scholarly journals Synergistic water-driven shape memory performance and improving mechanism of grading photo-thermal curing shape memory composite

2022 ◽  
pp. 110397
Author(s):  
Wenxin Wang ◽  
Jing Yang ◽  
Wei Li ◽  
Yongtao Yao ◽  
Yaqian Yan ◽  
...  
2020 ◽  
Vol 40 (3) ◽  
pp. 203-210 ◽  
Author(s):  
Tianning Ren ◽  
Guangming Zhu ◽  
Yi Liu ◽  
Xiao Hou

AbstractThe objective of this work is to investigate the thermomechanical, electrical, and shape-memory properties of bisphenol A-type cyanate ester (BACE)/polybutadiene epoxy (PBEP)/carbon black (CB) composite and assess its feasibility applied for deployable structure. Using a BACE/PBEP polymer as matrix and superconducting carbon black (CB) and short carbon fibers (SCFs) as reinforcing material, the shape memory composite was prepared by compression molding. The effects of CB and SCF content on the shape memory properties of the composites were investigated. The results demonstrate that the glass transition temperature (Tg) and the storage modulus of the composites increases as SCFs content increase. Because of the synergic effect of CB and SCFs, the shape memory composites exhibit excellent shape memory performance, and the shape recovery ratio is about 100%. With the increase in SCF content, the recovery time decreased, and the volume electrical resistivity of the composite could decrease by adding a small amount of SCFs. According to the above results, a shape memory polymer composite deployable structure was prepared.


Micromachines ◽  
2021 ◽  
Vol 12 (9) ◽  
pp. 1107
Author(s):  
Mijeong Kim ◽  
Seongeun Jang ◽  
Sungwoong Choi ◽  
Junghoon Yang ◽  
Jungpil Kim ◽  
...  

Shape memory polymers (SMPs) are attracting attention for their use in wearable displays and biomedical materials due to their good biocompatibility and excellent moldability. SMPs also have the advantage of being lightweight with excellent shape recovery due to their low density. However, they have not yet been applied to a wide range of engineering fields because of their inferior physical properties as compared to those of shape memory alloys (SMAs). In this study, we attempt to find optimized shape memory polymer composites. We also investigate the shape memory performance and physical properties according to the filler type and amount of hardener. The shape memory composite was manufactured by adding nanocarbon materials of graphite and non-carbon additives of Cu. The shape-recovery mechanism was compared, according to the type and content of the filler. The shape fixation and recovery properties were analyzed, and the physical properties of the shape recovery composite were obtained through mechanical strength, thermal conductivity and differential scanning calorimetry analysis.


2013 ◽  
Vol 30 (2) ◽  
pp. 134
Author(s):  
Hui FU ◽  
Jishan QIU ◽  
Ning CHONG ◽  
Yaqing WANG ◽  
Yuanyuan TIAN ◽  
...  

Author(s):  
Loredana Santo ◽  
Denise Bellisario ◽  
Giovanni Matteo Tedde ◽  
Fabrizio Quadrini

Shape memory polymers (SMP) and composites (SMPC) may be used for many applications in Space, from self-deployable structures (such as solar sails, panels, shields, booms and antennas), to grabbing systems for Space debris removal, up to new-concept actuators for telescope mirror tuning. Experiments on the International Space Station are necessary for testing prototypes in relevant environment, above all for the absence of gravity which affects deployment of slender structures but also to evaluate the aging effects of the Space environment. In fact, several aging mechanisms are possible, from polymer cracking to cross-linking and erosion, and different behaviors are expected as well, from consolidating the temporary shape to composite degradation. Evaluating the possibility of shape recovery because of sun exposure is another interesting point. In this study, a possible experiment on the ISS is shown with the aim of evaluating the aging effect of Space on material performances. The sample structure is described as well as the testing strategy.


Polymers ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 542 ◽  
Author(s):  
David Santiago ◽  
Dailyn Guzmán ◽  
Francesc Ferrando ◽  
Àngels Serra ◽  
Silvia De la Flor

A series of bio-based epoxy shape-memory thermosetting polymers were synthesized starting from a triglycidyl phloroglucinol (3EPOPh) and trimethylolpropane triglycidyl ether (TPTE) as epoxy monomers and a polyetheramine (JEF) as crosslinking agent. The evolution of the curing process was studied by differential scanning calorimetry (DSC) and the materials obtained were characterized by means of DSC, thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), stress-strain tests, and microindentation. Shape-memory properties were evaluated under free and totally constrained conditions. All results were compared with an industrial epoxy thermoset prepared from standard diglycidyl ether of Bisphenol A (DGEBA). Results revealed that materials prepared from 3EPOPh were more reactive and showed a tighter network with higher crosslinking density and glass transition temperatures than the prepared from DGEBA. The partial substitution of 3EPOPh by TPTE as epoxy comonomer caused an increase in the molecular mobility of the materials but without worsening the thermal stability. The shape-memory polymers (SMPs) prepared from 3EPOPh showed good mechanical properties as well as an excellent shape-memory performance. They showed almost complete shape-recovery and shape-fixation, fast shape-recovery rates, and recovery stress up to 7 MPa. The results obtained in this study allow us to conclude that the triglycidyl phloroglucinol derivative of eugenol is a safe and environmentally friendly alternative to DGEBA for preparing thermosetting shape-memory polymers.


2014 ◽  
Vol 783-786 ◽  
pp. 2509-2516 ◽  
Author(s):  
Fabrizio Quadrini

Shape memory composites and structures were produced by using carbon fiber reinforced prepregs and a shape memory epoxy resin. The matrix of the prepregs was an epoxy resin as well but without remarkable shape memory properties. This way, two different technical solutions were adopted. Shape memory composite tubes and plates were made by adding a shape memory layer between two carbon fiber reinforced skins. An optimal adhesion between the different layers was achieved thanks to the compatibility of the prepreg matrix and the shape memory material. Shape memory composite structures were also produced by joining composite shells with shape memory foams. Mechanical, dynamic mechanical and shape recovery tests were carried out to show the properties of the composite materials and structures. Results confirm the ability of this class of materials to easily change their shape without affecting the mechanical stiffness of the recovered structures.


2020 ◽  
Vol 209 (1) ◽  
pp. 30-39
Author(s):  
Yuqin Ma ◽  
Jie Wang ◽  
Shuangshuang Li ◽  
Juan Ma ◽  
Yatao Zhao ◽  
...  

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