Evolution of pore structure and fractal characteristics of coal char during coal gasification

2020 ◽  
Vol 93 (5) ◽  
pp. 1999-2005
Author(s):  
Daqian Wang ◽  
Haiping Yang ◽  
Yang Wu ◽  
Chuang Zhao ◽  
Fudong Ju ◽  
...  
Keyword(s):  
Pore Structure ◽  
Coal Gasification ◽  
Coal Char ◽  
Fractal Characteristics

scholarly journals Coal char characteristics variation in the gasification process and its influencing factors

2020 ◽  
Vol 38 (5) ◽  
pp. 1559-1573
Author(s):  
Zhenyong Yin ◽  
Hao Xu ◽  
Yanpen Chen ◽  
Tiantian Zhao
Keyword(s):  
Specific Surface ◽  
Pore Structure ◽  
Surface Area ◽  
Inner Mongolia ◽  
Coal Gasification ◽  
Coal Char ◽  
Gasification Process ◽  
Effective Component ◽  
Gasification Temperature ◽  
Better Than

Underground coal gasification is a burgeoning coal exploitation technique that coal is directly converted into gaseous fuel by controlled combustion. In this paper, the gasification experiments of Inner Mongolia lignite, Xinjiang subbituminous coal, and Hancheng medium volatile bitumite were conducted respectively by using the tube furnace coal gasification experiment system. The gasification process was conducted under 3°C/min increment within the range of 600–900°C. The gas composition was analyzed by gas chromatography and the pore structure of the coal char was detected by low-temperature N2 adsorption. The results show that the gasification temperature, gasification agent, and coal type have an important influence on the gasification reaction. With the increase of gasification temperature, the effective component, gas calorific value, and gas production rate increase. When CO2 is used as the gasifying agent, the effective components in the gas are mainly CO. When H2O(g) is used as the gasifying agent, the effective component of gas is H2. The coal gasification performance with low thermal maturity is obvious better than the high rank coal with higher coalification. N2 adsorption–desorption experiments show that the pore is mainly composed by transition pore and the micropores, the specific surface area is chiefly controlled by a pore size of 2–3 nm. With the increase of coalification degree, the adsorption amount, specific surface area, and total pore volume show a decreasing trend. The gasifying agent has a great influence on the pore structure of the coal char. The gasification effect of H2O (g) is significantly better than that of CO2. Analyzing the gasification characteristics and pore changes of different coal rank coals under different gasification agents, we found that Inner Mongolia lignite is more conducive to the transport of gasification agents and gaseous products in coal.

scholarly journals Effect of Grain Size on Microscopic Pore Structure and Fractal Characteristics of Carbonate-Based Sand and Silicate-Based Sand

2021 ◽  
Vol 5 (4) ◽  
pp. 152
Author(s):  
Shao-Heng He ◽  
Zhi Ding ◽  
Hai-Bo Hu ◽  
Min Gao
Keyword(s):  
Grain Size ◽  
Fractal Dimension ◽  
Pore Structure ◽  
Pore Size ◽  
Quartz Sand ◽  
Glass Bead ◽  
Fractal Theory ◽  
Calcareous Sand ◽  
Wide Range ◽  
Fractal Characteristics

In this study, a series of nuclear magnetic resonance (NMR) tests was conducted on calcareous sand, quartz sand, and glass bead with a wide range of grain sizes, to understand the effect of grain size on the micro-pore structure and fractal characteristics of the carbonate-based sand and silicate-based sand. The pore size distribution (PSD) of the tested materials were obtained from the NMR T2 spectra, and fractal theory was introduced to describe the fractal properties of PSD. Results demonstrate that grain size has a significant effect on the PSD of carbonate-based sand and silicate-based sand. As grain size increases, the PSD of sands evolves from a binary structure with two peaks to a ternary structure with three peaks. The increase in the grain size can cause a remarkable increase in the maximum pore size. It is also found that the more irregular the particle shape, the better the continuity between the large and medium pores. In addition, grain size has a considerable effect on the fractal dimension of the micro-pore structure. The increase of grain size can lead to a significant increase in the heterogeneity and fractal dimension in PSD for calcareous sand, quartz sand and glass bead.

scholarly journals Experimental Study on the Fractal Features and Permeability Characteristics of Low Metamorphic Coal Pore Structure under Thermal Damage

Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-13
Author(s):  
Zhen Liu ◽  
Mingrui Zhang ◽  
Shijian Yu ◽  
Lin Xin ◽  
Gang Wang ◽  
...  
Keyword(s):  
Experimental Study ◽  
Pore Structure ◽  
Coal Gasification ◽  
Thermal Damage ◽  
Fractal Model ◽  
Utilization Efficiency ◽  
Heating Process ◽  
Underground Coal Gasification ◽  
External Temperature ◽  
Permeability Characteristics

