Optimization of bio-crude yield and its calorific value from hydrothermal liquefaction of bagasse using methanol as co-solvent

This research is conducted for getting and examining bio-fuel from the process of hydrothermal liquefaction (HTL) using rice husk as raw material. The HTL process used ethanol as a solvent with concentration of 96%. Properties of the produced light fuels were examined on parameter such as water content, viscosity, calorific value, density, flash point, and gas chromatography-mass spectroscopy (GC-MS). The optimum yield 36.3 wt% of light fuel from HTL process of rice husk occurred at reactor temperature of 325°C and holding time of 45 minutes. Meanwhile, the optimum production of bio-fuel (light fuel + heavy fuel) was 69.3 wt% at reactor temperature of 325 °C and holding time of 30 minutes. The resulted light fuel has the calorivic value from 12.1 to 20.2 MJ/kg, viscosity from 1.11 to 1.6 cSt, and flash point from 14 to 29 °C. For the yield of bio-fuel from HTL process, the effect of reactor temperature was more pronounced than the effect of holding time. Further, the light fuels from HTL process with low water content are interesting objects as a fuel in internal combustion engines.

Download Full-text

Production of Bio-fuels by microwave-assisted Rapid Hydrothermal Liquefaction of Palm Kernel Shells Biomass

10.21203/rs.3.rs-409704/v1 ◽

2021 ◽

Author(s):

A A. Saleh ◽

Md Saiful Islam ◽

Md. Shaharul Islam ◽

M. A. M. A. Banggan

Keyword(s):

Ph Value ◽

Palm Kernel ◽

Calorific Value ◽

Product Yield ◽

Heating Time ◽

Microwave Oven ◽

Hydrothermal Liquefaction ◽

Bio Oil ◽

Increasing Trend ◽

Palm Kernel Shells

Abstract Hydrothermal Liquefaction (HTL) process is an alternative way for converting biomass to bio-fuels product. The aim of this study was to determine the effect of sample’s mass and heating time on the product yield (wt%) from palm kernel shells (PKS) and to characterize the bio-oil as produced. PKS which is one kind of biomass efficiently converted to bio-oil, bi-char and bio-gas by HTL associated with modified microwave oven. A modified household microwave oven with 800W was employed in this process. The product yield was increased proportionally with the sample mass from 31.16 wt% to 41.92 wt% for bio-oil at constant time of 15 minutes. However, a vice versa trend was observed for bio char. Furthermore, it was exhibited that the highest value of 66.51 wt% and then it reduced to 42.17 wt%. The last product, bio gas shows an increasing trend from 2.32wt% to 15.90wt%. For the second parameter, the production of bio oil decreases with the increasing of heating time while bio char and bio gas increases with the increases of time. For the highest product yield, the calorific value is 37.68 MJ/kg for 15g sample and 22.32 MJ/kg for 35g sample at 15 minutes heating time. Fourier Transform Infrared Spectroscopy (FTIR) result reveals that multiple functional groups i.e. alcohol, aldehydes, carboxylic acid and ketones is present in the PKS bio oil. Additionally, the pH value of the bio oil was in the range of 2-3.

Download Full-text

Study of the Kinetics of Thermal Destruction of Crossed Polyethylene

Bulletin of Science and Practice ◽

10.33619/2414-2948/49/04 ◽

2019 ◽

Vol 5 (12) ◽

pp. 37-46

Author(s):

K. Chalov ◽

Yu. Lugovoy ◽

Yu. Kosivtsov ◽

E. Sulman

Keyword(s):

Total Yield ◽

Calorific Value ◽

High Heat ◽

Process Temperature ◽

Optimum Process ◽

Quantitative Composition ◽

Pyrolysis Gas ◽

Gaseous Products ◽

Liquid Products ◽

Kinetics Of

This paper presents a study of the process of thermal degradation of crosslinked polyethylene. The kinetics of polymer decomposition was studied by thermogravimetry. Crosslinked polyethylene showed high heat resistance to temperatures of 400 °C. The temperature range of 430–500 °C was determined for the loss of the bulk of the sample. According to thermogravimetric data, the decomposition process proceeds in a single stage and includes a large number of fracture, cyclization, dehydrogenation, and other reactions. The process of pyrolysis of a crosslinked polymer in a stationary-bed metal reactor was investigated. The influence of the process temperature on the yield of solid, liquid, and gaseous pyrolysis products was investigated. The optimum process temperature was 500 °C. At this temperature, the yield of liquid and gaseous products was 85.0 and 12.5% (mass.), Respectively. Samples of crosslinked polyester decomposed almost completely. The amount of carbon–containing residue was 3.5% by weight of the feedstock. With increasing temperature, the yield of liquid products decreased slightly and the yield of gaseous products increased, but their total yield did not increase. For gaseous products, a qualitative and quantitative composition was determined. The main components of the pyrolysis gas were hydrocarbons C1–C4. The calorific value of pyrolysis gas obtained at a temperature of 500 °C was 17 MJ/m3. Thus, the pyrolysis process can be used to process crosslinked polyethylene wastes to produce liquid hydrocarbons and combustible gases.

