Abstract
Owing to the sensitivity for color vicissitude by exposing to UV irradiation, manufacturing of fluorescent fabrics is widely demanded to be exploited in camping, sensing and military purposes. Pyrimidine based heterocycles were investigated with excellent pharmacological activity, however, their photoluminescence activity was never been investigated till now. The presented approach demonstrate a quite novel route for manufacturing of potential military textiles (fluorescent/UV-protective cotton fabrics with micobicide activity) via exploitation of carbon quantum dots (CQDs) nucleated from pyrimidine based heterocycle (4-(2,4-dichlorophenyl)-6-oxo-2-thioxohexahydropyrimidine-5-carbonitrile, Target Molecule, TM). The synthesized TM & CQDs were separately immobilized within both of native and cationized cotton fabrics to obtain TM@cotton, CQDs@cotton, TM@Q-cotton and CQDs@Q-cotton fabrics. The estimated yellowness index, intensity of the fluorescence peak, UV-blocking activity and microbicide action, were all followed the order of CQDs@Q-cotton > TM@Q-cotton > CQDs@cotton > TM @cotton. CQDs@Q-cotton showed quite good durability, as after 5 washings, yellowness index was diminished from 26.5 to only 20.3, florescence intensity for CQDs@Q-cotton was decreased from 540 nm to 340 nm and transmission percent was increased from 7 % to 10 %. Moreover, even after 10 washings, microbial inhibition (as a percent) against E. coli, Staphylococcus aureus and Candida albicans was estimated to 63 %, 68 % and 67 %, respectively, while, UV protection factor (UPF) was diminished from 38.2 (very good) to 21.5 (good). The presented unique route was succeeded for manufacturing of durable fluorescent textiles that could be superiorly applied as potential military textiles.