scholarly journals Effect of UV-A, UV-B and UV-C irradiation of glyphosate on photolysis and mitigation of aquatic toxicity

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Dimitra Papagiannaki ◽  
Claudio Medana ◽  
Rita Binetti ◽  
Paola Calza ◽  
Peter Roslev
Keyword(s):  
High Resolution Mass Spectrometry ◽  
Aquatic Toxicity ◽  
Aquatic Organisms ◽  
Transformation Products ◽  
Trophic Levels ◽  
Indirect Photolysis ◽  
Before And After ◽  
Test Organisms ◽  
Inorganic Constituents ◽  
Uv C

AbstractThe active herbicide ingredient glyphosate [N-(phosphonomethyl)glycine] is frequently detected as a contaminant in groundwater and surface waters. This study investigated effects of UV-A (365 nm), UV-B (302 nm) and UV-C (254 nm) irradiation of glyphosate in water on photolysis and toxicity to aquatic organisms from different trophic levels. A test battery with bacteria (Bacillus subtilis, Aliivibrio fischeri), a green microalga (Raphidocelis subcapitata), and a crustacean (Daphnia magna) was used to assess biological effect of glyphosate and bioactive transformation products before and after UV irradiation (4.7–70 J/cm2). UV-C irradiation at 20 J/cm2 resulted in a 2–23-fold decrease in toxicity of glyphosate to aquatic test organisms. UV-B irradiation at 70 J/cm2 caused a twofold decrease whereas UV-A did not affect glyphosate toxicity at doses ≤ 70 J/cm2. UV-C irradiation of glyphosate in drinking water and groundwater with naturally occurring organic and inorganic constituents showed comparable or greater reduction in toxicity compared to irradiation in deionized water. High-resolution mass spectrometry analyses of samples after UV-C irradiation showed > 90% decreases in glyphosate concentrations and the presence of multiple transformation products. The study suggests that UV mediated indirect photolysis can decrease concentrations of glyphosate and generate less toxic products with decreased overall toxicity to aquatic organisms.

scholarly journals Investigation of Biotransformation Products of p-Methoxymethylamphetamine and Dihydromephedrone in Wastewater by High-Resolution Mass Spectrometry

Metabolites ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 66
Author(s):  
Juliet Kinyua ◽  
Aikaterini K. Psoma ◽  
Nikolaos I. Rousis ◽  
Maria-Christina Nika ◽  
Adrian Covaci ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Wastewater Treatment Plants ◽  
High Resolution Mass Spectrometry ◽  
Transformation Products ◽  
New Psychoactive Substances ◽  
Batch Reactors ◽  
Flight Mass Spectrometry ◽  
Detection And Identification ◽  
Wastewater Samples ◽  
Set Up

There is a paucity of information on biotransformation and stability of new psychoactive substances (NPS) in wastewater. Moreover, the fate of NPS and their transformation products (TPs) in wastewater treatment plants is not well understood. In this study, batch reactors seeded with activated sludge were set up to evaluate biotic, abiotic, and sorption losses of p-methoxymethylamphetamine (PMMA) and dihydromephedrone (DHM) and identify TPs formed during these processes. Detection and identification of all compounds was performed with target and suspect screening approaches using liquid chromatography quadrupole-time-of-flight mass spectrometry. Influent and effluent 24 h composite wastewater samples were collected from Athens from 2014 to 2020. High elimination rates were found for PMMA (80%) and DHM (97%) after a seven-day experiment and degradation appeared to be related to biological activity in the active bioreactor. Ten TPs were identified and the main reactions were O- and N-demethylation, oxidation, and hydroxylation. Some TPs were reported for the first time and some were confirmed by reference standards. Identification of some TPs was enhanced by the use of an in-house retention time prediction model. Mephedrone and some of its previously reported human metabolites were formed from DHM incubation. Retrospective analysis showed that PMMA was the most frequently detected compound.

