scholarly journals Investigating the hexavalent chromium removal from aqueous solution applying bee carcasses and corpses modified with Polyaniline

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Seyed Ali Hosseini ◽  
Majid Riahi Samani ◽  
Davood Toghraie
Keyword(s):  
Heavy Metals ◽  
Polyethylene Glycol ◽  
Hexavalent Chromium ◽  
Adsorption Isotherms ◽  
Contact Time ◽  
Environmental Pollutants ◽  
Industrial Effluents ◽  
Xrd Analysis ◽  
Chromium Concentration ◽  
Polyethylene Composite

AbstractThere are currently heavy metals in most industrial effluents which are among the most significant environmental pollutants. Hexavalent chromium is one of the most significant heavy metals. In this research for the first time, eliminating the hexavalent chromium from the aqueous medium/aquedia applying bee carcasses and corpses modified with polyethylene was examined. Adsorption experiments were conducted discontinuously on laboratory solutions, including hexavalent chromium. The optimal adsorption conditions such as different pH factors, contact time, initial chromium concentration, and adsorbent value on the adsorption rate were examined at different levels, and adsorption isotherms were plotted. Some adsorbent properties were examined using Field Emission Scanning Electron Microscopy, XRD analysis, Fourier Transform Infrared Spectroscopy, and BET test to study the properties of the synthesized adsorbent. This study indicated that the highest percentage of removal related to polyethylene composite and bee carcasses in the presence of polyethylene glycol was 50.56% among the bee carcasses composites. The parameters effective on the adsorption process for polyethylene composite and bee carcasses and losses in the presence of polyethylene glycol suggested that the adsorption percentage increased for this composite by decreasing the pH, increasing the contact time, and increasing the adsorbent. The highest percentage of adsorption was obtained when the pH was 2, the contact time was 120 min and the adsorbent value was 8 g/L and the initial concentration of chromium was 100 ppm. The most optimal removal percentage was achieved at the pH = 2, the contact time was 30 min, and the adsorbent value was 2 g/L, and the initial chromium concentration was 100 ppm. The results of drawing adsorption isotherms also indicated that higher R2 had a better fit than Langmuir for polyethylene composite and bee carcasses in the polyethylene glycol Freundlich equation.

scholarly journals Comparative Adsorptive Removal of Selected Heavy Metals from Battery Wastewater by Purified and Polyethylene Glycol Modified Carbon Nanotubes

2021 ◽  
Author(s):  
Abdulkareem AS ◽  
Hamzat WA ◽  
Tijani JO ◽  
Bankole MT ◽  
Titus Egbosiuba ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Carbon Nanotubes ◽  
Polyethylene Glycol ◽  
Toxic Metals ◽  
Contact Time ◽  
Batch Adsorption ◽  
Adsorption Effect ◽  
Adsorbent Dosage ◽  
Modified Carbon Nanotubes ◽  
Nano Adsorbent

Abstract Comparative adsorption study of some toxic metals (Ni, Fe, Cu, Cd, and Pb) from battery industrial effluent by purified and polyethylene glycol-modified carbon nanotubes (CNTs) is reported. The as-prepared CNTs via chemical vapour deposition method (A-CNTs), its acid purified form (P-CNTs), and polyethylene glycol functionalized form (PEG-CNTs) were characterized by HRTEM, BET, HRSEM, FTIR and XRD. The HRSEM and HRTEM micrograph revealed the formation of multi-walled tubular network structures of different inner and outer diameter. The BET study of PEG-CNTs and purified CNTs showed surface areas of 970.81 m2/g and 781.88 m2/g, respectively. The nanomaterials batch adsorption effect of various parameters such as contact time, nano-adsorbent dosage and temperature was conducted. The optimum equilibrium to achieve maximum removal of Cd (83.41 %), Ni (92.79 %), Fe (95.93%), Pb (97.16 %) Cu (99.9 9%) using PEG-CNTs was 90 min of contact time, 0.3 g of nano-adsorbent dosage and 60 oC temperature. While the maximum percentage removal efficiencies accomplished using P-CNTs under the same applied conditions were Cd (78.64 %), Ni (76.12 %), Fe (92.87 %), Pb (90.7 2%) Cu (99.09 %). PEG-CNTs was seen as more effective than P-CNTs. Adsorption data of Ni on P-CNTs followed Langmuir isotherm while the adsorption equilibrium model (Freundlich isotherm) of Ni, Fe, Cu and Pb on PEG-CNTs were fitted well. However, in both cases, the sorption kinetic study followed the pseudo-second-order model. The thermodynamics showed that the removal of toxic metals from battery wastewater was spontaneous and endothermic irrespective of the nano-adsorbents. The study found that surface modification of CNTs by polyethylene glycol adequately improved the nanotubes, thus leading to relatively adsorption capacities of heavy metals from industrial battery effluent.