Download Full-text

PROSPECTS OF OBTAINING ALTERNATIVE FUEL FROM VARIOUS BIOMASS AND WASTE SPECIES IN AZERBAIJAN

Alternative Energy and Ecology (ISJAEE) ◽

10.15518/isjaee.2019.01-03.025-041 ◽

2019 ◽

pp. 25-41

Author(s):

O. M. Salamov ◽

F. F. Aliyev

Keyword(s):

Power Plants ◽

Energy Intensity ◽

Oil And Gas ◽

Renewable Energy Sources ◽

Calorific Value ◽

High Energy ◽

Energy Sector ◽

Energy Sources ◽

Mineral Fertilizers ◽

Gaseous Fuels

The paper discusses the possibility of obtaining liquid and gaseous fuels from different types of biomass (BM) and combustible solid waste (CSW) of various origins. The available world reserves of traditional types of fuel are analyzed and a number of environmental shortcomings that created during their use are indicated. The tables present the data on the conditional calorific value (CCV) of the main traditional and alternative types of solid, liquid and gaseous fuels which compared with CCV of various types of BM and CSW. Possible methods for utilization of BM and CSW are analyzed, as well as the methods for converting them into alternative types of fuel, especially into combustible gases.Reliable information is given on the available oil and gas reserves in Azerbaijan. As a result of the research, it was revealed that the currently available oil reserves of Azerbaijan can completely dry out after 33.5 years, and gas reserves–after 117 years, without taking into account the growth rates of the exported part of these fuels to European countries. In order to fix this situation, first of all it is necessary to use as much as possible alternative and renewable energy sources, especially wind power plants (WPP) and solar photovoltaic energy sources (SFES) in the energy sector of the republic. Azerbaijan has large reserves of solar and wind energy. In addition, all regions of the country have large reserves of BM, and in the big cities, especially in industrial ones, there are CSW from which through pyrolysis and gasification is possible to obtain a high-quality combustible gas mixture, comprising: H2 + CO + CH4, with the least amount of harmful waste. The remains of the reaction of thermochemical decomposition of BM and CSW to combustible gases can also be used as mineral fertilizers in agriculture. The available and projected resources of Azerbaijan for the BM and the CSW are given, as well as their assumed energy intensity in the energy sector of the republic.Given the high energy intensity of the pyrolysis and gasification of the BM and CSW, at the present time for carrying out these reactions, the high-temperature solar installations with limited power are used as energy sources, and further preference is given to the use of WPP and SFES on industrial scale.

Download Full-text

Energetic properties of peat saturated with petroleum products

Safety and Reliability of Power Industry ◽

10.24223/1999-5555-2020-13-2-105-109 ◽

2020 ◽

Vol 13 (2) ◽

pp. 105-109

Author(s):

E. S. Dremicheva

Keyword(s):

Crude Oil ◽

Diesel Fuel ◽

Energy Use ◽

Experimental Studies ◽

Calorific Value ◽

Petroleum Products ◽

Ash Content ◽

Motor Oil ◽

Initial Sample

This paper presents a method of sorption using peat for elimination of emergency spills of crude oil and petroleum products and the possibility of energy use of oil-saturated peat. The results of assessment of the sorbent capacity of peat are presented, with waste motor oil and diesel fuel chosen as petroleum products. Natural peat has been found to possess sorption properties in relation to petroleum products. The sorbent capacity of peat can be observed from the first minutes of contact with motor oil and diesel fuel, and significantly depends on their viscosity. For the evaluation of thermal properties of peat saturated with petroleum products, experimental studies have been conducted on determination of moisture and ash content of as-fired fuel. It is shown that adsorbed oil increases the moisture and ash content of peat in comparison with the initial sample. Therefore, when intended for energy use, peat saturated with petroleum products is to be subjected to additional drying. Simulation of net calorific value has been performed based on the calorific values of peat and petroleum products with different ratios of petroleum product content in peat and for a saturated peat sample. The obtained results are compared with those of experiments conducted in a calorimetric bomb and recalculated for net calorific value. A satisfactory discrepancy is obtained, which amounts to about 12%. Options have been considered providing for combustion of saturated peat as fuel (burnt per se and combined with a solid fuel) and processing it to produce liquid, gaseous and solid fuels. Peat can be used to solve environmental problems of elimination of emergency spills of crude oil and petroleum products and as an additional resource in solving the problem of finding affordable energy.