Underground coal gasification and exploitation of geothermal mine resources can effectively improve coal conversion and utilization efficiency, and the basic theory of the above technologies generally relies on the change law of the coal pore structure under thermal damage. Therefore, the influence mechanism of the development of the coal pore structure under thermal damage is analyzed by the nuclear magnetic resonance experiment, and the temperature-permeability fractal model is created. The results show that compared with microtransitional pores, the volume of meso-macropores in the coal body is more susceptible to an increase in temperature, which was most obvious at 200-300°C. During the heating process, the measured fractal dimension based on the T2 spectral distribution is between 2 and 3, indicating that the fractal characteristics did not disappear upon a change in external temperature. The temperature has a certain negative correlation with DmNMR, DMNMR, and DNMR, indicating that the complexity of the pore structure of the coal body decreased gradually with the increase of the temperature. Compared with the permeability calculated based on the theoretical permeability fractal model, the permeability obtained from the temperature-permeability fractal model has a similar increasing trend as the permeability measured by the NMR experiment when the temperature increases. The experimental study on pore structure and permeability characteristics of the low metamorphic coal under thermal damage provides a scientific theory for underground coal gasification and geothermal exploitation.

scholarly journals The Impacts of Matrix Compositions on Nanopore Structure and Fractal Characteristics of Lacustrine Shales from the Changling Fault Depression, Songliao Basin, China

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 127 ◽  
Author(s):  
Zhuo Li ◽  
Zhikai Liang ◽  
Zhenxue Jiang ◽  
Fenglin Gao ◽  
Yinghan Zhang ◽  
...  
Keyword(s):  
Fractal Dimension ◽  
Pore Structure ◽  
Fractal Dimensions ◽  
Organic Medium ◽  
Songliao Basin ◽  
Sem Images ◽  
Fractal Characteristics ◽  
Inorganic Mineral ◽  
Nanopore Structure ◽  
High Fractal Dimension

The Lower Cretaceous Shahezi shales are the targets for lacustrine shale gas exploration in Changling Fault Depression (CFD), Southern Songliao Basin. In this study, the Shahezi shales were investigated to further understand the impacts of rock compositions, including organic matters and minerals on pore structure and fractal characteristics. An integrated experiment procedure, including total organic carbon (TOC) content, X-ray diffraction (XRD), field emission-scanning electron microscope (FE-SEM), low pressure nitrogen physisorption (LPNP), and mercury intrusion capillary pressure (MICP), was conducted. Seven lithofacies can be identified according to on a mineralogy-based classification scheme for shales. Inorganic mineral hosted pores are the most abundant pore type, while relatively few organic matter (OM) pores are observed in FE-SEM images of the Shahezi shales. Multimodal pore size distribution characteristics were shown in pore width ranges of 0.5–0.9 nm, 3–6 nm, and 10–40 nm. The primary controlling factors for pore structure in Shahezi shales are clay minerals rather than OM. Organic-medium mixed shale (OMMS) has the highest total pore volumes (0.0353 mL/g), followed by organic-rich mixed shale (ORMS) (0.02369 mL/g), while the organic-poor shale (OPS) has the lowest pore volumes of 0.0122 mL/g. Fractal dimensions D1 and D2 (at relative pressures of 0–0.5 and 0.5–1 of LPNP isotherms) were obtained using the Frenkel–Halsey–Hill (FHH) method, with D1 ranging from 2.0336 to 2.5957, and D2 between 2.5779 and 2.8821. Fractal dimensions are associated with specific lithofacies, because each lithofacies has a distinctive composition. Organic-medium argillaceous shale (OMAS), rich in clay, have comparatively high fractal dimension D1. In addition, organic-medium argillaceous shale (ORAS), rich in TOC, have comparatively high fractal dimension D2. OPS shale contains more siliceous and less TOC, with the lowest D1 and D2. Factor analysis indicates that clay contents is the most significant factor controlling the fractal dimensions of the lacustrine Shahezi shale.

Adsorption pore structure and its fractal characteristics of coals by N2 adsorption/desorption and FESEM image analyses

Fuel ◽  
2019 ◽  
Vol 257 ◽  
pp. 116031 ◽  
Author(s):  
Zhentao Li ◽  
Dameng Liu ◽  
Yidong Cai ◽  
Yunpeng Wang ◽  
Juan Teng
Keyword(s):  
Pore Structure ◽  
Fesem Image ◽  
N2 Adsorption ◽  
Fractal Characteristics ◽  
Adsorption Desorption ◽  
Image Analyses
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