scholarly journals Effective Removal of Hexavalent Chromium from Polluted Water using Phoenix sylvestris Seed Powder as Adsorbent

2019 ◽  
Vol 31 (6) ◽  
pp. 1327-1331
Author(s):  
P. KARUNASRI MEGHANA ◽  
K. VENKATA PRAVALIKA ◽  
P. JANAKI SRIRAM ◽  
K. RAVINDHRANATH
Keyword(s):  
Adsorption Capacity ◽  
Hexavalent Chromium ◽  
Extraction Method ◽  
Contact Time ◽  
Industrial Effluents ◽  
Polluted Water ◽  
Chromium Vi ◽  
Effective Removal ◽  
Maximum Extraction ◽  
Fold Excess

Phoenix sylvestris seed powder (PSSP) was investigated as an adsorbent for the removal of chromium(VI) ions from water using batch extraction method. The conditions for the maximum extraction were optimized. The adsorption capacity was found to be 22.5 mg/g at pH= 2, contact time: 60 min, PSSP dosage: 0.40 g/500mL, rpm: 300 and temp.: 28 ± 2 ºC and found to be more suitable adsorbant than compared to other reported adsorbents in the literature. Co-ions even in five-fold excess were less interfered. Regeneration studies revealed that Phoenix sylvestris seed powder can be used up to three cycles. The method developed was successfully applied to polluted water/industrial effluents samples.

scholarly journals Biodegradation of Pollutants in Waste Water from Pharmaceutical, Textile and Local Dye Effluent in Lagos, Nigeria

2016 ◽  
Vol 6 (12) ◽  
pp. 34-42 ◽  
Author(s):  
Idowu A. Aneyo ◽  
Funmilayo V. Doherty ◽  
Olumide A. Adebesin ◽  
Mariam O. Hammed
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Physicochemical Parameters ◽  
Low Cost ◽  
Environmental Pollutants ◽  
Oxygen Demand ◽  
Industrial Effluents ◽  
World Health ◽  
Klebsiella Pneumonia ◽  
The World

Background. Discharged effluents from industry have been responsible for the deterioration of the aquatic environment in many parts of the world, especially in developing countries. Increasing industrialization and urbanization have resulted in the discharge of large amounts of waste into the environment, resulting in high pollution loads. Utilization of microbes such as fungi and bacteria have been used for pollution degradation. Objectives. The aim of this research was to utilize microbial agents such as fungi and bacteria to reduce pollutant loads such as heavy metals in effluent samples. Methods. Three types of effluent (pharmaceutical, textile effluent, and dye) were obtained from Surulere in Lagos Metropolitan Area, Nigeria. Heavy metals analysis was carried out using a flame atomic adsorption spectrophotometer according to standard methods. Samples were cultured for microbes and identified. Bacteria samples were inoculated on nutrient agar and incubated at 37°C for 24 hours. Fungi counts were carried out using potato dextrose agar and incubated at 28°C for 3–5 days. The isolated organisms were identified based on their morphological and biochemical characteristics. Then 100 mL of the effluents was dispensed into 250 mL flasks, and the pH of the medium was adjusted to 7.2 by the addition of either sodium hydroxide or hydrogen chloride and autoclaved at 121°C for 15 minutes. The autoclaved flask was inoculated with 1 mL of bacteria and fungi for 21 days and pH was recorded properly every 48 hours. Results. The results of the physicochemical parameters indicated that conductivity, total suspended solids, total dissolved solids, turbidity, chemical oxygen demand and biochemical oxygen demand for all the three industrial effluents were higher than the World Health Organization (WHO) permissible limits. Heavy metal analysis results show that the effluents had high values for cadmium, above the WHO limit of 0.003 mg/L. Concentrations of zinc ranged from 0.136–1.690 mg/L, and nickel ranged between 0.004–0.037mg/L for the three effluents, within the WHO limit. The identified bacteria were Bacillus subtilis, Klebsiella pneumonia, Salmonella typhi and Bacillus cereus and isolated fungi were Aspergillus flavus and Penicillium chrysogenum. All the physicochemical parameters and heavy metal concentrations were reduced after the biodegradation study in the effluents. Conclusions. The responses observed in the various microbes indicated that the use of microbes for the reduction of environmental pollutants has an advantage over the use of other methods because it is environmentally friendly, low cost, and no new chemicals are introduced into the environment. This method should be encouraged for pollution reduction to bring about ecosystem sustainability advocated for Ghana.

