High quality oil recovery from oil-based drill cuttings via catalytic upgrading in presence of near-/supercritical water and different industrial wastes

2021 ◽  
Vol 321 ◽  
pp. 129061
Author(s):  
Zhong Chen ◽  
Kun Tong ◽  
Chunlan He ◽  
Ming Xue ◽  
Chong Lyu ◽  
...  
SPE Journal ◽  
2019 ◽  
Vol 24 (03) ◽  
pp. 1057-1075 ◽  
Author(s):  
Jinyu Tang ◽  
Mohammed N. Ansari ◽  
William R. Rossen

Summary The effectiveness of foam for mobility control in the presence of oil is key to foam enhanced oil recovery (EOR). A fundamental property of foam EOR is the existence of two steady-state flow regimes: the high-quality regime and the low-quality regime. Experimental studies have sought to understand the effect of oil on foam through its effect on these two regimes. Here, we explore the effect of oil on the two flow regimes for one widely used foam model. The STARS (CMG 2015) foam model includes two algorithms for the effect of oil on foam: In the “wet-foam” model, oil changes the mobility of full-strength foam in the low-quality regime, and in the “dry-out” model, oil alters the limiting water saturation around which foam collapses. We examine their effects as represented in each model on the two flow regimes using a Corey relative permeability function for oil. Specifically, we plot the pressure-gradient contours that define the two flow regimes as a function of superficial velocities of water, gas, and oil, and show how oil shifts behavior in the regimes. The wet-foam model shifts behavior in the low-quality regime with no direct effect on the high-quality regime. The dry-out model shifts behavior in the high-quality regime but not the low-quality regime. At fixed superficial velocities, both models predict multiple steady states at some injection conditions. We perform a stability analysis of these states using a simple 1D simulator with and without incorporating capillary diffusion. The steady state attained after injection depends on the initial state. In some cases, it appears that the steady state at the intermediate pressure gradient is inherently unstable, as represented in the model. In some cases, the introduction of capillary diffusion is required to attain a uniform steady state in the medium. The existence of multiple steady states, with the intermediate one being unstable, is reminiscent of catastrophe theory and of studies of foam generation without oil.


Author(s):  
V. Z. Abdrakhimov

The results of the studies showed that it is possible to obtain high-quality light-weight refractories based on industrial waste (the clay part of the gravity tailings of zircon-ilmenite ores ― non-ferrous metallurgy and drill cuttings ― oil production) without using traditional natural materials. Ill. 2. Ref. 17. Tab. 6.


SPE Journal ◽  
2016 ◽  
Vol 21 (05) ◽  
pp. 1669-1687 ◽  
Author(s):  
W.. Lee ◽  
S.. Lee ◽  
M.. Izadi ◽  
S. I. Kam

Summary Numerous laboratory and field tests reveal that foam can effectively control gas mobility and improve sweep efficiency, if correctly designed. It is believed that there is a significant gap between small laboratory-scale experiments and large field-scale tests because of two main reasons: (1) Typical laboratory flow tests are conducted in linear systems, whereas field-scale foam enhanced-oil-recovery (EOR) processes are performed in radial (or spherical partly) systems and (2) through the complicated in-situ lamella creation/coalescence mechanisms and non-Newtonian behavior, foam rheology depends on the geometry and dimensionality. As a result, it is still an open question as to how to translate laboratory-measured data to field-scale treatments. Motivated by earlier studies of Kovscek et al. (1994, 1997), this study investigates how such dimensionality-dependent foam rheological properties are affected by different injection conditions on small and large scales, with a mechanistic foam-modeling technique. Complex foam-flow characteristics such as three foam states (weak-foam, strong-foam, and intermediate states) and two steady-state strong-foam regimes (high-quality regime and low-quality regime) lie in the heart of this analysis. The calculation results from small radial and spherical systems showed that (1) for strong foams in the low-quality regime injected, foam mobility decreased [or mobility reduction factor (MRF) increased] significantly with distance showing a good sweep efficiency; (2) for strong foams in the high-quality regime, the situation became more complicated—near the well, foam mobility decreased, but away from the well, foam mobility increased with distance, which eventually gave a relatively low sweep efficiency; and (3) for weak foams injected, foam mobility increased with distance showing a poor sweep efficiency. The results implied that the use of a fixed value of MRF, which is a common practice in field-scale reservoir simulations, might lead to a significant error. When the method was applied to a larger scale, it was shown that strong foams could propagate deeper into the reservoir at higher injection rate, higher injection pressure, and at lower injection foam quality. Foam-propagation distance was very sensitive to these injection conditions for strong foams in the high-quality regime, but much less sensitive for strong foams in the low-quality regime.


