Nature and Distribution of Pyrite in Iowa Coal
Iowa has a large reserve of high-sulfur coal. In view of the projected energy requirements for the state, in-state coal resources should provide a significant contribution. Environmental considerations and air pollution regulations emphasize the desirability of sulfur removal. Both microstructural and microchemical characteristics of Iowa coal relate to the choice and improvement of processing and purification procedures, as well as provide information which may aid in local correlation of deposits.Iron sulfides occur in the coal as nodules and narrow seams (up to 150 mm thick, thinning out over a distance of hundreds of millimeters) and in finely disseminated form. Individual pyrite euhedra occur predominantly in a size range of about one to 40 micrometers in diameter, with by far most of the crystallites being one to two micrometers in diameter (Fig. 1). This raises special characterization problems for routine conventional optical microscope studies. The pyrite also occurs as spherical assemblies of crystallites. These framboidal masses (after Framboise, the French for Raspberry) range from a few micrometers to several hundred micrometers in diameter, with most of them being approximately 10 and 20 micrometers in diameter (Fig. 2).