Electrochemical impedance behaviour of type 304L stainless steel under tensile loading

2004 ◽  
Vol 58 (27-28) ◽  
pp. 3381-3384 ◽  
Author(s):  
K.R. Trethewey ◽  
M. Paton
Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 135
Author(s):  
Kathleen Jaffré ◽  
Benoît Ter-Ovanessian ◽  
Hiroshi Abe ◽  
Nicolas Mary ◽  
Bernard Normand ◽  
...  

The effect of dry grinding on 304L stainless steel’s passive behavior is compared to two other surface finishing (mechanical polishing down to 2400 with SiC emery paper and 1 µm with diamond paste, respectively). The characterization of the surface state was performed using scanning electron microscopy, transmission electron microscopy, 3D optical profilometer, and X-ray diffraction. Results indicate that each surface treatment leads to different surface states. The ground specimens present an ultrafine grain layer and a strong plastic deformation underneath the surface, while an ultrafine grain layer characterizes the subsurface of the polished specimens. Grinding induces high residual compressive stresses and high roughness compared to polishing. The characterization of the passive films was performed by electrochemical impedance spectroscopy and Mott–Schottky analysis. The study shows that the semiconductor properties and the thickness of the passive films are dependent on the surface state of the 304L stainless steel.


2022 ◽  
Vol 318 ◽  
pp. 125925
Author(s):  
Vittoria Laghi ◽  
Michele Palermo ◽  
Lavinia Tonelli ◽  
Giada Gasparini ◽  
Valentina Alena Girelli ◽  
...  

2013 ◽  
Vol 351-352 ◽  
pp. 1072-1076 ◽  
Author(s):  
Wen Shi ◽  
Song Xiang ◽  
Yan Li Li ◽  
Ming Yang ◽  
Ya Nan Hu ◽  
...  

Electrochemical behavior of 304L and S32304 stainless steel in different temperature and concentration phosphoric acid solution by means of polarization curve and electrochemical impedance spectroscopy. The results showed that with the increase of the phosphoric acid solution temperature, the corrosion voltage and the corrosion current of the stainless steel increase and the polarization resistance and solution resistance decrease. The corrosion-resistant properties of S32304 stainless steel are superior to that of 304L stainless steel.


2019 ◽  
Vol 66 (2) ◽  
pp. 149-158 ◽  
Author(s):  
Gopinath Shit ◽  
S. Ningshen

Purpose High corrosion resistance in different concentrations of nitric acid is essential for structural steels to be used for the aqueous reprocessing of spent nuclear fuels with high plutonium content. Design/methodology/approach In the present study, the corrosion resistance of type 304L stainless steel (SS) with modified composition was evaluated in different concentrations of nitric acid using surface analytical techniques, weight loss method and electrochemical measurements. Findings Weight loss measurement in boiling 65 per cent nitric acid showed a low corrosion rate value of about 0.2 mm/y (8 mpy) after 240 h exposure. Electrochemical measurements revealed the shift in open circuit potentials as well as corrosion potential toward more noble direction, and the results of electrochemical impedance spectroscopy studies indicated the reduction in the thickness and stability of the passive film with increasing concentration from 6 to 11.5 M nitric acid. Research limitations/implications The low corrosion rate observed for this steel is attributed to the higher content of Cr (19 per cent), Ni (10 per cent) and Si (0.3 per cent) and controlled minor alloying elements (S, P, B, C, etc.) in the alloy that contributed to improving the transpassive corrosion resistance and minimizing the intergranular corrosion attack. The X-ray photoelectron spectroscopic analysis revealed the composition of the passive films to be mainly of iron and chromium oxides. Practical implications Materials with lower corrosion rates are desirable for applications in nitric acid. Social implications The used of nitric acid creates a severe corrosive environment in chemical or aqueous nuclear reprocessing plants, and hence with a modified composition of type 304L SS resulting in minimizing failure of components are desirable for reducing cost and maintenance. Originality/value The present paper is an original work carried out by the authors on the corrosion resistance behaviors of composition modified AISI type 304L SS for nitric acid application. The effects of different nitric acid concentrations were compared to provide understanding on in applicability in boiling and high nitric acid concentrations.


