The formation and structure of Pd2InP on InP
Palladium appears to be an important component in contact metallizations to p-type III-V semiconductors. Several successful ohmic contacts containing Pd have been fabricated to p-type GaAs; e.g. Au/Pd/Zn/Pd to GaAs. Palladium is easily deposited on and reacts readily with GaAs, at relatively low temperatures, to form binary and ternary compounds. The formation of these compounds helps generate Ga vacancies in GaAs, necessary for dopant incorporation. Palladium also aids in the wetting of metals, such as Zn to GaAs, improving their adherance to the semiconductor surface. For the same reasons expressed above, Pd may also prove to be a valuable component in contact metallizations to p- type InP. Very little work has been done on the interaction between Pd and InP, however. Krishnan et al have reported on the formation of a Pd InP ternary phase, which is predominantly amorphous with some signs of crystallinity. The interaction between Pd and InP, under annealing conditions usually encountered in contact fabrication, is discussed in this paper. Particular emphasis is put on one ternary phase that forms during annealing, i.e Pd2InP.