Comparison of RSM Based FFD and CCD Methods for Biodiesel Production Using Microwave Technique

Author(s):  
Nirav Prajapati ◽  
Pravin Kodgire ◽  
Surendra Singh Kachhwaha
2014 ◽  
Vol 917 ◽  
pp. 87-95 ◽  
Author(s):  
Suliana Abu Bakar ◽  
Suzana Yusup ◽  
Murni Melati Ahmad ◽  
Armando T. Quitain ◽  
Mitsuru Sasaki ◽  
...  

The production of biodiesel from crude palm oil (CPO) using microwave technique is investigated and has been compared with conventional heating. Two-step biodiesel production process is applied to maximize the highest biodiesel yield in short reaction time using microwave method. Sulfuric acid (H2SO4) as acid catalysts is used in pre-treatment of feedstock by esterification process followed by potassium hydroxide (KOH) as base catalyst for transesterification process with low methanol to oil ratio. The main purpose of the pre-treatment process is to reduce the free fatty acids (FFA) content of CPO from higher value of FFA content (>6.8%) to a minimum level for biodiesel production (<1%). Esterification and transesterification is carried out in fully instrumented and controlled microwave reactor system to get higher yield in shorter time. This two-step esterification and transesterification process showed that the maximum conversion of palm biodiesel obtained is 95.1% with the process conditions of methanol-to-oil molar ratio of 6:1, reaction temperature 65oC, reaction time 15min, and 2% (wt/wt) KOH amount using microwave method compared to conventional heating where the palm oil methyl ester (POME) yield obtained is 81% at the same conditions. The result showed that, the biodiesel production using microwave technique proved to be a fast and easy route to get high yields of biodiesel.


2020 ◽  
pp. 149-159
Author(s):  
Jatinder Kataria ◽  
Saroj Kumar Mohapatra ◽  
Amit Pal

The limited fossil reserves, spiraling price and environmental impact due to usage of fossil fuels leads the world wide researchers’ interest in using alternative renewable and environment safe fuels that can meet the energy demand. Biodiesel is an emerging renewable alternative fuel to conventional diesel which can be produced from both edible and non-edible oils, animal fats, algae etc. The society is in dire need of using renewable fuels as an immediate control measure to mitigate the pollution level. In this work an attempt is made to review the requisite and access the capability of the biodiesel in improving the environmental degradation.


2016 ◽  
Vol 5 (3) ◽  
pp. 38-43
Author(s):  
Windi Monica Surbakti ◽  
Gerson Rico M.H ◽  
Mersi Suriani Sinaga

Glycerol as a byproduct of biodiesel production was approximately formed 10% of the biodiesel weight. Impurities which contained in the glycerol such as catalyst, soap, methanol, water, salt, and matter organic non glycerol (MONG) have a significant effect on the glycerol concentration. So, it is necessary to treat the impurities. The purpose of this study is to know the effect of chloroform to glycerol purification process with acidification method using hydrochloric acid as pretreatment process. This research was begun with acid addition to the glycerol to neutralize the base content and to split the soap content into free fatty acid and salt, that are more easily separated from glycerol. Then the process was continued with extraction by the solvent chloroform using the variable of test volume ratio (v/v) (1:1, 1:1.5, 1:2)  and the extraction time (20, 40, and 60 minutes). The results showed that the more volume of solvent used, gave less extraction time to produce high purity of glycerol. The highest purity produced in this study amounted to 90,9082% is obtained at the ratio of the volume solvent (v/v) 1:1 with extraction time 60 minutes.


Author(s):  
M. Mohammadi ◽  
M. Azizollahi-Aliabadi
Keyword(s):  

2020 ◽  
pp. 22-30
Author(s):  
SERGEY N. DEVYANIN ◽  
◽  
VLADIMIR A. MARKOV ◽  
ALEKSANDR G. LEVSHIN ◽  
TAMARA P. KOBOZEVA ◽  
...  

The paper presents the results of long-term research on the oil productivity and chemical composition of soybean oil of the Northern ecotype varieties in the Central Non-Black Earth Region. The authors consider its possible use for biodiesel production. Experiments on growing soybeans were carried out on the experimental fi eld of Russian State Agrarian University –Moscow Timiryazev Agricultural Academy (2008-2019) on recognized ultra-early ripening varieties of the Northern ecotype Mageva, Svetlaya, Okskaya (ripeness group 000). Tests were set and the research results were analyzed using standard approved methods. It has been shown that in conditions of high latitudes (57°N), limited thermal resources of the Non-Chernozem zone of Russia (the sum of active temperatures of the growing season not exceeding 2000°С), the yield and productivity of soybeans depend on the variety and moisture supply. Over the years, the average yield of soybeans amounted to 1.94 … 2.62 t/ha, oil productivity – 388 … 544 kg/ha, oil content – 19…20%, the content of oleic and linoleic fatty acids in oil – 60%, and their output from seeds harvested – 300 kg/ha. It has been established that as soybean oil and diesel fuel have similar properties,they can be mixed by conventional methods in any proportions and form stable blends that can be stored for a long time. Experimental studies on the use of soybean oil for biodiesel production were carried out on a D-245 diesel engine (4 ChN11/12.5). The concentrations of toxic components (CO, CHx, and NOx) in the diesel exhaust gases were determined using the SAE-7532 gas analyzer. The smoke content of the exhaust gases was measured with an MK-3 Hartridge opacimeter. It has been experimentally established that the transfer of a diesel engine from diesel fuel to a blend of 80% diesel fuel and 20% lubrication oil leads to a change in the integral emissions per test cycle: nitrogen oxides in 0.81 times, carbon monoxide in 0.89 times and unburned hydrocarbons in 0.91 times, i.e. when biodiesel as used as a motor fuel in a serial diesel engine, emissions of all gaseous toxic components are reduced. The study has confi rmed the expediency of using soybeans of the Northern ecotype for biofuel production.


2013 ◽  
Vol 12 (8) ◽  
pp. 1563-1573 ◽  
Author(s):  
Giuseppe Olivieri ◽  
Teresa Guida ◽  
Piero Salatino ◽  
Antonio Marzocchella

Tsitologiya ◽  
2018 ◽  
Vol 60 (7) ◽  
pp. 567-571
Author(s):  
A. I. Sidorenko ◽  
◽  
A. V. Sklyarenko ◽  
S. V. Yarotsky ◽  
◽  
...  

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