Effect of Si addition to CrN coatings on the corrosion resistance of CrN/stainless steel coating/substrate system in a deaerated 3.5 wt.% NaCl solution

2007 ◽  
Vol 201 (24) ◽  
pp. 9518-9523 ◽  
Author(s):  
Y.H. Yoo ◽  
J.H. Hong ◽  
J.G. Kim ◽  
H.Y. Lee ◽  
J.G. Han
Coatings ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 598
Author(s):  
Wenwei Li ◽  
Jun-e Qu ◽  
Zhiyong Cao ◽  
Hairen Wang

The colored films were successfully prepared on the 304 stainless steel surfaces in coloring solutions with different NiSO4 contents. The purpose of this study was to investigate the effects of NiSO4 in the coloring solution on the coloring performance of 304 stainless steel and corrosion resistance of the obtained colored film in NaCl solution. The coloring rate was determined from coloring potential-time curve, and the protection properties of the color films in a 3.5% NaCl solution were characterized by potentiodynamic polarization scan, electrochemical impedance spectroscopy, and wear resistance test. The results showed that adding NiSO4 could accelerate the coloring process but brought about a negative impact on the surface’s corrosion resistance.


Author(s):  
Lidia R Constantin ◽  
Anca C Parau ◽  
Mihai Balaceanu ◽  
Mihaela Dinu ◽  
Alina Vladescu

ZrCN and Zr–Cr–Si–C–N coatings were deposited on Si (100) and 316L stainless steel substrates using the cathodic vacuum arc technique in a mixed atmosphere of C2H2 and N2. The coatings were grown keeping almost constant the ratio of the C2H2 and N2 mass flow rates, substrate bias and deposition temperature at ∼0.81, −200 V and 320 ℃, respectively. The investigation carried out aimed to determine the corrosion and tribological performance of the novel Zr–Cr–Si–C–N coating obtained by Cr and Si addition to the ZrCN reference coating. The films were characterized in terms of elemental and phase composition, crystalline structure, hardness, reduced elastic modulus and adhesion. Particular attention was devoted to the investigation of coatings' corrosion resistance and tribological performance carried out in a 3.5% NaCl solution. Cr and Si addition to ZrCN coating leads to reduction in film crystallinity, finer microstructure, enhanced corrosion resistance and better tribological performance under corrosive testing conditions. In this paper, we discuss the measured mechanical and tribological properties of the two coatings in terms of various ratios of hardness and reduced elastic modulus. The coated samples exhibited high corrosion protection efficiency, reaching 97.8% for the Zr–Cr–Si–C–N coating. Both coatings improved the tribological performance of 316L steel in the saline solution. Specifically, the addition of Cr and Si into ZrCN coating results in a decrease of the wear rate of about 60%.


2013 ◽  
Vol 652-654 ◽  
pp. 1143-1148
Author(s):  
Peng Jun Cao ◽  
Ji Ling Dong ◽  
Hai Dong Wu ◽  
Pei Geng Fan

The Cu-based bulk glassy alloys in Cu-Zr-Ti-Ni systems were prepared by means of copper mold casting. The structure and corrosion resistance of Cu-based bulk glassy alloys were analyzed by X-ray diffraction (XRD), differential scanning calorimetry (DSC), electrochemistry method, lost weight method. The result indicates the supercooled liquid temperature interval (ΔTx) is up to 70.98 K for Cu50Zr25Ti15Ni10bulk glassy alloy. The maximum diameter was up to 5.0 mm for the Cu55Zr25Ti15Ni5bulk glassy alloy. For electrochemistry corrosion in 3.5% NaCl solution, self-corrosion electric current density of the Cu50Zr25Ti15Ni10bulk glassy alloys is obviously lower than that of stainless steel and brass, so corrosion resistance of Cu-based bulk glassy alloys is better than stainless steel and brass at the same corrosion condition. The lost weight method showed that the corrosion rate of brass, stainless steel and glassy alloy is respectively 10.08 g/(m2•h), 6.08 g/(m2•h) and 2.19 g/(m2•h) in the 3% NaCl solution, which also indicates that the corrosion resistance of Cu-based bulk glassy alloys is better than stainless steel and brass. The Cu-based bulk glassy alloys can be used in the special field demanding to have the super high strength, hardness and corrosion resistance.


RSC Advances ◽  
2015 ◽  
Vol 5 (1) ◽  
pp. 706-716 ◽  
Author(s):  
F. Ansari ◽  
R. Naderi ◽  
C. Dehghanian

An eco-friendly silane sol–gel coating incorporating nanoclay was formulated to provide an effective corrosion protection for stainless steel 304L in a NaCl solution.