Hexavalent chromium removal by using synthesis of polyaniline and polyvinyl alcohol

2016 ◽  
Vol 74 (10) ◽  
pp. 2305-2313 ◽  
Author(s):  
Majid Riahi Samani ◽  
Parisa Ebrahimbabaie ◽  
Hamed Vafaei Molamahmood
Keyword(s):  
Heavy Metals ◽  
Polyvinyl Alcohol ◽  
Hexavalent Chromium ◽  
Removal Efficiency ◽  
Chromium Concentration ◽  
Chromium Removal ◽  
Chromium Vi ◽  
Pani Composite ◽  
Stirring Time ◽  
Textile Finishing

Over the past few years, heavy metals have been proved to be one of the most important contaminants in industrial wastewater. Chromium is one of these heavy metals, which is being utilized in several industries such as textile, finishing and leather industries. Since hexavalent chromium is highly toxic to human health, removal of it from the wastewater is essential for human safety. One of the techniques for removing chromium (VI) is the use of different adsorbents such as polyaniline. In this study, composites of polyaniline (PANi) were synthesized with various amounts of polyvinyl alcohol (PVA). The results showed that PANi/PVA removed around 76% of chromium at a pH of 6.5; the PVA has altered the morphology of the composites and increased the removal efficiency. Additionally, synthesis of 20 mg/L of PVA by PANi composite showed the best removal efficiency, and the optimal stirring time was calculated as 30 minutes. Moreover, the chromium removal efficiency was increased by decreasing the pH, initial chromium concentration and increasing stirring time.

scholarly journals Eco Friendly Sorbent for the Removal of Iron and Lead from Industrial Waste Water

2019 ◽  
pp. 125-128
Author(s):  
Renjusha S ◽  
Shyama Nair
Keyword(s):  
Waste Water ◽  
Heavy Metals ◽  
Industrial Waste ◽  
Contact Time ◽  
Metal Ion ◽  
Industrial Effluents ◽  
Batch Adsorption ◽  
Industrial Waste Water ◽  
Adsorption Studies ◽  
Removal Of Heavy Metals

Industrial effluents loaded with heavy metals are a cause of hazards to human and other forms of life. Conventional methods such as chemical precipitation, evaporation, electroplating, ion exchange, reverse osmosis etc., used for removal of heavy metals from waste water however, are often cost prohibitive having inadequate efficiencies at low metal ion concentrations. Biosorption can be considered as an alternative technology which has been proved as more efficient and economical for removal of heavy metals from the industrial waste water. In the present study, the adsorption capacity of epicarp of Atrocarpus heterophyllus for the removal of heavy metals, lead and iron were determined by batch adsorption studies. Adsorption of heavy metals were studied till equilibrium was reached. Studies were carried by using different doses of adorbent, varying the conditions of adsorption and contact time. The results obtained shows that, the adsorption of the metal ions is contact time and adsorbent dosage dependent. Adsorption studies obeys both Langmuir isotherm model and Freundlich models. The goal for this work is to develop inexpensive, highly available, effective adsorbents from epicarp of jackfruit as alternative to existing commercial adsorbents.

