scholarly journals Mapping the physical and chemical properties of the planetary nebula NGC 3242

2011 ◽  
Vol 7 (S283) ◽  
pp. 448-449
Author(s):  
Hektor Monteiro ◽  
Denise Gonçalves ◽  
Marcelo Leal-Ferreira ◽  
Romano Corradi ◽  
Sebastian Sánchez

AbstractWe present optical integral field spectroscopy analysis of the main components, with the exception of the halo, as well as of the detected small-scale structures of the planetary nebulae NGC 3242. The observations were obtained with the VIMOS instrument attached to VLT-UT3. Spatially resolved maps of the electronic density (Ne), temperatures (Te) and chemical abundances, i.e., in a pixel to pixel fashion of the small and large-scales structures of this planetary nebula are determined in this work. These diagnostic and abundance maps represent important constraints for future detailed three dimensional photoionization modeling of the nebula, as well as providing important information on biases introduced by traditional slit observations.

1997 ◽  
Vol 180 ◽  
pp. 231-231
Author(s):  
R. Gruenwald ◽  
S. M. Viegas ◽  
D. Broguière

A three-dimensional (3D) self-consistent photoionization code is developed in order to build more realistic models for asymmetrical and/or inhomogeneous photoionized nebulae. With these models the assumption of spherical or plane-parallel symmetry can be dropped and models with various geometries can be treated. The gaseous region is divided into numberous cubic cells, and the physical conditions in each cell are obtained taking into account the effect of the other cells in the optical depth and their contribution into the diffuse radiation. A model for IC 4406, which is a typical example of bipolar planetary nebula is presented. The model assumes a torus of dense material around the central star, as suggested in the literature. Its presence is confirmed by the model, in particular by the shape of the theoretical Hα + [NII] isophotal map. The chemical abundances required to explain the observed line intensities indicate that the chemical properties of this bipolar nebula are not characteristic of type I planetaries. A detailed paper will be published in Ap.J. (FAPESP, CNPq)


2015 ◽  
Vol 19 (2) ◽  
pp. 39-50
Author(s):  
Inna Tiurikova ◽  
Mykhailo Peresichnyi

Abstract The results of studies in the field of beverage functionality using walnut are presented. The main components such as celery, Jerusalem artichokes, carrots, pumpkin and rhubarb, as a dietary supplement - extracts from walnut of milk-maturity stage are offered for creating blends. The basic physical and chemical properties of fruit and vegetable raw materials and semi-finished products created on the base of them have been studied, and their nutritional and biological value has been proved. Rational technologies of fruit and vegetable blends with nut additives have been identified. Their biological value has been confirmed. Drinks are recommended for use in the daily diet of human beings to satisfy thirst and enrich the body by biologically valuable components.


2017 ◽  
pp. 1133-1164
Author(s):  
Snežana S. Ilić-Stojanović ◽  
Ljubiša B. Nikolić ◽  
Vesna D. Nikolić ◽  
Slobodan D. Petrović

The latest development in the field of smart hydrogels application as drugs carriers is shown in this chapter. Hydrogels are three-dimensional polymer network consisting of at least one hydrophilic monomer. They are insoluble in water, but in the excess presence of water or physiological fluids, swell to the equilibrium state. The amount of absorbed water depends on the chemical composition and the crosslinking degree of 3D hydrogel network and reaches over 1000% of the xerogel weight. Stimuli-responsive hydrogels exhibit significant change of their properties (swelling, color, transparency, conductivity, shape) due to small changes in the external environment conditions (pH, ionic strength, temperature, light wavelength, magnetic or electric fields, ultrasound, or a combination thereof). This smart hydrogels, with different physical and chemical properties, chemical structure and technology of obtaining, show great potential for application in the pharmaceutical industry. The application of smart hydrogels is very promising and at the beginning of the development and exploitation.