Chlorinated C 1 and C 2 hydrocarbons in the marine environment

1975 ◽  
Vol 189 (1096) ◽  
pp. 305-332 ◽  
Keyword(s):  
Carbon Tetrachloride ◽  
Acute Toxicity ◽  
Microbial Degradation ◽  
Chemical Industry ◽  
Aquatic Organisms ◽  
Trophic Levels ◽  
Food Chains ◽  
Laboratory Bioassay ◽  
Marine Food ◽  
Chemical Manufacture

A range of chlorinated hydrocarbons derived from C 1 and C 2 hydrocarbons is manufactured industrially. They are used as intermediates for further chemical manufacture and also outside the chemical industry as solvents or carriers. In the latter category losses in use are eventually dispersed to the environment. The distribution of some of these compounds, including chloroform, carbon tetrachloride, trichloroethylene, perchloroethylene and trichloroethane, in the environment (air, water and marine sediments) has been investigated and the results are presented. The concentrations found have been compared with acute toxicity levels to fish and other aquatic organisms, ascertained by laboratory bioassay. The occurrence of the compounds has been determined in a number of marine organisms, especially those at higher trophic levels, and the accumulation of some of them has been investigated in the laboratory. Chemical and microbial degradation processes have been studied in the laboratory to help determine the course of their removal from the aqueous and aerial environment, and the half lives of some of the compounds have been estimated. It is concluded that these compounds are not persistent in the environment, and that there is no significant bioaccumulation in marine food chains.

scholarly journals Aquatic Toxicity Comparison of Silver Nanoparticles and Silver Nanowires

2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
Eun Kyung Sohn ◽  
Seyed Ali Johari ◽  
Tae Gyu Kim ◽  
Jin Kwon Kim ◽  
Ellen Kim ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Daphnia Magna ◽  
Silver Nanowires ◽  
Aquatic Toxicity ◽  
Oryzias Latipes ◽  
Aquatic Environments ◽  
Silver Nanomaterials ◽  
Raphidocelis Subcapitata ◽  
Test Organisms ◽  
Test Fish

To better understand the potential ecotoxicological impact of silver nanoparticles (AgNPs) and silver nanowires (AgNWs) released into freshwater environments, the toxicities of these nanomaterials were assessed and compared using Organization for Economic Cooperation and Development (OECD) test guidelines, including a “Daphniasp., acute immobilization test,” “Fish, acute toxicity test,” and “freshwater alga and cyanobacteria, growth inhibition test.” Based on the estimated median lethal/effective concentrations of AgNPs and AgNWs, the susceptibility to the nanomaterials was different among test organisms (daphnia > algae > fish), suggesting that the AgNPs are classified as “category acute 1” forDaphnia magna, “category acute 2” forOryzias latipes, and “category acute 1” forRaphidocelis subcapitata, while the AgNWs are classified as “category acute 1” forDaphnia magna, “category acute 2” forOryzias latipes, and “category acute 2” forRaphidocelis subcapitata, according to the GHS (Globally Harmonized System of Classification and Labelling of Chemicals). In conclusion, the present results suggest that more attention should be paid to prevent the accidental or intentional release of silver nanomaterials into freshwater aquatic environments.

scholarly journals Environmental Risk Assessment of Vehicle Exhaust Particles on Aquatic Organisms of Different Trophic Levels

Toxics ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 261
Author(s):  
Konstantin Pikula ◽  
Mariya Tretyakova ◽  
Alexander Zakharenko ◽  
Seyed Ali Johari ◽  
Sergey Ugay ◽  
...  
Keyword(s):  
Risk Assessment ◽  
Sea Urchin ◽  
Urban Areas ◽  
Aquatic Organisms ◽  
Artemia Salina ◽  
Trophic Levels ◽  
Submicron Particles ◽  
Vehicle Exhaust ◽  
Exhaust Particles ◽  
The Difference