2021 ◽  
Author(s):  
Vinda Puspasari ◽  
Mukhlis Agung Prasetyo ◽  
Arini Nikitasari ◽  
Efendi Mabruri ◽  
Moch. Syaiful Anwar

2018 ◽  
Vol 47 (5) ◽  
pp. 444-452
Author(s):  
Fahimeh Ansari ◽  
Reza Naderi ◽  
Fahimeh Rafiaei

Propose This paper aims to access the protective function of hybrid sol-gel coatings deposited on 304L stainless steel substrate in silane solutions containing a mixture of tetraethoxysilane, methyltriethoxysilane and glycidyloxypropyltrimethoxysilane with different pH values during various immersion periods. Design/methodology/approach The 304L stainless steels coated through 10 and 30 s of immersion in the silane solutions with pH values of 2.1 and 2.8 were exposed to NaCl solution. The corrosion resistance of the coated substrates was studied through taking advantage of electrochemical noise method as well as atomic force microscopy (AFM), water contact angle and field emission-type scanning electron microscopy (FESEM) surface analysis. Findings The electrochemical current noise, PSD (I) plot, noise resistance and characteristic charge as parameters extracted from electrochemical noise method indicated the superiority of eco-friendly silane coating deposited on the substrate surface during 10 s exposure to the solution, due to the film uniformity and homogeneity as confirmed by FESEM and AFM. Moreover, immersion of the stainless steel in the silane solution with pH 2.1, characterized by higher hydrolysis ratio, led to more effective corrosion control in the NaCl electrolyte according to the results of electrochemical noise and FTIR measurements. Research limitations/implications The noise resistance and characteristic charge as electrochemical noise parameters were only used in this research to evaluate the protective behavior of the water-based silane sol-gel coatings. Future studies should examine the correlation between electrochemical noise data and the parameters extracted from other electrochemical methods, e.g. electrochemical impedance spectroscopy. Practical implications The data obtained in this research may provide an effective approach based on electrochemical noise method to screen the silane sol-gel coatings for protection of metallic substrates against corrosion. Originality/value According to the literature, no report can be found studying the effect of immersion time on a silane solution, including glycidyloxypropyltrimethoxysilane, tetraethoxysilane and methyltriethoxysilane, as well as the silane solution pH on the corrosion resistance of 304L stainless steel in NaCl solution through electrochemical noise method.


Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1104
Author(s):  
Zexu Du ◽  
Zhengfei Hu ◽  
Yuqiang Feng ◽  
Fan Mo

Two kinds of 60NiTi powders were prepared by pure Ni mixed with Ti powders, and 55NiTi alloy powder with pure Ni powder and both the powders were fully mixed by alcohol ball milling. Two kinds of coatings (denoted as 60Ni-40Ti and 55NiTi-5Ni) were prepared on a 316L stainless steel substrate by laser cladding. The microstructure, microhardness and electrochemical behavior of the prepared coatings were investigated extensively. The results show that 55NiTi-5Ni has a typical dendritic eutectic structure, but 60Ni-40Ti tends to form a eutectic network structure. The main phases in both coatings are (Ni, Fe)Ti and (Ni, Fe)3Ti; however, the (Ni, Fe)Ti phase is dominant in 55NiTi-5Ni, but the (Ni, Fe)3Ti phase is more prevalent in 60Ni-40Ti. The microhardness was significantly improved with the 316L stainless steel substrate, and the microhardness of 55NiTi-5Ni is slightly higher than 60Ni-40Ti. The corrosion resistance of the two coatings in 3.5 wt% NaCl solution also leads to significant improvements compared with the substrate, and the corrosion resistance of 55NiTi-5Ni was also increased. These different behaviors and characteristics might be related to the different microstructures. Uniform and fine eutectic structure in 55NiTi-5Ni coating lead to better performance, which is also conducive to the formation of the dense oxide film to improve corrosion resistance.


2018 ◽  
Vol 27 (3-4) ◽  
Author(s):  
S. Vignesh ◽  
K. Shanmugam ◽  
V. Balasubramanian ◽  
K. Sridhar ◽  
D. Thirumalaikumarasamy

AbstractNew thermally sprayed amorphous metallic coatings have been developed recently that may provide a viable coating option for fluid handling equipment such as propellers, impellers and pumps. They possess the inherent risk of flow-dependent erosion-corrosion problems. In this investigation, iron based (Fe) amorphous coatings were deposited on AISI 316 stainless steel substrate by the high velocity oxy-fuel (HVOF) spraying process, and the coating microstructure was characterised using an optical microscope and scanning electron microscopy. The Fe-based amorphous coating consisted of an amorphous phase, an absence of dislocations, a nanocrystalline phase, less porosity and high hardness. The corrosion behaviour of the substrate and Fe-based amorphous coatings were evaluated by means of electrochemical tests in 3.5 wt.% NaCl solution. Three kinds of electrochemical tests were employed to identify the corrosion resistance of the coating and substrate. The results showed that the Fe30Cr25Mn5Mo20W10B5C3Si2 amorphous metallic coating had a superior corrosion resistance than 316 stainless steel. It was attributed to the amorphous structure and the presence of the corrosion resistant element chromium (Cr).


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