scholarly journals Revisiting the Redox Transitions of Polyaniline. Semiquantitative Interpretation of Electrochemically Induced IR Bands

Author(s):  
F. Huerta ◽  
C. Quijada ◽  
F. Montilla ◽  
E. Morallón
Keyword(s):  
2021 ◽  
Vol 11 (4) ◽  
pp. 1544
Author(s):  
Meguya Ryu ◽  
Yoshiaki Nishijima ◽  
Shinya Morimoto ◽  
Naoki To ◽  
Tomoki Hashizume ◽  
...  

The four polarisation method is adopted for measurement of molecular orientation in dielectric nanolayers of metal-insulator-metal (MIM) metamaterials composed of gold nanodisks on polyimide and gold films. Hyperspectral mapping at the chemical finger printing spectral range of 4–20 μμm was carried out for MIM patterns of 1–2.5 μμm period (sub-wavelength). Overlay images taken at 0,π4,π2,3π4 orientation angles and subsequent baseline compensation are shown to be critically important for the interpretation of chemical mapping results and reduction of spurious artefacts. Light field enhancement in the 60-nm-thick polyimide (I in MIM) was responsible for strong absorption at the characteristic polyimide bands. Strong absorbance A at narrow IR bands can be used as a thermal emitter (emittance E=1−R), where R is the reflectance and A=1−R−T, where for optically thick samples the transmittance is T=0.


1994 ◽  
Vol 14 (1-3) ◽  
pp. 155-160 ◽  
Author(s):  
Tatsuhisa Kato

Absorption spectra are detected for C60− and C602− produced electrolytically in solution at room temperature. Theoretical analysis of the spectrum of C60− by CNDO/S calculations gives an interpretation of the characteristic near-IR bands, the weak visible bands, and the strong bands in the UV region. The emission spectrum of C60− is a mirror image of the near-IR absorption band, and the detection of the emission reconfirms our original assignment of the absorption spectrum. The nature of the spectrum of C602− is characterized by a similar orbital picture to that of C60−. Further laser experiments of significance are proposed.


Author(s):  
J. A. Leñero-Bardallo ◽  
J. Bernabéu-Wittel ◽  
J. Ceballos-Cáceres ◽  
Á. Rodríguez-Vázquez
Keyword(s):  

2019 ◽  
Vol 92 (1) ◽  
pp. 80-86 ◽  
Author(s):  
Hitomi Okabe ◽  
Daisuke Miyata ◽  
Takakazu Nakabayashi ◽  
Hirotsugu Hiramatsu
Keyword(s):  

2005 ◽  
Vol 69 (2) ◽  
pp. 155-167 ◽  
Author(s):  
B. J. Reddy ◽  
R. L. Frost ◽  
W. N. Martens

AbstractThe mineral conichalcite from the western part of Bagdad mine, Bagdad, Eureka District, Yavapai County, Arizona, USA has been characterized by electronic, near-infrared (NIR), Raman and infrared (IR) spectroscopy. Scanning electron microscopy (SEM) images show that the mineral consists of bundles of fibres. Calculations based on the results of the energy dispersive X-ray analyses on a stoichiometric basis show the substitution of arsenate by 12 wt.% of phosphate in the mineral. Raman and IR bands are assigned in terms of the fundamental modes of AsO43− and PO43− molecules and are related to the mineral structure. Near-IR reflectance spectroscopy shows the presence of adsorbed water and hydroxyl units in the mineral. The Cu(II) coordination polyhedron in conichalcite can have at best pseudo-tetragonal geometry. The crystal field and tetragonal field parameters of the Cu(II) complex were calculated and found to agree well with the values reported for known tetragonal distortion octahedral complexes.


2012 ◽  
Vol 10 (H16) ◽  
pp. 699-700 ◽  
Author(s):  
Christine Joblin

AbstractWhen referring to unidentified infrared emission features, one has in mind the series of aromatic IR bands (AIBs) between 3.3 and 15 μm that are observed in emission in many environments where UV photons irradiate interstellar matter. These bands are now used by astronomers to classify objects and characterize local physical conditions. However, a deep analysis cannot proceed without understanding the properties of the band carriers. Large polycyclic aromatic hydrocarbon molecules are attractive candidates but interstellar species are still poorly characterized. Various studies emphasize the need for tackling the link between molecular aromatic species, aliphatic material and very small carbonaceous grains. Other unidentified emission features such as the 6.9, 21 and 30 μm bands could be involved in the evolutionary scenario.


Polymers ◽  
2021 ◽  
Vol 13 (16) ◽  
pp. 2773
Author(s):  
Ion Smaranda ◽  
Andreea Nila ◽  
Paul Ganea ◽  
Monica Daescu ◽  
Irina Zgura ◽  
...  