Parameters Affecting Dye Adsorption - Using Graphene Coated Sand (GSC)

2018 ◽  
Vol 4 (02) ◽  
Author(s):  
Seroor Atalah Khaleefa Alia ◽  
Dr. Mohammed Ibrahimb ◽  
Hussein Ali Hussein
Keyword(s):  
Heavy Metals ◽  
Contact Time ◽  
Organic Dyes ◽  
Low Cost ◽  
Dye Adsorption ◽  
Contaminated Water ◽  
Maximum Adsorption Capacity ◽  
Engineering Designs ◽  
Heavy Metals Ions ◽  
Coated Sand

Adsorption is most commonly applied process for the removal of pollutants such as dyes and heavy metals ions from wastewater. The present work talks about preparing graphenic material attached sand grains called graphene sand composite (GSC) by using ordinary sugar as a carbon source. Physical morphology and chemical composition of GSC was examined by using (FTIR, SEM, EDAX and XRD). Efficiency of GSC in the adsorption of organic dyes from water was investigated using reactive green dye with different parameters such as (ph, temperature, contact time and dose). Adsorption isotherm was also studied and the results showed that the maximum adsorption capacity of dye is 28.98 mg/g. This fast, low-cost process can be used to manufacture commercial filters to treat contaminated water using appropriate engineering designs.

Utilisation of Biomass and Hybrid Biochar from Elephant Grass and Low Density Polyethylene for the Competitive Adsorption of Pb(II), Cu(II), Fe(II) and Zn(II) from Aqueous Media

2020 ◽  
Vol 13 ◽  
Author(s):  
Joshua O. Ighalo ◽  
Lois T. Arowoyele ◽  
Samuel Ogunniyi ◽  
Comfort A. Adeyanju ◽  
Folasade M. Oladipo-Emmanuel ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Removal Efficiency ◽  
Contact Time ◽  
Competitive Adsorption ◽  
Adsorption Process ◽  
Aqueous Media ◽  
Polluted Water ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Elephant Grass

Background: The presence of pollutants in polluted water is not singularized hence pollutant species are constantly in competition for active sites during the adsorption process. A key advantage of competitive adsorption studies is that it informs on the adsorbent performance in real water treatment applications. Objective: This study aims to investigate the competitive adsorption of Pb(II), Cu(II), Fe(II) and Zn(II) using elephant grass (Pennisetum purpureum) biochar and hybrid biochar from LDPE. Method: The produced biochar was characterised by Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). The effect of adsorption parameters, equilibrium isotherm modelling and parametric studies were conducted based on data from the batch adsorption experiments. Results: For both adsorbents, the removal efficiency was >99% over the domain of the entire investigation for dosage and contact time suggesting that they are very efficient for removing multiple heavy metals from aqueous media. It was observed that removal efficiency was optimal at 2 g/l dosage and contact time of 20 minutes for both adsorbent types. The Elovich isotherm and the pseudo-second order kinetic models were best-fit for the competitive adsorption process. Conclusion: The study was able to successfully reveal that biomass biochar from elephant grass and hybrid biochar from LDPE can be used as effective adsorbent material for the removal of heavy metals from aqueous media. This study bears a positive implication for environmental protection and solid waste management.

scholarly journals Synthesis, characterization and heavy metal removal efficiency of nickel ferrite nanoparticles (NFN’s)

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Waheed Ali Khoso ◽  
Noor Haleem ◽  
Muhammad Anwar Baig ◽  
Yousuf Jamal
Keyword(s):  
Heavy Metals ◽  
Nickel Ferrite ◽  
Contact Time ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Ferrite Nanoparticles ◽  
Batch Adsorption ◽  
Aqueous Environment ◽  
Human Beings ◽  
Nickel Ferrite Nanoparticles

AbstractThe heavy metals, such as Cr(VI), Pb(II) and Cd(II), in aqueous solutions are toxic even at trace levels and have caused adverse health impacts on human beings. Hence the removal of these heavy metals from the aqueous environment is important to protect biodiversity, hydrosphere ecosystems, and human beings. In this study, magnetic Nickel-Ferrite Nanoparticles (NFNs) were synthesized by co-precipitation method and characterized using X-Ray Diffraction (XRD), Energy Dispersive Spectroscopy (EDS) and Field Emission Scanning Electronic Microscopy (FE-SEM) techniques in order to confirm the crystalline structure, composition and morphology of the NFN’s, these were then used as adsorbent for the removal of Cr(VI), Pb(II) and Cd(II) from wastewater. The adsorption parameters under study were pH, dose and contact time. The values for optimum removal through batch-adsorption were investigated at different parameters (pH 3–7, dose: 10, 20, 30, 40 and 50 mg and contact time: 30, 60, 90, and 120 min). Removal efficiencies of Cr(VI), Pb(II) and Cd(II) were obtained 89%, 79% and 87% respectively under optimal conditions. It was found that the kinetics followed the pseudo second order model for the removal of heavy metals using Nickel ferrite nanoparticles.

