Rodlike 4,6-diamino-1,3,5-triazine derivatives, effect of the core length on mesophase behavior and their application as LE-LCD device

2021 ◽  
pp. 117879
Author(s):  
Xiaoping Tan ◽  
Qing Chang ◽  
Fawu Su ◽  
Yu Cao ◽  
Feng Liu ◽  
...  
2014 ◽  
Vol 118 (1209) ◽  
pp. 1245-1278 ◽  
Author(s):  
Arun Kumar P. ◽  
E. Rathakrishnan

AbstractThe mixing promoting capability of right-angled triangular tab with sharp and truncated vertex has been investigated by placing two identical tabs at the exit of a Mach 2 axi-symmetric nozzle. The mixing promoting efficiency of these tabs have been quantified in the presence of adverse and marginally favourable pressure gradients at the nozzle exit. It was found that, at all levels of expansion of the present study though the core length reduction caused by both the tabs are appreciable, but the mixing caused by the truncated tab is superior. The mixing promoting efficiency of the truncated tab is found to increase with increase of nozzle pressure ratio (that is, decrease of adverse pressure gradient). For all the nozzle pressure ratios of the present study, the core length reduction caused by the truncated vertex tab is more than that of sharp vertex tab. As high as 84% reduction in core length is achieved with truncated vertex right-angled triangular tabs at moderately overexpanded level, corresponding to expansion levelpe/pa= 0·90. The corresponding core length reduction for right-angled triangular tabs with sharp vertex and rectangular tabs are 65% and 31%, respectively. The present results clearly show that the mixing promoting capability of the triangular tab is best than that of rectangular tabs at identical blockage and flow conditions.


Author(s):  
A Sureshkumar ◽  
BTN Sridhar

Experimental studies were conducted to assess the effect of an annular coflow which surrounded a supersonic core jet in a coaxial jet system. Two different core jet shapes were employed which were circular and equilateral triangular. The core jets were maintained at two different total pressures, i.e. 360 and 550 kPa which corresponded to overexpansion conditions. The effect of coflow which surrounded core jet at a distance larger than the core jet diameter was such that the supersonic core length of the core jet was reduced in contrast to the elongation which was reported by earlier researchers for closer distances between the two jets. The Schlieren images of the coaxial jet system had shown that the region between the jet boundary of core jet and inner boundary of the annular coflow had a strong interaction with core jet which was characterised by a wave system and vortices. This region caused a reduction in supersonic core length and weakening of shock structure in the core jet. These findings have been corroborated by total pressure measurements along the core jet centreline. For the same operational conditions, the coflow caused reduction in supersonic core length more for triangular core jet when compared to that for circular core jet.


1969 ◽  
Vol 9 (02) ◽  
pp. 247-254 ◽  
Author(s):  
J.L. Thompson ◽  
N. Mungan

Abstract Laboratory displacement tests were performed to study oil recovery efficiency by gravity drainage in fractured systems under miscible conditions. The porous media used were cylindrical Berea and Blue porous media used were cylindrical Berea and Blue jacket sandstone cores containing a number of well-defined, artificially formed, vertical and subvertical fractures. Butane and Soltrol 130 were the two miscible fluids used. The purpose of the study was to examine the influences of the displacement rate, fracture density, fracture orientation, fracture permeability, matrix permeability, crossflow, core length and connate permeability, crossflow, core length and connate water on the oil recovery. It was found that displacement rate, matrix permeability and the subvertical fractures affected permeability and the subvertical fractures affected oil recovery most. The critical flow rate, based on the matrix permeability, was found to be a significant factor in the process. For displacement rates below the critical flow rate, the oil recovery efficiency appeared to be unaffected by the density of the subvertical fractures. At the high displacement rates, the fracture density becomes important, with the recovery being the most efficient in the core having the greatest number of the subvertical fractures. The magnitude of the fracture permeability, the fracture orientation, the core permeability, the fracture orientation, the core length and the connate water have little effect on the oil recovery efficiency. Introduction Gravity drainage under miscible conditions from relatively thick reservoirs can be a very efficient recovery process, especially at low flow rates where the gravity forces are dominant and, consequently, the adverse viscous fingers associated with the unfavorable viscosity ratio are minimized or eliminated. Such a process might involve injection of an LPG or some solvent bank at the crest and then driving the bank with dry gas. For some favorable combination of reservoir temperature, pressure and oil composition, there may be no need to inject any solvent bank, since enrichment of the dry gas by the light ends of the crude creates an in-situ solvent bank. Slobod and Howlett have studied the effects of gravity segregation in vertical unconsolidated porous media under miscible conditions in the porous media under miscible conditions in the laboratory. The main variables in their study were the viscosity ratio, the density differences and the rate of flow. In this study, the objective was to find the influence of fractures on gravity drainage under miscible conditions. A greater number of related variables were also studied. LABORATORY STUDY CORE DESCRIPTION Displacement tests were performed mostly in cylindrical Berea sandstone cores. In a few cases in which a much lower matrix permeability was desired, Blue jacket sandstone cores were used. The vertical fractures were formed by cutting the cores with a thin circular blade or by parting them along a bedding plane. The vertical fracture plane always contained the axis of the cylindrical core. The subvertical fractures, cut with a saw, were inclined 45 degrees from the horizontal. The line of intersection between the planes of the vertical and subvertical fractures was parallel to the circular faces of the cores in all cases except one, as depicted by VF3HF-2 in Fig. 1. Fracture geometry of the other cores is also given in Fig. 1. Tables 1 and 2 give the physical properties of the solid and fractured cores, respectively. The suffixes and prefixes shown for each core have been used prefixes shown for each core have been used throughout the paper so that the reader may discern the fracture geometry from the core numbers. SPEJ P. 247


