend of asphalt binder and mineral filler smaller than 0.075 mm while asphalt mortar consists of asphalt binder, mineral filler and fine aggregate smaller than 2.36 mm. The material compositions of mastic and mortar were determined from the commonly used asphalt mixtures. Dynamic shear rheometer was used to conduct rheological analysis on asphalt binder, mastic and mortar. The obtained test data on complex modulus and phase angle were used for the construction of rheological master curves and the investigation of asphalt-filler/aggregate interaction. Test results indicated a modulus increase of three- to five-fold with the addition of filler and a further increase of one to two orders of magnitude with cumulative addition of fine aggregates into asphalt binder. Fine aggregates resulted in a phase change for mortar at high temperatures and low frequencies. The filler had stronger physical interaction than fine aggregate with an interaction parameter of 1.8–2.8 and 1.15–1.35 respectively. Specific area could enhance asphalt-filler interaction. The mastic and mortar modulus can be well predicted based on asphalt binder modulus by using particle filling effect. Asphalt mortar had a significant modulus reinforcement and phase change and thus could be the closest subscale in terms of performance to that of asphalt mixtures. It could be a vital scale that bridges the gap between asphalt binder and asphalt mixtures in multiscale performance analysis.

scholarly journals Experimental Assessment of Mineral Filler on the Volumetric Properties and Mechanical Performance of HMA Mixtures

2020 ◽  
Vol 6 (12) ◽  
pp. 2312-2331
Author(s):  
Hanaa Khaleel Alwan Al-Bayati ◽  
Abimbola Grace Oyeyi ◽  
Susan L. Tighe
Keyword(s):  
Mechanical Performance ◽  
Asphalt Binder ◽  
Field Performance ◽  
Hydrated Lime ◽  
Volumetric Properties ◽  
Mineral Filler ◽  
Freezing And Thawing ◽  
Binder Ratio ◽  
Asphalt Content ◽  
Mineral Aggregates

This research is conducted to evaluate the influence of mineral filler on the volumetric properties, mechanical and field performance of Hot Mix Asphalt (HMA). Two mineral filler types, namely, Hydrated Lime (HL) and Dust Plant (DPt) were used. Three filler proportions were utilized greater than 1% which represents the most applicable percentage, especially for HL, used by the Ministry of Transportation Ontario (MTO). The effect of filler on various volumetric properties including Voids In Mineral Aggregates (VMA), Voids Filled With Asphalt (VFA), dust to binder ratio (Dp) is examined. Mechanical and predicted field performance of HMA to the best filler proportion that meets all the MTO limitations is also investigated. The obtained results indicated that the Optimum Asphalt Content (OAC), VMA, and VFA decrease as the filler content is increased. HMA mixtures that includes DPt filler had the higher values of VMA, VFA, and OAC compared to the hydrated lime. The addition of filler with 2.5% percentage is very successful for both filler types due to satisfying all MTO requirements for volumetric properties of HMA. Based on MTO specifications, the addition of 2.0% filler seems to be unsuccessful for both filler types due to lowering the Dp ratio. Mix design with 3.0% filler was also unsuccessful because of the lower value of OAC meaning that the mix is dry and there is insufficient asphalt binder to coat the aggregate particles. Besides, filler type has a significant effect on the mechanical properties of the HMA mixtures. As a filler in HMA mixtures, the utilization of HL as a portion of 2.5 % leads to a significant improvement in mixture resistance to water and freezing and thawing. The mixtures that included HL have a higher cracking resistance, greater stiffness, and a higher fracture stress than the mixtures that included DPt. Furthermore, predicted field performance indicated better outcomes for mixes with HL compared to DPt mixes. Doi: 10.28991/cej-2020-03091619 Full Text: PDF

scholarly journals Substitution of Fly Ash as Mineral Filler in Wearing Course of Hot Mix Asphalt

2021 ◽  
Vol 2129 (1) ◽  
pp. 012039
Author(s):  
Mohd Badrul Hisyam Ab Manaf ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Rafiza Abdul Razak ◽  
Muhammad Munsif Ahmad ◽  
Mustaqqim Abdul Rahim ◽  
...  
Keyword(s):  
Fly Ash ◽  
Asphalt Binder ◽  
Mineral Filler ◽  
Bitumen Content ◽  
Public Work Department ◽  
Sustainable Materials ◽  
The Stability ◽  
Marshall Stability ◽  
Air Void