Vehicle emission particles (VEPs) represent a significant part of air pollution in urban areas. However, the toxicity of this category of particles in different aquatic organisms is still unexplored. This work aimed to extend the understanding of the toxicity of the vehicle exhaust particles in two species of marine diatomic microalgae, the planktonic crustacean Artemia salina, and the sea urchin Strongylocentrotus intermedius. These aquatic species were applied for the first time in the risk assessment of VEPs. Our results demonstrated that the samples obtained from diesel-powered vehicles completely prevented egg fertilization of the sea urchin S. intermedius and caused pronounced membrane depolarization in the cells of both tested microalgae species at concentrations between 10 and 100 mg/L. The sample with the highest proportion of submicron particles and the highest content of polycyclic aromatic hydrocarbons (PAHs) had the highest growth rate inhibition in both microalgae species and caused high toxicity to the crustacean. The toxicity level of the other samples varied among the species. We can conclude that metal content and the difference in the concentrations of PAHs by itself did not directly reflect the toxic level of VEPs, but the combination of both a high number of submicron particles and high PAH concentrations had the highest toxic effect on all the tested species.

Oxidation of ethylenethiourea in water via ozone enhanced by UV-C: identification of transformation products

2018 ◽  
Vol 26 (5) ◽  
pp. 4498-4509 ◽  
Author(s):  
Sue Ellen C. Bottrel ◽  
Pedro C. Pereira ◽  
Renata de Oliveira Pereira ◽  
Mônica M. D. Leão ◽  
Camila C. Amorim
Keyword(s):  
Transformation Products ◽  
Uv C

scholarly journals Sorption Characteristics of Mixed Molecules of Glutaraldehyde from Water on Mesoporous Acid-Amine Modified Low-Cost Activated Carbon: Mechanism, Isotherm, and Kinetics

2015 ◽  
Vol 2015 ◽  
pp. 1-13 ◽  
Author(s):  
Mukosha Lloyd ◽  
Onyango S. Maurice ◽  
Ochieng Aoyi ◽  
Taile Y. Leswifi
Keyword(s):  
Activated Carbon ◽  
Significant Contribution ◽  
Aldol Condensation ◽  
Low Cost ◽  
Aquatic Toxicity ◽  
Aquatic Organisms ◽  
Surface Groups ◽  
Intraparticle Diffusion Model ◽  
Cooperative Adsorption ◽  
Deactivation Process

The environmental discharge of inefficiently treated waste solutions of the strong biocide glutaraldehyde (GA) from hospitals has potential toxic impact on aquatic organisms. The adsorption characteristics of mixed polarized monomeric and polymeric molecules of GA from water on mesoporous acid-amine modified low-cost activated carbon (AC) were investigated. It was found that the adsorption strongly depended on pH and surface chemistry. In acidic pH, the adsorption mechanism was elaborated to involve chemical sorption of mainly hydroxyl GA monomeric molecules on acidic surface groups, while in alkaline pH, the adsorption was elaborated to involve both chemical and physical sorption of GA polymeric forms having mixed functional groups (aldehyde, carboxyl, and hydroxyl) on acidic and amine surface groups. The optimum pH of adsorption was about 12 with significant contribution by cooperative adsorption, elucidated in terms of hydrogen bonding and aldol condensation. Freundlich and Dubinin-Radushkevich models were fitted to isotherm data. The adsorption kinetics was dependent on initial concentration and temperature and described by the Elovich model. The adsorption was endothermic, while the intraparticle diffusion model suggested significant contribution by film diffusion. The developed low-cost AC could be used to supplement the GA alkaline deactivation process for efficient removal of residual GA aquatic toxicity.

Humic substances alleviate the aquatic toxicity of polyvinylpyrrolidone-coated silver nanoparticles to organisms of different trophic levels

2015 ◽  
Vol 34 (6) ◽  
pp. 1239-1245 ◽  
Author(s):  
Zhuang Wang ◽  
Joris T.K. Quik ◽  
Lan Song ◽  
Evert-Jan Van Den Brandhof ◽  
Marja Wouterse ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Humic Substances ◽  
Aquatic Toxicity ◽  
Trophic Levels
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