scholarly journals Contamination of Heavy Metals, Polychlorinated Dibenzo-p-Dioxins/Furans and Dioxin-Like Polychlorinated Biphenyls in Wharf Roach Ligia spp. In Japanese Intertidal and Supratidal Zones

2021 ◽  
Vol 11 (4) ◽  
pp. 1856
Author(s):  
Masato Honda ◽  
Xuchun Qiu ◽  
Suzanne Lydia Undap ◽  
Takeshi Kimura ◽  
Tsuguhide Hori ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Polychlorinated Biphenyls ◽  
Limit Of Detection ◽  
Environmental Pollutants ◽  
Dry Weight ◽  
Polychlorinated Dibenzofurans ◽  
Environmental Indicator ◽  
Pollution Levels ◽  
Copper Zinc ◽  
Total Concentrations

We investigated the pollution levels of 6 heavy metals and 29 dioxins (polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and dioxin-like polychlorinated biphenyls (DL-PCBs)) in intertidal and supratidal zones by using wharf roaches (Ligia spp.) collected from 12 sampling sites on the coast of Northeast Japan from November 2011 to June 2012. The total concentrations of heavy metals ranged from 177 to 377 µg/g-dry weight (dw), and the predominant metals were copper, zinc, and aluminum. The order of the detected level of heavy metals was zinc > aluminum > copper > cadmium > lead > chromium, and this trend was similar to a previous report. The total toxic equivalent (TEQ) value of the PCDD/Fs ranged from less than the limit of detection (<LOD) to 2.33 pg-TEQ/g-dw, and the predominant congener was octachlorodibenzodioxin (<LOD to 110 pg/g-dw). Compared with PCDD/Fs, DL-PCBs were detected at a predominantly higher level (total TEQ value: 0.64–27.79 pg-TEQ/g-dw). Detected levels of dioxins, especially DL-PCBs in the wharf roach, were like those in the bivalves. These results indicate that the wharf roach could reflect heavy metals and dioxin pollution in the supratidal zones and is a suitable environmental indicator for these environmental pollutants. This is the first study to investigate heavy metals, PCDD/Fs, and DL-PCBs pollution in coastal isopods in Japan.

scholarly journals Application of modified green algae Nannochloropsis sp. as adsorbent in the simultaneous adsorption of Methylene Blue and Cu(II) cations in solution

2021 ◽  
Vol 31 (1) ◽  
Author(s):  
Buhani ◽  
Tri Agus Wijayanti ◽  
Suharso ◽  
Sumadi ◽  
Muslim Ansori
Keyword(s):  
Heavy Metals ◽  
Methylene Blue ◽  
Green Algae ◽  
Contact Time ◽  
Organic Dyes ◽  
Silica Matrix ◽  
Particle Coating ◽  
Adsorption Data ◽  
Magnetite Particles ◽  
Simultaneous Sorption

AbstractBiomass of algae is a very potent adsorbent for absorbing aqueous waste containing heavy metals and organic dyes. This study purposes to confirm the ability of adsorbents from green algae Nannochloropsis sp. modified with silica (ASN) and followed by coating magnetite particles (ASN-MPs) to absorb simultaneously the mixture of Methylene Blue (ME) and Cu(II) cations in aqueous solution. Simultaneous sorption of ME and Cu(II) cations to ASN and ASN-MPs was carried out by the batch method with the interaction pH condition 7, contact time 90 min, and initial concentrations of ME and Cu(II) cations (0.1–1.0 mM). Based on adsorption data, Cu(II) cations have a greater adsorption rate and capacity (qm) compared to ME at the same contact time and initial concentration. The adsorption capacity (qm) values of the bi-component ME and Cu(II) cation mixture in ASN and ASN-MPs were 1.39 × 10− 1 and 5.32 × 10− 1 mmol g− 1, respectively, with the binary Langmuir adsorption isotherm constant for Cu(II) cations greater than ME. Modified adsorbent from algae Nannochloropsis sp. with silica matrix and magnetite particle coating is an adsorbent that has a high effectiveness in the collective sorption of ME and Cu(II) cations. Therefore, these adsorbents can be used for the adsorption of cation mixtures of heavy metals and organic dyes that are cationic in solution.

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