1982 ◽  
Vol 99 ◽  
pp. 87-104 ◽  
Author(s):  
Allan J. Willis

This review summarises current knowledge of the chemical composition of PopI WR stars, concentrating on work carried out in this area since the last IAU, No. 49, symposium devoted to this stellar class (Bappu & Sahade 1973). Earlier reviews of this topic are found in Gebbie & Thomas (1968). The dichotomy of the WR stars into the WN and WC sequences (Beals 1934) has generally been qualitatively interpreted as arising because of gross differences in the C and N abundances: WN stars which exhibit emission lines of predominantly He and N ions with little evidence for C, being inferred as C-poor objects, whilst WC stars, showing predominantly He and C lines and virtually no evidence for N being inferred as N-poor. In both sequences the visible spectra show little or no evidence for hydrogen. However, although the WR stars have been acknowledged as a class for over a century now, progress has been very slow in putting quantitative determinations of their physical and chemical properties on a firm basis, with the bulk of work in this area being conducted during the past decade. The chemical nature of the WR stars has always been a matter of considerable uncertainty, controversy and, quite often, passionate disagreement, arising from uncertainties in the interpretation of the, often ambiguous, observational material available, as well as from disagreements as to the reliability of the use of comparatively simple analytical models employed to date. Recent results strongly suggest that the WR stars are chemically evolved objects, with low H/He ratios and quite different C/N ratios in the WN and WC sequences, with some measure of agreement in these results with the chemistries predicted to arise at various stages of evolutionary theory for hot massive stars which, by one means or another, have shed much of their atmospheric material during their evolution. My purpose in this review is to summarise the investigations and results that lead to the above conclusions. §2 deals with an assessment of the atmospheric H/He ratio in both WN and WC stars: a parameter of fundamental importance in addressing their evolutionary status, as well as providing a base species with which to compare other derived chemical abundances. §3 briefly deals with the models generally employed and gives recent results for He, C and N abundances derived from both visible and UV line analyses. §4 summarises recent results from stellar evolutionary theory and in §5 compares these with those derived from observation, assessing the significance of these new results and their implications for the evolutionary status of the WR stars. Some areas for further advancement are identified.


2020 ◽  
Vol 21 (20) ◽  
pp. 7577
Author(s):  
Noriyuki Uchida ◽  
Takahiro Muraoka

Peptide-based fibrous supramolecular assemblies represent an emerging class of biomaterials that can realize various bioactivities and structures. Recently, a variety of peptide fibers with attractive functions have been designed together with the discovery of many peptide-based self-assembly units. Cross-linking of the peptide fibers is a key strategy to improve the functions of these materials. The cross-linking of peptide fibers forming three-dimensional networks in a dispersion can lead to changes in physical and chemical properties. Hydrogelation is a typical change caused by cross-linking, which makes it applicable to biomaterials such as cell scaffold materials. Cross-linking methods, which have been conventionally developed using water-soluble covalent polymers, are also useful in supramolecular peptide fibers. In the case of peptide fibers, unique cross-linking strategies can be designed by taking advantage of the functions of amino acids. This review focuses on the current progress in the design of cross-linked peptide fibers and their applications.


The structures into which the Irish Waulsortian limestones are organized have been regarded as reefs. They are re-interpreted as carbonate mudbanks. Their growth mechanism has been deduced from a study of bank morphology and depositional structures. The banks grew from Upper Tournaisian to Lower Visean times, occupying an offshore position on a shallow water shelf. They formed a bank complex covering thousands of square miles, and many smaller masses scattered in the lagoon on its northern and eastern sides. Southwards the Waulsortian Complex was bounded by the ‘Culm’ mud belt. Individual banks were detected and their internal structure mapped by studying the spatial arrangement of small-scale bedding features. The sparry masses ( Stromatacis or ‘reef tufa’) proved the most useful of these because their shape and orientation were found to depend directly upon the depositional attitude of the bank bed containing them. Form lines, constructed from measurements on bedding features, were used to delineate banks incompletely exposed. When compared with the size of the Complex the banks were not large. At any one time they may neither have risen much more than 50 ft. above the sea floor nor exceeded a few hundred yards in diameter. They are constructed from irregular, thin, lenticular limestone bodies here termed ‘bank beds’. These, which are sometimes difficult to detect, apparently represent growth increments not erosional remnants. Flat-lying beds characterize the earliest stage of bank growth. Later, the depositional slope gradually increased. In the final ‘climax form’ depositional dips up to 50° are known. Bank geometry was controlled by the size, shape and arrangement of the bank beds (affected by several factors) and the relative rates of bank and off-bank sedimentation. Most banks conform to a basic ‘knoll’ growth pattern. ‘Sheet’ forms, probably highly modified knolls, are rare. Single, isolated knoll-form banks have not been seen: the existence of one bank always seems to have promoted the formation of others. Four examples illustrate stages in the aggregation of banks to form a complex. These, taken from localities in Counties Longford, Galway, Tipperary and Limerick, show successively less intercalation of lagoonal limestone and shale until finally all the banks overlap one another directly. Lithological variation in the Waulsortian limestones can be expressed in terms of their five main components: (i) calcite mudstone, (ii) coarsely crystalline calcite mosaics (including Stromatactis and ‘ reef tufa ’), (iii) in situ fenestellid Bryozoa, (iv) crinoidal, shelly and bryozoan debris, and (v) entire fossils other than Bryozoa. Except at bank margins no simple pattern of lithological changes has been recognized. Fenestellids are often common, acting as baffles trapping fine sediment. However, they did not constitute a rigid framework and cannot be regarded as the sole agents of bank growth. Depositional structures in the calcite mudstones provide the key to an understanding of bank genesis. Stromatactis spars, which elsewhere have attracted most attention, are less important because their form depends directly upon the depositional sequence in the mudstones. In any one sample several distinct mudstone generations are present. Most were deposited before any spar formed. Their present distribution mainly results from internal sedimentation. The earliest mud generation ( M 1) forms discrete patches or loose ‘ flocculent ’ masses often occupying less than half the total volume of mud present. It is generally surrounded by later muds ( M 2 et seq .) and spars. The arrangement of the generations and the structures within them suggest that (i) M 1 behaved as lumps of sediment (compacted but not lithified) while later muds were finely particulate, (ii) both M 1 and M 2 arrived in their present positions together by downward movement in a gently collapsing system, and (iii) loose packing of M 1 and M 2 left cavities roofed by mechanical ‘bridges’. Similar ‘bridging’ and cavities can be produced experimentally. The collapse features can be explained by decay of the organisms (perhaps plants or sponges) around and within which the mudstones of the bank accumulated. M 1 may then represent mud trapped between the organisms and M 2 that trapped or produced within them. A local origin for the mud is favoured. Cavities remaining after collapse were filled by geopetal muds trickling from higher parts of the bed, and by precipitated spars (thus producing Stromatactis ). In some instances, at least, the spars were formed before deposition of the next bed. They could thus have provided an inorganic skeleton supporting the bank until the mud lithified. It is concluded that the morphology of the banks, their steep depositional slopes, and the presence, bulk and arrangement of the calcite mudstones all point to the baffling activity of organisms (not preserved) as the mechanism of bank growth. Details of the physical and chemical environment around the banks cannot be surely deduced from evidence available at present. The sedimentary structures give few direct clues because of extensive internal resedimentation. Further, the value of any of the mechanical structures as indicators of the state of the water around the banks is doubtful. Even if the banks grew in agitated water the presence of baffles could inhibit formation of mechanical depositional and erosional features otherwise associated with these conditions. Absence of such features may thus be misleading.