1981 ◽  
Vol 42 (C5) ◽  
pp. C5-193-C5-198 ◽  
Author(s):  
N. Igata ◽  
H. B. Chen ◽  
K. Miyahara ◽  
T. Uba

Alloy Digest ◽  
2003 ◽  
Vol 52 (2) ◽  

Abstract Carpenter Project 70+ Type 304/304L is a modified version of Type 304/304L stainless steel with improved machinability when compared to conventional 304 (Alloy Digest SS-418, revised September 1997) and 304L (Alloy Digest SS-513, revised November 1997). The alloys are nonhardenable austenitic chromium-nickel steels and are good general-purpose materials for simple and complex parts. This datasheet provides information on composition, physical properties, and elasticity. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-875. Producer or source: Carpenter Specialty Alloys.


Alloy Digest ◽  
1996 ◽  
Vol 45 (7) ◽  

Abstract Sandvik 3R12/4L7 is a composite tube consisting of type 304L stainless steel for corrosion resistance on the outside diameter and having carbon steel (A210 Gr. A1) as the inside component for both water wetted service and the design load. The major application is tubing to handle the corrosive conditions in black liquor recovery boilers. This datasheet provides information on composition, physical properties, microstructure as well as fatigue. It also includes information on forming, heat treating, and joining. Filing Code: SA-482. Producer or source: Sandvik.


Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 571
Author(s):  
Aurelia Elena Tudose ◽  
Ioana Demetrescu ◽  
Florentina Golgovici ◽  
Manuela Fulger

The aim of this work was to study the corrosion behavior of a Fe-Cr-Ni alloy (310 H stainless steel) in water at a supercritical temperature of 550 °C and a pressure of 250 atm for up to 2160 h. At supercritical temperature, water is a highly aggressive environment, and the corrosion of structural materials used in a supercritical water-cooled nuclear reactor (SCWR) is a critical problem. Selecting proper candidate materials is one key issue for the development of SCWRs. After exposure to deaerated supercritical water, the oxides formed on the 310 H SS surface were characterized using a gravimetric analysis, a metallographic analysis, and electrochemical methods. Gravimetric analysis showed that, due to oxidation, all the tested samples gained weight, and oxidation of 310H stainless steel at 550 °C follows parabolic rate, indicating that it is driven by a diffusion process. The data obtained by microscopic metallography concord with those obtained by gravimetric analysis and show that the oxides layer has a growing tendency in time. At the same time, the results obtained by electrochemical impedance spectroscopy (EIS) measurements indicate the best corrosion resistance of Cr, and (Fe, Mn) Cr2O4 oxides developed on the samples surface after 2160 h of oxidation. Based on the results obtained, a strong correlation between gravimetric analysis, metallographic analysis, and electrochemical methods was found.


2020 ◽  
Vol 39 (1) ◽  
pp. 340-350
Author(s):  
Mingjing Wang ◽  
Song Zeng ◽  
Huihui Zhang ◽  
Ming Zhu ◽  
Chengxin Lei ◽  
...  

AbstractCorrosion behaviors of 316 stainless steel (316 ss) and Inconel 625 alloy in molten NaCl–KCl–ZnCl2 at 700°C and 900°C were investigated by immersion tests and electrochemical methods, including potentiodynamic polarization and electrochemical impedance spectroscopy. X-ray diffraction and scanning electron microscopy/energy dispersive spectroscopy were used to analyze the phases and microstructures of the corrosion products. Inconel 625 alloy and 316 ss exhibited high corrosion rates in molten chlorides, and the corrosion rates of these two alloys accelerated when the temperature increased from 700°C to 900°C. The results of the electrochemical tests showed that both alloys exhibited active corrosion in chloride molten salt, and the current density of 316 ss in chloride molten salt at 700°C was 2.756 mA/cm−2, which is about three times the value for Inconel 625 alloy; and the values of the charge transfer resistance (Rt) for Inconel 625 were larger than those for 316 ss. The corrosion of these two alloys is owing to the preferred oxidation of Cr in chloride molten salt, and the corrosion layer was mainly ZnCr2O4 which was loose and porous and showed poor adherence to metal.


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