This paper prepared composites under the free membranes form that are based on thermoplastic polymers of the type of polyurethane (TPU) and polyolefin (TPO), which are blended in the weight ratio of 2:1, and ceramic nanoparticles (CNs) such as BaSrTiO3 and SrTiO3. The structural, optical, and conductive properties of these new composite materials are reported. The X-ray diffraction studies highlight a cubic crystalline structure of these CNs. The main variations in the vibrational properties of the TPU:TPO blend induced by CNs consist of the following: (i) the increase in the intensity of the Raman line of 1616 cm−1; (ii) the down-shift of the IR band from 800 to 791 cm−1; (iii) the change of the ratio between the absorbance of IR bands localized in the spectral range 950–1200 cm−1; and (iv) the decrease in the absorbance of the IR band from 1221 cm−1. All these variations were correlated with a preferential adsorption of thermoplastic polymers on the CNs surface. A photoluminescence (PL) quenching process of thermoplastic polymers is demonstrated to occur in the presence of CNs. The anisotropic PL measurements have highlighted a change in the angle of the binding of the TPU:TPO blend, which varies from 23.7° to ≈49.3° and ≈53.4°, when the concentration of BaSrTiO3 and SrTiO3 CNs, respectively, is changed from 0 to 25 wt. %. Using dielectric spectroscopy, two mechanisms are invoked to take place in the case of the composites based on TPU:TPO blends and CNs, i.e., one regarding the type of the electrical conduction and another specifying the dielectric–dipolar relaxation processes.


2021 ◽  
Vol 13 (16) ◽  
pp. 3120
Author(s):  
Fei Tang ◽  
Xiaoyong Zhuge ◽  
Mingjian Zeng ◽  
Xin Li ◽  
Peiming Dong ◽  
...  

This study applies the Advanced Radiative Transfer Modeling System (ARMS), which was developed to accelerate the uses of Fengyun satellite data in weather, climate, and environmental applications in China, to characterize the biases of seven infrared (IR) bands of the Advanced Geosynchronous Radiation Imager (AGRI) onboard the Chinese geostationary meteorological satellite, Fengyun–4A. The AGRI data are quality controlled to eliminate the observations affected by clouds and contaminated by stray lights during the mid–night from 1600 to 1800 UTC during spring and autumn. The mean biases, computed from AGRI IR observations and ARMS simulations from the National Center for Environmental Prediction (NCEP) Final analysis data (FNL) as input, are within −0.7–1.1 K (0.12–0.75 K) for all seven IR bands over the oceans (land) under clear–sky conditions. The biases show seasonal variation in spatial distributions at bands 11–13, as well as a strong dependence on scene temperatures at bands 8–14 and on satellite zenith angles at absorption bands 9, 10, and 14. The discrepancies between biases estimated using FNL and the European Center for Medium–Range Weather Forecasts Reanalysis–5 (ERA5) are also discussed. The biases from water vapor absorption bands 9 and 10, estimated using ERA5 over ocean, are smaller than those from FNL. Such discrepancies arise from the fact that the FNL data are colder (wetter) than the ERA5 in the middle troposphere (upper–troposphere).


Holzforschung ◽  
2016 ◽  
Vol 70 (4) ◽  
pp. 305-312 ◽  
Author(s):  
Shengzhen Cai ◽  
Mohamed Jebrane ◽  
Nasko Terziev

Abstract Scots pine sapwood was treated with a new formulation consisting of vinyl acetate (VAc) and epoxidized linseed oil (ELO) catalyzed by potassium persulfate to impart protection to wood. The effects of various curing temperatures, durations, and solution uptakes on dimensional stability (DS) and leachability were studied. The new formulation provided good anti-swelling efficiency (ASE) ranging from 35% to 47% with negligible leaching of the treating agent after four cycles of water soaking and oven drying (2%–2.5%). The extent of polymerization in wood was observed by FTIR-attenuated total reflectance (FTIR-ATR) by evaluation of the areas below typical IR bands as a function of curing temperature and time. Linear relationships were found with high R2 values. The FTIR data of extracted samples were interpreted that chemical reactions took place between the resulting copolymer and wood components.


2005 ◽  
Vol 23 (6) ◽  
pp. 425-436
Author(s):  
Toshinori Mori ◽  
Yasushige Kuroda ◽  
Ryotaro Kumashiro ◽  
Koji Hirata ◽  
Hidehiro Toyota ◽  
...  

Interactions between the surfaces of alkaline earth fluorides (CaF2, SrF2 and BaF2) and water molecules were investigated by calorimetric and spectroscopic methods. The exposed surfaces of the alkaline earth fluoride samples, with which the (100) crystalline plane is mainly associated, were found to be fully covered with strongly adsorbed water molecules, resulting in characteristic IR bands at 3684, 2561, 1947 and 1000 cm−1, respectively. This surface was homogeneous towards further water adsorption. The strongly adsorbed water molecules were almost completely desorbed from the surface on evacuating the sample up to 473 K. The heat of immersion in water also increased with increasing pretreatment temperature; this may be attributed to surface rehydration of the alkaline earth fluorides. The state of the surface changed drastically as the pretreatment temperature was increased and stabilized towards incoming water molecules. Thus, the surface formed after evacuation at temperatures greater than 473 K was resistant to hydration even after immersion in water at room temperature. This surface was relatively heterogeneous towards water adsorption, although it behaved homogeneously towards argon adsorption. These facts indicate that strongly adsorbed water molecules appear to be somewhat specific towards the adsorption of further incoming water molecules. The adsorption properties of the (100) plane of alkaline earth fluorides towards water and argon molecules depend strongly on both the electrostatic field strength and the extent of rehydration of the alkaline earth fluoride surface.


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