High resolution emission FT spectra of sodium in a microwave discharge: Intensity variation of the D1/D2 lines in exoplanetary atmospheres

Author(s):  
Svatopluk Civiš ◽  
Alan N. Heays ◽  
Antonín Knížek ◽  
Martin Ferus
Author(s):  
M. Kelly ◽  
D.M. Bird

It is well known that strain fields can have a strong influence on the details of HREM images. This, for example, can cause problems in the analysis of edge-on interfaces between lattice mismatched materials. An interesting alternative to conventional HREM imaging has recently been advanced by Pennycook and co-workers where the intensity variation in the annular dark field (ADF) detector is monitored as a STEM probe is scanned across the specimen. It is believed that the observed atomic-resolution contrast is correlated with the intensity of the STEM probe at the atomic sites and the way in which this varies as the probe moves from cell to cell. As well as providing a directly interpretable high-resolution image, there are reasons for believing that ADF-STEM images may be less suseptible to strain than conventional HREM. This is because HREM images arise from the interference of several diffracted beams, each of which is governed by all the excited Bloch waves in the crystal.


1968 ◽  
Vol 46 (13) ◽  
pp. 1539-1546 ◽  
Author(s):  
R. Colin

The 0–0, 1–1, 2–2, and 0–1 bands of the b1Σ+–X3Σ− transition of the SO molecule have been observed in the afterglow produced when COS + O2 is pumped rapidly through a microwave discharge. The two strongest bands, 0–0 and 1–1, which lie respectively at 9549.08 and 9626.13 Å, have been photographed at high resolution and have been analyzed. Using the known X3Σ− rotational constants, the vibrational and rotational constants of the 1Σ+ state (Tc = 10 509.97 cm−1) have been determined: ωc′ = 1067.66 cm−1, Bc′ = 0.70262 cm−1, and rc′ = 1.5005 Å. Rotational intensity distributions for 1Σ+–3Σ− transitions are discussed. The a1Δ state of SO is predicted to lie at T ~ 6350 cm−1.


2020 ◽  
Author(s):  
Joe Zalesky ◽  
Michael Line ◽  
Matteo Brogi

<p>High Resolution Cross Correlation Spectroscopy (HRCCS) has become a powerful tool to constrain both the physical characteristics and abundances of atomic/molecular constituents in exoplanetary atmospheres. Brogi & Line (2019) recently introduced a novel Bayesian atmospheric retrieval methodology that can combine observations from both longer wavelength (2-4 micron), ground-based, HRCCS and shorter wavelength (1-2 micron) space-based observatories such as the Hubble Space Telescope (HST). Here we present results from the application of this technique to both new and previously published observations of HD209458b and HD189733b from VLT/CRIRES, HST, and Spitzer. The more complete wavelength coverage provides a more comprehensive assessment of the atmosphere by way of stronger constraints on the thermal profiles, atmospheric metallicity, and carbon/oxygen inventory for these two benchmark planets. We also investigate the impact of possible model-induced biases including assumptions regarding molecular cross-sections, cloud model prescriptions, and thermal profile parameterizations. Finally, we present what constraints may be possible in the future by performing retrievals of synthetic observations from the next generation of high-resolution spectrographs like CRIRES+. This work has laid a foundational dataset that combines both space and ground-based observations to comprehensively characterize exoplanetary atmospheres and will be a useful benchmark in comparison to future efforts for both transiting and non-transiting atmospheric characterization.</p>


2018 ◽  
Vol 612 ◽  
pp. A53 ◽  
Author(s):  
Lorenzo Pino ◽  
David Ehrenreich ◽  
Aurélien Wyttenbach ◽  
Vincent Bourrier ◽  
Valerio Nascimbeni ◽  
...  

Space-borne low- to medium-resolution (ℛ ~ 102–103) and ground-based high-resolution spectrographs (ℛ ~ 105) are commonly used to obtain optical and near infrared transmission spectra of exoplanetary atmospheres. In this wavelength range, space-borne observations detect the broadest spectral features (alkali doublets, molecular bands, scattering, etc.), while high-resolution, ground-based observations probe the sharpest features (cores of the alkali lines, molecular lines). The two techniques differ by several aspects. (1) The line spread function of ground-based observations is ~103 times narrower than for space-borne observations; (2) Space-borne transmission spectra probe up to the base of thermosphere (P ≳ 10−6 bar), while ground-based observations can reach lower pressures (down to ~10−11 bar) thanks to their high resolution; (3) Space-borne observations directly yield the transit depth of the planet, while ground-based observations can only measure differences in the apparent size of the planet at different wavelengths. These differences make it challenging to combine both techniques. Here, we develop a robust method to compare theoretical models with observations at different resolutions. We introduce πη, a line-by-line 1D radiative transfer code to compute theoretical transmission spectra over a broad wavelength range at very high resolution (ℛ ~ 106, or Δλ ~ 0.01 Å). An hybrid forward modeling/retrieval optimization scheme is devised to deal with the large computational resources required by modeling a broad wavelength range ~0.3–2 μm at high resolution. We apply our technique to HD 189733b. In this planet, HST observations reveal a flattened spectrum due to scattering by aerosols, while high-resolution ground-based HARPS observations reveal sharp features corresponding to the cores of sodium lines. We reconcile these apparent contrasting results by building models that reproduce simultaneously both data sets, from the troposphere to the thermosphere. We confirm: (1) the presence of scattering by tropospheric aerosols; (2) that the sodium core feature is of thermospheric origin. When we take into account the presence of aerosols, the large contrast of the core of the sodium lines measured by HARPS indicates a temperature of up to ~10 000K in the thermosphere, higher than what reported in the literature. We also show that the precise value of the thermospheric temperature is degenerate with the relative optical depth of sodium, controlled by its abundance, and of the aerosol deck.


