Aqueous fluids and hydrous melts in high-pressure and ultra-high pressure rocks: Implications for element transfer in subduction zones

Lithos ◽  
2006 ◽  
Vol 92 (3-4) ◽  
pp. 399-417 ◽  
Author(s):  
J HERMANN ◽  
C SPANDLER ◽  
A HACK ◽  
A KORSAKOV
2012 ◽  
Vol 4 (1) ◽  
pp. 745-781 ◽  
Author(s):  
C. J. Warren

Abstract. The exhumation of high and ultra-high pressure rocks is ubiquitous in Phanerozoic orogens created during continental collisions, and is common in many ocean-ocean and ocean-continent subduction zone environments. Three different tectonic environments have previously been reported, which exhume deeply buried material by different mechanisms and at different rates. However it is becoming increasingly clear that no single mechanism dominates in any particular tectonic environment, and the mechanism may change in time and space within the same subduction zone. In order for buoyant continental crust to subduct, it must remain attached to a stronger and denser substrate, but in order to exhume, it must detach (and therefore at least locally weaken) and be initially buoyant. Denser oceanic crust subducts more readily than more buoyant continental crust but exhumation must be assisted by entrainment within more buoyant and weak material such as serpentinite or driven by the exhumation of structurally lower continental crustal material. Weakening mechanisms responsible for the detachment of crust at depth include strain, hydration, melting, grain size reduction and the development of foliation. These may act locally or may act on the bulk of the subducted material. Metamorphic reactions, metastability and the composition of the subducted crust all affect buoyancy and overall strength. Subduction zones change in style both in time and space, and exhumation mechanisms change to reflect the tectonic style and overall force regime within the subduction zone. Exhumation events may be transient and occur only once in a particular subduction zone or orogen, or may be more continuous or occur multiple times.


2020 ◽  
Author(s):  
Jungjin Lee ◽  
Haemyeong Jung ◽  
Reiner Klemd ◽  
Matthew Tarling ◽  
Dmitry Konopelko

<p>Strong seismic anisotropy is generally observed in subduction zones. Lattice preferred orientation (LPO) of olivine and elastically anisotropic hydrous minerals has been considered to be an important factor causing anomalous seismic anisotropy. For the first time, we report on measured LPOs of polycrystalline talc. The study comprises subduction-related ultra-high-pressure metamorphic schists from the Makbal Complex in Kyrgyzstan-Kazakhstan and amphibolite-facies metasomatic schists from the Valla Field Block in Unst, Scotland. The here studied talc revealed a strong alignment of [001] axes (sub)normal to the foliation and a girdle distribution of [100] axes and (010) poles (sub)parallel to the foliation. The LPOs of polycrystalline talc produced a significant P–wave anisotropy (AVp = 72%) and a high S–wave anisotropy (AVs = 24%). The results imply that the LPO of talc influence both the strong trench-parallel azimuthal anisotropy and positive/negative radial anisotropy of P–waves, and the trench-parallel seismic anisotropy of S–waves in subduction zones.</p>


2022 ◽  
Vol 13 (1) ◽  
Author(s):  
P. Bouilhol ◽  
B. Debret ◽  
E. C. Inglis ◽  
M. Warembourg ◽  
T. Grocolas ◽  
...  

AbstractSerpentinites are an important sink for both inorganic and organic carbon, and their behavior during subduction is thought to play a fundamental role in the global cycling of carbon. Here we show that fluid-derived veins are preserved within the Zermatt-Saas ultra-high pressure serpentinites providing key evidence for carbonate mobility during serpentinite devolatilisation. We show through the O, C, and Sr isotope analyses of vein minerals and the host serpentinites that about 90% of the meta-serpentinite inorganic carbon is remobilized during slab devolatilisation. In contrast, graphite-like carbonaceous compounds remain trapped within the host rock as inclusions within metamorphic olivine while the bulk elemental and isotope composition of organic carbon remains relatively unchanged during the subduction process. This shows a decoupling behavior of carbon during serpentinite dehydration in subduction zones. This process will therefore facilitate the transfer of inorganic carbon to the mantle wedge and the preferential slab sequestration of organic carbon en route to the deep mantle.


2021 ◽  
Author(s):  
Stefan Markus Schmalholz ◽  
Lorenzo Candioti ◽  
Joshua Vaughan-Hammon ◽  
Thibault Duretz