Download Full-text

VALUE INCREASING OF REJECT COAL WITH BIOMASS ADDING AS BIO-COAL BRIQUETTE

INDONESIAN JOURNAL OF URBAN AND ENVIRONMENTAL TECHNOLOGY ◽

10.25105/urbanenvirotech.v3i2.5110 ◽

2020 ◽

Vol 3 (2) ◽

pp. 123

Author(s):

Dyah Marganingrum ◽

Lenny Marilyn Estiaty

Keyword(s):

Alternative Energy ◽

Ignition Time ◽

Bottom Ash ◽

Calorific Value ◽

Added Value ◽

Physical Test ◽

Chemical Test ◽

Agglomeration Process ◽

Strategic Solution ◽

Index Value

Aim: This paper aims to explain the added value increasing method of reject coal which has not utilized by the company. Methodology and Results: The method to increase added value in this study used the agglomeration process of briquettes form that changing composition by adding biomass. The biomass functions to minimize bottom ash produced from burning briquettes so that the briquettes burn entirely. Stages processes in this study consist of characterization, briquetting, physical test, and chemical test. Based on the analysis, reject coal still has a high calorific value of 5,929 cal/gr. Shapes and sizes that were not following needs of coal market or consumer due to reject coal to be a waste. Briquettes have been successfully produced and meet specification requirements based on applicable regulations in Indonesia. Besides physical properties, the briquette meet density requirements which are greater than or equal to 1 gr/cm3 and shatter index value is less than 0.5%. The gas emission test shows below threshold, which is CO 0-30 ppm, H2S 0-3.6 ppm, and NOx is not detected. After evaluation, it showed that by adding 30% biomass, ignition time could be decreased and remaining unburned briquettes or bottom ash was reduced as much as 68.68%. Conclusion, significance and impact study: The bio-coal briquettes is a strategic solution to environmental problems and alternative energy sources that are environmentally friendly, because CO and H2S emissions are still below the threshold, even for NOx not detected. Making Bio-coal briquettes as a solution to the utilization of reject coal mining waste to be used as an alternative energy source has been successfully carried out.

Download Full-text

Renewable Diesel Blendstocks and Biopriviliged Chemicals Distilled from Algal Biocrude Oil Converted via Hydrothermal Liquefaction

10.26434/chemrxiv.9630695 ◽

2019 ◽

Author(s):

Wan-Ting (Grace) Chen ◽

Zhenwei Wu ◽

Buchun Si ◽

Yuanhui Zhang

Keyword(s):

Oxidation Stability ◽

Ash Content ◽

Hydrothermal Liquefaction ◽

Fractional Distillation ◽

Chemical Compositions ◽

Steam Temperature ◽

Renewable Diesel ◽

Commodity Chemicals ◽

Biocrude Oil ◽

Specification Analysis

This study aims to produce renewable diesel and biopriviliged chemicals from microalgae that can thrive in wastewater environment. <i>Spirulina</i> (SP) was converted into biocrude oil at 300ºC for a 30-minute reaction time via hydrothermal liquefaction (HTL). Next, fractional distillation was used to separate SP-derived biocrude oil into different distillates. It was found that 62% of the viscous SP-derived biocrude oil can be separated into liquids at about 270ºC (steam temperature of the distillation). Physicochemical characterizations, including density, viscosity, acidity, elemental compositions, higher heating values and chemical compositions, were carried out with the distillates separated from SP-derived biocrude oil. These analyses showed that 15% distillates could be used as renewable diesel because they have similar heating values (43-46 MJ/kg) and carbon numbers (ranging from C8 to C18) to petroleum diesel. The Van Krevelan diagram of the distillates suggests that deoxygenation was effectively achieved by fractional distillation. In addition, GC-MS analysis indicates that some distillates contain biopriviliged chemicals like aromatics, phenols and fatty nitriles that can be used as commodity chemicals. An algal biorefinery roadmap was proposed based on the analyses of different distillates from the SP-derived biocrude oil. Finally, the fuel specification analysis was conducted with the drop-in renewable diesel, which was prepared with 10 vol.% (HTL10) distillates and 90 vol.% petroleum diesel. According to the fuel specification analysis, HTL10 exhibited a qualified lubricity (<520 µm), acidity (<0.3 mg KOH/g) and oxidation stability (>6 hr), as well as a comparable net heat of combustion (1% lower), ash content (29% lower) and viscosity (17% lower) to those of petroleum diesel. Ultimately, it is expected that this study can provide insights for potential application of algal biocrude oil converted via HTL.

Download Full-text