2003 ◽  
Vol 21 (2) ◽  
pp. 123-127 ◽  
Author(s):  
Andrew K. Lee ◽  
Tatiana Doytchinova ◽  
Ming-Hui Chen ◽  
Andrew A. Renshaw ◽  
Michael Weinstein ◽  
...  

2017 ◽  
Vol 122 (1247) ◽  
pp. 131-147 ◽  
Author(s):  
A. Bajpai ◽  
E. Rathakrishnan

ABSTRACTMach 2 jet from a convergent-divergent elliptical nozzle, of aspect ratio 2, has been controlled with limiting flat and arc tabs. The mixing promoting capability of the flat and arc tabs were studied in the presence of different levels of pressure gradient, at the nozzle exit, corresponding to nozzle pressure ratios of 4 to 8, in steps of one. The geometrical blockage of both the tabs is 5% of nozzle exit area. For the flat tab along the minor axis, the waves in the core become weaker and the core length becomes shorter than the uncontrolled jet, at all the NPRs studied. But the flat tab along the major axis promotes mixing only for some NPRs and retards the mixing for the rest of the NPRs studied. At NPR 5, the flat tab along the minor axis causes the largest core length reduction of 86%. For circular arc tab, along the minor axis, the maximum core length reduction is 55% at NPR 6. Arc tab along the major axis protects the core length for the entire range of the nozzle pressure ratios tested and maximum extension in core length is found at NPR 4, which is 40%.


2021 ◽  
Vol 39 (1) ◽  
pp. 219-226
Author(s):  
Haixia Hu ◽  
Wei Luo ◽  
Qinghua Wang ◽  
Junzheng Yang ◽  
Xiaoyan Zhang ◽  
...  

The oil-water and gas-water relative permeability curves are important reference data for the dynamic analysis and numerical simulation of oil and gas reservoir exploitation. Although the petroleum industry of China and other countries have formulated reference standards for the measuring methods of relative permeability of cores, they haven’t given the definite reference values of the core length, therefore we cannot know for sure whether different core length values are required in the measurement and whether the core length has an impact on the measurement results. In view of this gap, this paper conducted a research on the relative permeability of cores with different lengths. The core samples are artificial core with similar properties as the outcrop cores of the Halfaya Oilfield (Iraq), in our experiment, the oil-water and gas-water relative permeability curves of the sample cores were measured and the results suggest that, for the oil-water relative permeability curves, as the core length grows, the iso-permeability points move to the right, and they basically stabilize when the core length is greater than 20cm; as for gas-water relative permeability curves, in case of low-permeability cores, under constant injection pressure, as the core length grows, the iso-permeability points and the two-phase co-permeation areas present an obvious tendency of moving to the left, but when the core length is greater than 20cm, such tendency is not obvious, and the high-permeability cores do not have such characteristics. These results indicate that, the unsteady-state two-phase relative permeability measurement experiments obtained accurate results at a core length of about 20cm, which provided a reference for similar experiments in subsequent research.


