Intergrainular structure and deformation mechanism in nanocrystalline materials
It is recognized that boundary structure (GB) characterization is essential in order to understand the structure-properties relationship of nanocrystalline (NC). In most cases, NC materials have to suffer deformation during compacting or ball milling techniques, a deep and systematic study on deformation mechanism is also necessary. In this paper, characterization of microstructure in NC materials synthesized by three methods has been presented.1. Ordered and Disordered Regions at GBs of NC Pd The NC Pd samples were synthesized by the inert gas condensation and in situ compacting technique. The results of X-ray diffraction and HREM observations showed that the average grain size of the NC Pd is about 10 nm. It can be seen that most of the GBs have ordered structure and no 'gas-like' feature has been observed. Some disordered GB regions, such as nanovoid formed during compacting process, are also detected as marked by "V" in Fig.l. The structural modification from the disordered state was found during in situ HREM investigation.