2008 ◽  
Vol 35 (1) ◽  
pp. 71
Author(s):  
ANDREA LOPES IESCHECK ◽  
CLAUDIA ROBBI SLUTER ◽  
RENATO ANTÔNIO DEDECEK

This paper is on volume visualization of spatial data. It aims at showing new possibilities to visualize three-dimensional phenomena such as geology, soils, geophysics, seismic and the like. The use of volumes in the evaluation processes allows one to visualize and to explore the phenomenon as a continuous body in space, thus incorporating the third dimension in cartography. The volumetric visualization is a branch of scientific visualization that has shown a fast growth and its goal is to comprehend the internal structure and the behavior of three-dimensional volumetric objects. Volumetric visualization depends on the interaction. We must, therefore, interact with the volume trough rotations, cuts and other forms of graphic manipulation, seeking the complete information. The methodology of this research entails the acquisition of three-dimensional data, three-dimensional interpolation, as well as volume formation and visualization by means of three-dimensional Geographic Information System and volumetric visualization software. Soil’s data were interpolated in order to be continuously represented in three-dimensional space. The outcome of volume representations of physical and chemical properties is a new way to visualize the soil and a new source of knowledge to the study of this phenomenon.


Author(s):  
Kristina Ivana Fabijanic ◽  
Aída Ninfa Salinas López ◽  
Long Pan ◽  
Chi-Yuan Cheng ◽  
Yu Wang ◽  
...  

AbstractThere is an increasing need for materials with tunable physical and chemical properties that are relatively non-toxic and efficacious for their intended application. Many wood stains and finishes emit toxic chemicals which may have serious implications to one’s health. A novel alternative material is realized between xanthan gum and Neodol, a non-ionic surfactant. The resulting three-dimensional film is evaluated as a free-radical scavenger for the protection of wood at different ratios. Atomic force microscopy visualizes the topography and quantifies the local nanomechanics, while rheological measurements showcase a shift from viscoelastic material to gel. Electron plasmon resonance confirms the free-radical reducing ability (3.5 times), while liquid chromatography mass spectroscopy quantifies the UV degradation of sinapyl alcohol. This material has potential, not only in coating industries as a safer option, but also in those industries requiring flexibility and tenability, namely for biosensors and anti-inflammatory therapeutics. Graphic abstract


2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Pooja Mittal ◽  
Anjali Saharan ◽  
Ravinder Verma ◽  
Farag M. A. Altalbawy ◽  
Mohammed A. Alfaidi ◽  
...  

Dendrimers are nanosized, symmetrical molecules in which a small atom or group of atoms is surrounded by the symmetric branches known as dendrons. The structure of dendrimers possesses the greatest impact on their physical and chemical properties. They grow outwards from the core-shell which further reacts with monomers having one reactive or two dormant molecules. Dendrimers’ unique characteristics such as hyperbranching, well-defined spherical structure, and high compatibility with the biological systems are responsible for their wide range of applications including medical and biomedical areas. Particularly, the dendrimers’ three-dimensional structure can incorporate a wide variety of drugs to form biologically active drug conjugates. In this review, we focus on the synthesis, mechanism of drug encapsulations in dendrimers, and their wide applications in drug delivery.


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