Exploring the relationship between the physical properties of activated carbon catalysts and their efficiency in catalyzing hydrogen iodide decomposition to produce hydrogen

Author(s):  
Sida Rong ◽  
Ran Zhang ◽  
Xiao Zhu ◽  
Mengze Zhang ◽  
Jun Li ◽  
...  
2011 ◽  
Vol 36 (1) ◽  
pp. 216-223 ◽  
Author(s):  
Zhihua Wang ◽  
Yun Chen ◽  
Chao Zhou ◽  
Ronald Whiddon ◽  
Yanwei Zhang ◽  
...  

2011 ◽  
Vol 105 (1-2) ◽  
pp. 30-40 ◽  
Author(s):  
P. Favuzza ◽  
C. Felici ◽  
L. Nardi ◽  
P. Tarquini ◽  
A. Tito

Author(s):  
C.E. Voegele-Kliewer ◽  
A.D. McMaster ◽  
G.W. Dirks

Materials other than polymers, e.g. ceramic silicates, are currently being investigated for gas separation processes. The permeation characteristics of one such material, Vycor (Corning Glass #1370), have been reported for the separation of hydrogen from hydrogen iodide. This paper will describe the electron microscopy techniques applied to reveal the porous microstructure of a Vycor membrane. The application of these techniques has led to an increased understanding in the relationship between the substructure and the gas transport properties of this material.


2011 ◽  
Vol 65 (12) ◽  
pp. 1293-1297
Author(s):  
Keiko Hashiguchi ◽  
Takehiro Yoshimatsu ◽  
Masanori Kawashima

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 504
Author(s):  
Yane Ansanay ◽  
Praveen Kolar ◽  
Ratna Sharma-Shivappa ◽  
Jay Cheng ◽  
Consuelo Arellano

In the present research, activated carbon-supported sulfonic acid catalysts were synthesized and tested as pretreatment agents for the conversion of switchgrass into glucose. The catalysts were synthesized by reacting sulfuric acid, methanesulfonic acid, and p-toluenesulfonic acid with activated carbon. The characterization of catalysts suggested an increase in surface acidities, while surface area and pore volumes decreased because of sulfonation. Batch experiments were performed in 125 mL serum bottles to investigate the effects of temperature (30, 60, and 90 °C), reaction time (90 and 120 min) on the yields of glucose. Enzymatic hydrolysis of pretreated switchgrass using Ctec2 yielded up to 57.13% glucose. Durability tests indicated that sulfonic solid-impregnated carbon catalysts were able to maintain activity even after three cycles. From the results obtained, the solid acid catalysts appear to serve as effective pretreatment agents and can potentially reduce the use of conventional liquid acids and bases in biomass-into-biofuel production.


2019 ◽  
Vol 81 (3) ◽  
Author(s):  
N. Masdiana ◽  
M. Rashid ◽  
S. Hajar ◽  
M. R. Ammar

TrikotAC filter aids is a combination of a pre-coating material PreKot™ with two adsorbents; activated carbon and lime and their characteristics were investigated in this study. TrikotAC was formulated into three different weight ratios of 5:1:94, 10:1:89 and 10:5:85, respectively. The relationship between adsorption properties and characteristics of the formulated materials particle size distribution, particle density, bulk density, and BET surface area were investigated. The results showed that the adsorption capacity for TrikotAC 10:5:85 (11.88 mg/g) was higher than for the other formulated filter aids samples, and the formulated filter aids material TrikotAC showed promising characteristic as a filter aids and adsorbent for organic compound in fabric filtration system.


2011 ◽  
Vol 243-249 ◽  
pp. 4956-4959
Author(s):  
Jian Chao Hao ◽  
Hui Fen Liu ◽  
Dong Ling Wei ◽  
Li Jun Shi ◽  
Jun Li Li ◽  
...  

The relationship between formaldehyde emission and time was researched and a mathematical model was developed which describes the variation of formaldehyde with time in the airtight chamber. It was found that high quality composite floor was in line with 0-order kinetic equation and low quality composite floor was in line with 1-order kinetic equation. Besides, the effect of activated carbon adsorption on formaldehyde was studied and the result showed that activated carbon had poor adsorption on formaldehyde for weak van der waals force.


2012 ◽  
Vol 501 ◽  
pp. 442-447
Author(s):  
Ping Fu ◽  
Feng Bao Bai ◽  
Chuan Sheng Wang ◽  
Shan Hu Li

In this paper adopting the orthogonal method, self-developed compound formulation had tested, and the relationship between the physical properties of vulcanized rubber and rectangular synchronous rotor mixer parameters had researched. The results showed that when the fill factor was 0.6, the rotor speed was 70r/min, cooling water temperature was 45 °C, pressure on the top bolt was 0.8Mpa, the physical properties of the vulcanized rubber was best.


2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Nicolás Carrara ◽  
Carolina Betti ◽  
Fernando Coloma-Pascual ◽  
María Cristina Almansa ◽  
Laura Gutierrez ◽  
...  

A series of low-loaded metallic-activated carbon catalysts were evaluated during the selective hydrogenation of a medium-chain alkyne under mild conditions. The catalysts and support were characterized by ICP, hydrogen chemisorption, Raman spectroscopy, temperature-programmed desorption (TPD), temperature-programmed reduction (TPR), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR micro-ATR), transmission electronic microscopy (TEM), and X-ray photoelectronic spectroscopy (XPS). When studying the effect of the metallic phase, the catalysts were active and selective to the alkene synthesis. NiCl/C was the most active and selective catalytic system. Besides, when the precursor salt was evaluated, PdN/C was more active and selective than PdCl/C. Meanwhile, alkyne is present in the reaction media, and geometrical and electronic effects favor alkene desorption and so avoid their overhydrogenation to the alkane. Under mild conditions, nickel catalysts are considerably more active and selective than the Lindlar catalyst.


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