2016 ◽  
Vol 116 ◽  
pp. 105-112 ◽  
Author(s):  
Peigao Duan ◽  
Yuping Xu ◽  
Feng Wang ◽  
Bing Wang ◽  
Weihong Yan

Author(s):  
Shuting Fu ◽  
Wenbiao Wu

The extraction of oil by a new aqueous method has been promoted because it is environmentally friendly, safe and economical of cost. A new aqueous method using 1.4:10.0 water-to-pecan kernel slurry ratio was developed, which recovered 97.73% of oils from the kernel containing 70.47% crude oil content. The method had a higher oil recovery as compared to enzyme-assisted extraction or solvent extraction or cold pressing in terms of producing oil for safe consumption. The method recovered oils with 0.47 mg KOH/g acid value and 0.34 mmol/kg peroxide value which were identical to that obtained by enzyme-assisted aqueous method and lower than that obtained by solvent extraction. The de-oiled pecan meal obtained by the new aqueous method only contained 5.14% residual oils, which was edible since no harmful chemical was added during oil extraction. No waste water was produced during the aqueous extraction of oils.


2021 ◽  
Author(s):  
Ying Li ◽  
Ying Ai ◽  
Haitao Li ◽  
Mingjun Chen

Abstract Tight sandstone reservoirs are an important petroleum resources in recent years. Hydraulic fracturing is widely used to stimulate development of tight sandstone oil reservoirs by creating underground fractures, but the low flowback rate of fracturing fluid leads to the water blocking damage and low oil recovery of tight sandstone oil reservoirs compared with those of conventional oil reservoirs. The object of this study is to experimentally investigate the possibility of improving flowback efficiency and oil recovery efficiency through achievement of the supercritical water condition. Self-developed reaction system is used to conduct hydraulic fracturing for tight sandstone samples under both regular and supercritical conditions. While comparing the oil recovery factor and flowback efficiency of the regular and supercritical water hydraulic fracturing, mechanisms behind these results are explored through examination of the change in oil components, the change in rock minerals and the change in pore-fracture distribution. Results show that the dynamic viscosity of the crude oil after the supercritical water hydraulic fracturing is significantly lower than that before hydraulic fracturing, with a decrease of 2.88 mPa·s under ambient condition and a decrease of 0.39 mPa·s under in situ condition. Lighter oil components occupy more percentage of the totoal oil components in the recovered oil from supercritical water hydraulic fracturing than that in the oil recovered from regular hydraulic fracturing, with an average increase of 16% for the oil components of molecular weight from 100 to 200. Heavier oil components of molecular weight larger than 300 have an average decrease of 15.5% after the supercritical water hydraulic fracturing. This indicate the visbreaking of the crude oil under the supercritical water condition. Oil recovery after supercritical water hydraulic fracturing is always higher than that after regular hydraulic fracturing, and the ultimate oil recovery after supercritical water hydraulic fracturing is 66.5% compared with 60% of regular hydraulic fracturing. Fracturing fluid after the supercritical water condition flows much quicker and smoothly than that after the regular hydraulic fracturing, and the ultimate flow back factor of the fracturing fluid is 63% after the supercritical water hydraulic fracturing compared with that of 49% after the regular hydraulic fracturing. Increase in percentage of larger pores/fractures after the supercritical water hydraulic fracturing is more significant than that after regular hydraulic fracturing. The percentage of interstratified illite-montmorillonite decreases an average of 15.2%, while that of kaolinite increase an average of 14.3% in the rock samples after supercritical water hydraulic fracturing compared with the original rock samples. This will benefit the recovery process when oil and water flows together into the well bore after the hydraulic fracturing.


Fuel ◽  
2021 ◽  
pp. 122702
Author(s):  
Richard Djimasbe ◽  
Mikhail A. Varfolomeev ◽  
Ameen A. Al-Muntaser ◽  
Chengdong Yuan ◽  
Dmitriy A. Feoktistov ◽  
...  

SPE Journal ◽  
2021 ◽  
pp. 1-16
Author(s):  
Jiaxi Gao ◽  
Yuedong Yao ◽  
Dawen Wang ◽  
Hang Tong

Summary Supercritical water has been proved effective in heavy-oil recovery. However, understanding the flow characteristics of supercritical water in the wellbore is still in the early stages. In this paper, using the theory of heat transfer and fluid mechanics and combining that with the physical properties of supercritical water, a heat-transfer model for vertical wellbore injection with supercritical water is established. The influence of heat transfer and the Joule-Thomson effect on the temperature of supercritical water are considered. Results show the following: The predicted values of pressure and temperature are in good agreement with the test values. The apparent pressure of supercritical water at the upper end of the wellbore is lower than the apparent pressure at the lower end. However, the equivalent pressure of supercritical water at the upper end of the wellbore is higher than the equivalent pressure at the lower end. The apparent pressure of supercritical water is affected by three factors: flow direction, overlying pressure, and Joule-Thomsoneffect. The closer to the bottom of the well, the greater the overlying pressure of the supercritical water, resulting in an increase in apparent pressure and the density of the supercritical water. As the injection time for supercritical water increases, the temperature around the upper horizontal wellbore increases.


Fuel ◽  
2019 ◽  
Vol 235 ◽  
pp. 460-472 ◽  
Author(s):  
Muhammad Kashif Khan ◽  
Handi Setiadi Cahyadi ◽  
Sung-Min Kim ◽  
Jaehoon Kim

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