Microstructure of electromagnetic pulse tungstic electrode argon arc welding (EMP-TIG) welded Mg/Al dissimilar metal joint is studyed using optical microscope, scanning electron microscope, and X-ray diffraction. The results indicate that gas tungsten arc welding can provide Mg/Al joint with excellent microstructure and performance. The welding region is composed of Mg3Al2 phase, α(Mg), β(Li), and MgAl. The weld zone and the Al alloy base materials are well combined. There are massive MgAl phase dendrites in the weld area, which cause the significantly increase of hardness at weld zone. Near the Mg-8Li alloy base metal side of the weld zone, there exists a layer of 100~ 200μm equiaxed region. About 1μm Mg3Al2 reaction layer is distributed between Mg-8Li alloy base metal and the equiaxed grains. This reaction layer and the Mg-8Li alloy base metal, as well as the weld zone of equiaxed grains, have a good combination.