<p>Subduction zones are one of the main features of plate tectonics, they are essential for geochemical cycling and are often a key player during mountain building. However, several processes related to subduction zones remain elusive, such as the initiation of subduction or the exhumation of (ultra)high-pressure rocks.</p><p>Collision orogens, such as the European Alps or Himalayas, provide valuable insight into long-term subduction zone processes and the larger geodynamic cycles of plate extension and subsequent convergence. For the Alps, geological reconstructions suggest a horizontally forced subduction initiation caused by the onset of convergence between the Adriatic and European plates. During Alpine orogeny, the Piemont-Liguria basin and the European passive magma-poor margin (including the Briançonnais domain) were subducted below Adria. The petrological rock record indicates burial and subsequent exhumation of both continental and oceanic crustal rocks that were exposed to (ultra)high-pressure metamorphic conditions during their Alpine burial-exhumation cycle. Moreover, estimates of exhumation velocities yield magnitudes in the range of several mm/yr to several cm/yr. However, published estimates of exhumation velocities, ages of peak metamorphic conditions and estimates for peak pressure and peak temperature vary partly significantly, even for the same tectonic unit. Consequently, many, partly significantly, contrasting conceptual models for subduction initiation (convergence versus buoyancy driven) or rock exhumation (channel-flow, diapirism, episodic regional extension, erosion etc.) have been proposed for the Alps. </p><p>Complementary to the data-driven approach, mathematical models of the lithosphere and upper mantle system are useful tools to investigate geodynamic processes. These mathematical models integrate observational and experimental data with the fundamental laws of physics (e.g. conservation of mass, momentum and energy) and are useful to test conceptual models of subduction initiation and rock exhumation. Here, we present numerical solutions of two-dimensional petrological-thermo-mechanical models. The initial model configuration consists of an isostatically and thermally equilibrated lithosphere, which includes mechanical heterogeneities in the form of elliptical regions with different effective viscosity. We model a continuous geodynamic cycle of subsequent extension, no far-field deformation and convergence. During extension, the continental crust is necked, separated and mantle is exhumed, forming a marine basin bounded by passive margins. During the subsequent stage with no far-field deformation, the thermal field of the lithosphere is re-equilibrated above a convecting mantle. During convergence, subduction is initiated at one passive margin and the mantle lithosphere below the marine basin as well as the other passive margin are subducted. During progressive subduction, parts of the subducted continental upper crust are sheared-off the subducting plate and are exhumed to the surface, ultimately forming an orogenic wedge. For the convergence, we test the impact of serpentinites at the top of the exhumed mantle on orogenic wedge formation. We compare the model results with observational and experimental constraints, discuss the involved processes and driving forces and propose a model for subduction initiation and (ultra)high-pressure rock exhumation for the Alps.</p>


2020 ◽  
Author(s):  
Alexander Sokol ◽  
Igor Kupriyanov ◽  
Yurii Seryotkin ◽  
Ella Sokol

<p>The current flux of nitrogen into the mantle in subduction zones is about three times its amount outgassing at mid-ocean ridges, arc and intraplate volcanoes, i.e., some efficient nitrogen hosts and carriers should exist in slabs. The K<sup>+</sup> → (NH<sub>4</sub><sup>+</sup>) substitution in silicate minerals is possible only within limited redox-favorable parts of slabs. Whether nitrogen can be transported and immobilized in the mantle as part of solids by some redox-independent mechanisms? The experimental study of the muscovite-NH<sub>3</sub>-N<sub>2</sub>-H<sub>2</sub>O and eclogite+muscovite-NH<sub>3</sub>-N<sub>2</sub>-H<sub>2</sub>O systems at 6.3-7.8 GPa and 1000 to 1200°C shows that NH<sub>3</sub>- and N<sub>2</sub>-rich K-cymrite can be stable in metapelite and act as a redox insensitive carrier of nitrogen to mantle depths >200 km in downgoing slabs. This ability is related to its unique clathrate structure that can accommodate three species of nitrogen: N<sub>2</sub> and NH<sub>3</sub> molecules in cages and (NH<sub>4</sub>)<sup>+</sup> substituting for K<sup>+</sup>, while imprisoned N<sub>2</sub> and NH<sub>3</sub> were first discovered in cages of ultra-high pressure minerals. The storage capacity K-cymrite with respect to nitrogen increases from 2.9 to 6.3 wt.% with increase of fO<sub>2 </sub>from ~IW to ~NNO, at the N<sub>2</sub>/(NH<sub>3</sub>+N<sub>2</sub>) ratio in fluid from 0.1 to 0.9. Comparison of equilibrated muscovite and K-cymrite synthesized at 7.8 GPa, 1070°C, and fO<sub>2 </sub>~IW demonstrates that the clathrate mechanism of nitrogen entrapment by aluminosilicates (in the form of N<sub>2</sub> and NH<sub>3 </sub>molecules) is much more efficient than the K<sup>+ </sup>® (NH<sub>4</sub><sup>+</sup>) substitution even in strongly reduced conditions. The presence of an N-bearing fluid in the studied systems stabilizes the K-cymrite structure. Muscovite does not convert to K-cymrite in the absence of NH<sub>3</sub>-N<sub>2</sub>-bearing fluid within 7.8 GPa and 1070-1120°C. Our estimates of normalized volume per non-hydrogen atom show that N<sub>2</sub>-bearing cymrite is the densest in the series of K-cymrite with cages filled to different degrees: K-Cym<sub>NH3</sub> > K-Cym<sub>H2O</sub> > K-Cym<sub>N2</sub> and is thus the most stable among cymrite-type compounds under high pressure.</p><p><em>The research was performed by a grant of the Russian Science Foundation (16-17-10041).</em></p>


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