Abstract Fly Ash (FA) is one of the sustainable materials to substitute Ordinary Portland Cement (OPC) was found commercialized in construction field but the usage in HMA pavement is limited. Thus, this study is important to promote FA as a sustainable filler instead of using OPC to reduce greenhouse gases. The primary aim is to investigate the Marshall Stability of HMA that incorporating of OPC and FA as filler. In addition, Optimum Bitumen Content (OBC) determination also conducted in this study. Marshall Stability test was conducted based on ASTM 2006 for both mixtures. The parameters gained from the test are the stability, flow, air void in mix (VIM), void filled bitumen (VFB) and stiffness being used to OBC. The OBC for HMA with OPC filler obtained is 5.06% meanwhile for HMA with FA is 4.79%. All Marshall Parameters was complied with of Malaysia Public Work Department (PWD) Standard for both mixtures. The HMA with FA filler give better results for all parameters. Based on OBC percentage, usage of asphalt binder was reduced at 0.29%. Thus, it was more economical if using FA compared with OPC as a filler. Furthermore, HMA with FA filler have better stability and strength as well as lesser deformation with HMA with OPC filler. For the overall, FA have huge potential in substituting other mineral filler to produce better quality of asphalt pavement.

Cryomicroscopy of multiphase latices

1991 ◽  
Vol 49 ◽  
pp. 1060-1061
Author(s):  
O. L. Shaffer ◽  
M.S. El-Aasser ◽  
C. L. Zhao ◽  
M. A. Winnik ◽  
R. R. Shivers
Keyword(s):  
Electron Microscopy ◽  
Radiation Damage ◽  
Freeze Fracture ◽  
Particle Morphology ◽  
Second Stage ◽  
Transmission Electron ◽  
Important Approach ◽  
Carbon Coated ◽  
Preparation Techniques

Transmission electron microscopy is an important approach to the characterization of the morphology of multiphase latices. Various sample preparation techniques have been applied to multiphase latices such as OsO4, RuO4 and CsOH stains to distinguish the polymer phases or domains. Radiation damage by an electron beam of latices imbedded in ice has also been used as a technique to study particle morphology. Further studies have been developed in the use of freeze-fracture and the effect of differential radiation damage at liquid nitrogen temperatures of the latex particles embedded in ice and not embedded.Two different series of two-stage latices were prepared with (1) a poly(methyl methacrylate) (PMMA) seed and poly(styrene) (PS) second stage; (2) a PS seed and PMMA second stage. Both series have varying amounts of second-stage monomer which was added to the seed latex semicontinuously. A drop of diluted latex was placed on a 200-mesh Formvar-carbon coated copper grid.

Piezoelectric β-polymorph formation of new textiles by surface modification with coating process based on interfacial interaction on the conformational variation of poly (vinylidene fluoride) (PVDF) chains

2020 ◽  
Vol 91 (3) ◽  
pp. 31301
Author(s):  
Nabil Chakhchaoui ◽  
Rida Farhan ◽  
Meriem Boutaldat ◽  
Marwane Rouway ◽  
Adil Eddiai ◽  
...  
Keyword(s):  
High Efficiency ◽  
Vinylidene Fluoride ◽  
Research Work ◽  
Research Area ◽  
Interfacial Interaction ◽  
Tetraethyl Orthosilicate ◽  
Poly Vinylidene Fluoride ◽  
Carbon Nanofillers ◽  
The Impact ◽  
Advanced Applications

Novel textiles have received a lot of attention from researchers in the last decade due to some of their unique features. The introduction of intelligent materials into textile structures offers an opportunity to develop multifunctional textiles, such as sensing, reacting, conducting electricity and performing energy conversion operations. In this research work nanocomposite-based highly piezoelectric and electroactive β-phase new textile has been developed using the pad-dry-cure method. The deposition of poly (vinylidene fluoride) (PVDF) − carbon nanofillers (CNF) − tetraethyl orthosilicate (TEOS), Si(OCH2CH3)4 was acquired on a treated textile substrate using coating technique followed by evaporation to transform the passive (non-functional) textile into a dynamic textile with an enhanced piezoelectric β-phase. The aim of the study is the investigation of the impact the coating of textile via piezoelectric nanocomposites based PVDF-CNF (by optimizing piezoelectric crystalline phase). The chemical composition of CT/PVDF-CNC-TEOS textile was detected by qualitative elemental analysis (SEM/EDX). The added of 0.5% of CNF during the process provides material textiles with a piezoelectric β-phase of up to 50% has been measured by FTIR experiments. These results indicated that CNF has high efficiency in transforming the phase α introduced in the unloaded PVDF, to the β-phase in the case of nanocomposites. Consequently, this fabricated new textile exhibits glorious piezoelectric β-phase even with relatively low coating content of PVDF-CNF-TEOS. The study demonstrates that the pad-dry-cure method can potentially be used for the development of piezoelectric nanocomposite-coated wearable new textiles for sensors and energy harvesting applications. We believe that our study may inspire the research area for future advanced applications.

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