2018 ◽  
Vol 619 ◽  
pp. A3 ◽  
Author(s):  
Lorenzo Pino ◽  
David Ehrenreich ◽  
Romain Allart ◽  
Christophe Lovis ◽  
Matteo Brogi ◽  
...  

Transmission spectroscopy with ground-based, high-resolution instruments provides key insight into the composition of exoplanetary atmospheres. Molecules such as water and carbon monoxide have been unambiguously identified in hot gas giants through cross-correlation techniques. A maximum in the cross-correlation function (CCF) is found when the molecular absorption lines in a binary mask or model template match those contained in the planet. Here, we demonstrate how the CCF method can be used to diagnose broadband spectroscopic features such as scattering by aerosols in high-resolution transit spectra. The idea consists in exploiting the presence of multiple water bands from the optical to the near-infrared. We have produced a set of models of a typical hot Jupiter spanning various conditions of temperature and aerosol coverage. We demonstrate that comparing the CCFs of individual water bands for the models constrains the presence and the properties of the aerosol layers. The contrast difference between the CCFs of two bands can reach ~100 ppm, which could be readily detectable with current or upcoming high-resolution stabilized spectrographs spanning a wide spectral range, such as ESPRESSO, CARMENES, HARPS-N+GIANO, HARPS+NIRPS, SPIRou, or CRIRES+.


1979 ◽  
Vol 57 (7) ◽  
pp. 1051-1058 ◽  
Author(s):  
R. Colin

Six bands of the b1Σ+–X3Σ− transition of the PBr molecule have been observed in a microwave discharge of PBr3 + He. High resolution spectra have allowed the rotational analysis of the 0–0 and 1–1 bands. The principal molecular constants obtained are:X3Σ−: P79Br; ωe = 458.35 cm−1, Be = 0.16067 cm−1; P81Br; ωe = 457.78 cm−1, Be = 0.15958 cm−1; re = 2.1714 Å.B1Σ+: P79Br; ωe = 485.47 cm−1, Be = 0.16509 cm−1; P81Br; ωe = 483.84 cm−1, Be = 0.16399 cm−1; re = 2.1421 Å and Te = 11779.75 cm−1.


1992 ◽  
Vol 70 (5) ◽  
pp. 291-294 ◽  
Author(s):  
Sheila Gopal ◽  
M. Singh ◽  
G. Lakshminarayana

The emission spectrum of Si130Te was excited by microwave discharge (2450 MHz) in a sealed quartz tube. The A1Π–X1Σ+ band system (3100–3900 Å) (1 Å = 10−10 m) photographed under high resolution on a 10.6 m Ebert grating spectrograph. The rotational analysis of 32 bands was carried out, which led to the determination of the accurate vibrational and rotational constants. The rotational structure belonging to ν′ > 9 levels appear to be perturbed.


2021 ◽  
Vol 162 (6) ◽  
pp. 233
Author(s):  
Anne Boucher ◽  
Antoine Darveau-Bernier ◽  
Stefan Pelletier ◽  
David Lafrenière ◽  
Étienne Artigau ◽  
...  

2018 ◽  
Vol 617 ◽  
pp. A134 ◽  
Author(s):  
F. Borsa ◽  
A. Zannoni

Context. In-depth studies of exoplanetary atmospheres are starting to become reality. In order to unveil their properties in detail, we need spectra with a higher signal-to-noise ratio (S/N) and also more sophisticated analysis methods. Aims. With high-resolution spectrographs, we can not only detect the sodium feature in the atmosphere of exoplanets, but also characterize it by studying its line profile. After finding a clearly w-shaped sodium line profile in the transmission spectrum of HD 189733b, we investigated the possible sources of contamination given by the star and tried to correct for these spurious deformations. Methods. By analyzing the single transmission spectra of HD 189733b in the wavelength space, we show that the main sodium signal that causes the absorption in the transmission spectrum is centered on the stellar rest frame. We concentrate on two main stellar effects that contaminate the exoplanetary transmission spectrum: center-to-limb variations (CLVs) and stellar rotation. We show the effects on the line profile: while we correct for the CLV using simulated theoretical stellar spectra, we provide a new method, based directly on observational data, to correct for the Rossiter–McLaughlin contribution to the line profile of the retrieved transmission spectrum. Results. We apply the corrections to the spectra of HD 189733b. Our analysis shows line profiles of the Na D lines in the transmission spectrum that are narrower than reported previously. The correction of the sodium D2 line, which is deeper than the D1 line, is probably still incomplete since the planetary radius is larger at this wavelength. A careful detrending from spurious stellar effects followed by an inspection in the velocity space is mandatory when studying the line profile of atmospheric features in the high-resolution transmission spectrum of exoplanets. Since the line profile is used to retrieve atmospheric properties, the resulting atmospheric parameters could be incorrectly estimated when the stellar contamination is not corrected for. Data with higher S/N coupled with improved atmospheric models will allow us to adapt the magnitude of the corrections of stellar effects in an iterative way.


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