1998 ◽  
Vol 1 (01) ◽  
pp. 43-46 ◽  
Author(s):  
Faruk Civan ◽  
R.D. Evans

Summary This paper presents a comparison of the accuracy of the pressure-squared and pseudo pressure formulations of the Forchheimer equation for simultaneous determination of the permeability and non-Darcy flow coefficient from high-velocity flow tests using core plugs. We show that the pressure-squared formulation must satisfy two contradictory conditions. The core length should be sufficiently small so that the average viscosity and real gas deviation factor, which are dependent on the pressure drop, approach the actual values. The core length, however, should be long enough to be representative of the characteristic length of the porous media. Because these two conditions cannot be met simultaneously, the pressure-squared formulation is less accurate. We show that these effects are more pronounced for tight formations because of higher pressure drop across the core. The pseudo pressure formulation requires only that the core length should approach the representative core length, and, therefore, it provides more accurate interpretation of the high-velocity core flow tests and generates accurate values of the permeability and non-Darcy flow coefficient and the representative core length. Introduction Previous studies, including Firoozabadi et al.,1 have facilitated the integral forms of the Forchheimer2 equation as a convenient means of determining the permeability, k, and non-Darcy flow coefficient, ß, from high-velocity flow data. However, as Civan3 and Civan and Evans4 state, the core length averaged k and ß are functions of length, because the viscosity, µ, and the real gas deviation factor, z, are averaged over the pressure drop across the core ends to obtain µ and z, respectively. In theory, the pressure-squared function that many used, including Firoozabadi et al.,1 has inherent limitations because it must satisfy two contradictory conditions to obtain accurate estimation of permeability and inertial flow coefficient from laboratory core tests. The first condition requires very short cores for average viscosity and real gas deviation factor to be close to actual values. The second conditions requires sufficiently long cores to approximate the representative core length correctly. Mathematically, Eqs. 1 and 2 can express these conditions, respectively: where LR is a representative elemental core length. The pseudo pressure formulation by Civan and Evans4 involve only µ, which is almost constant for practical purposes because the effect of pressure on the gas viscosity is negligible. Therefore, the pseudo pressure formulation alleviates the need for satisfying both of these contrasting conditions. Thus, only the condition stated by Eq. 1 needs to be satisfied. Therefore, in the pseudo pressure formulation, the limit is taken with respect to the representative length only. Civan and Evans4,5 present the details of the formulations and the method that forms the basis for this paper elsewhere. We present the application and the verification of the method in this paper. This paper presents a comparison of the pressure-squared and pseudo pressure formulations, a demonstration of the effect of the core length, and determination of the representative core length for simultaneous measurement of permeability and non-Darcy flow coefficient. Applications and Discussion We checked the values of the inertial flow coefficients determined by Firoozabadi et al.1 against those predicted by the Liu et al.6 correlation given by in which ß is in ft–1, k is in md, and t is the tortuosity. Because Firoozabadi et al.1 do not report any values, the tortuosity of the sandstone was approximated as 2 following Carman.7 As Table 1 shows, the Liu et al.6 correlation can predict the inertial flow coefficients with two significant digits. This is within the accuracy of the pressure-squared function (i.e., Eq. 2 of Firoozabadi et al.1). We used existing in-house data (Evans and Civan8) to demonstrate the effect of the core length on permeability and non-Darcy flow coefficients. A series of different length berea cores have been used to generate the pressure differential vs. flow rate experimental data at steady-state conditions. We then plotted these data for each different core length, and Table 2 shows the determined permeability and the non-Darcy flow coefficient values, which we then plotted against core length to determine the sensitivity owing to the core length. The results that Fig. 1 gives indicate that the core-length average permeability and the non-Darcy flow coefficient are dependent on the core length. We obtained the representative values of permeability and the non-Darcy flow coefficient by extrapolation of the core-length average values to the representative elemental core length for which these values reach the limiting values given, respectively, as As can be seen, the representative elemental core length necessary for accurate measurements is simultaneously estimated to about 10 cm. One should be cautioned, however, that the extrapolated values obtained in this example represent the average k and ß values for the whole porous material, not the local values of k and ß at a selected location along the core. Note that the errors caused by not using representative core lengths are not negligible. If, for example, a core of 2.54 cm length instead of the representative length of 10 cm had been used, there would have been an error of ×100=21% in the ß value and ×100=-15% in the k value according to the data presented in Fig. 1.


Author(s):  
De Satyajit ◽  
Ethirajan Rathakrishnan

A detailed experimental study was carried out to investigate the behaviour of a Mach 2 primary jet in the presence of a Mach 1.6 annular co-flow. The lip thickness of the inner nozzle was 7.75 mm. The characteristics of jets were investigated at nozzle pressure ratios 3 to 8, in steps of 1. At nozzle pressure ratios 3 to 7, the centre jet is overexpanded; and at nozzle pressure ratio 8, it is marginally underexpanded. Both primary and secondary jets were operated at the nozzle pressure ratio. Centreline pressure distribution was measured to examine the supersonic core length of the centre jet in the presence and absence of the co-flow at all nozzle pressure ratios. It is found that the co-flow reduces the core length of the primary jet at all overexpanded states. A maximum core length reduction of about 61% is at nozzle pressure ratio 4, whereas the core increases by 5% at the marginally underexpanded state corresponding to nozzle pressure ratio 8. The co-flow jet merges with the primary jet at 4 D, at nozzle pressure ratio 3, and at 8 D for nozzle pressure ratios above 4. Shadowgraph images of the jet in the presence and absence of co-flow reveal that the waves in the core of the jet are strongly influenced by the co-flow.


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