Novel electrochemical fingerprinting methods for the precise determination of Ptshell coverage on Rucore nanoparticles

2014 ◽  
Vol 50 (78) ◽  
pp. 11558-11561 ◽  
Author(s):  
Ehab N. El Sawy ◽  
Hany A. El-Sayed ◽  
Viola I. Birss
Keyword(s):  
Precise Determination ◽  
Oxide Formation ◽  
Electronic Interactions ◽  
Co Stripping ◽  
Two Phases ◽  
First Time ◽  
Fingerprinting Methods ◽  
Core Nanoparticles

The electrochemical signatures of Ru oxide formation and CO stripping were used, for the first time, to determine the Pt shell coverage (from 0–2 monolayers) on Ru core nanoparticles, also revealing the chemical and electronic interactions that exist between these two phases.

scholarly journals The Cretaceous-Paleogene boundary in turbiditic deposits identified to the bed: a case study from the Skole Nappe (Outer Carpathians, southern Poland)

2011 ◽  
Vol 62 (4) ◽  
pp. 333-343 ◽  
Author(s):  
M. Gasiński ◽  
Alfred Uchman
Keyword(s):  
Precise Determination ◽  
Thrust Sheet ◽  
Southern Poland ◽  
The Carpathians ◽  
Early Paleocene ◽  
Outer Carpathians ◽  
First Time

The Cretaceous-Paleogene boundary in turbiditic deposits identified to the bed: a case study from the Skole Nappe (Outer Carpathians, southern Poland)The Cretaceous-Paleogene (K-T) boundary has been recognized in turbiditic sediments of the Ropianka Formation in the Skole Nappe (Bąkowiec section) on the basis of planktonic foraminiferids with an accuracy of 40 cm. Such precise determination of the K-T boundary for the first time in the Carpathians and in turbiditic flysch sediments in general was possible due to the successive occurrence of the Early Paleocene planktonic taxa of the P1 Zone above the latest MaastrichtianAbathomphalus mayaroensisZone with theRacemiguembelina fructicosaSubzone. The trends in composition of the latest Maastrichtian foraminiferal assemblages are similar to the Gaj section from the adjacent thrust sheet, probably due to the influence of the same paleoenvironmental factors.

PRECISE DETERMINATION OF BACKBONE STRUCTURE AND CONDUCTIVITY OF 3D PERCOLATION NETWORKS BY THE DIRECT ELECTRIFYING ALGORITHM

2009 ◽  
Vol 20 (03) ◽  
pp. 423-433 ◽  
Author(s):  
CHUNYU LI ◽  
TSU-WEI CHOU
Keyword(s):  
Efficient Algorithm ◽  
Precise Determination ◽  
Scaling Exponents ◽  
Resistor Network ◽  
Backbone Structure ◽  
Definition Of ◽  
First Time ◽  
Good Agreement

This paper confirms the applicability of a newly developed efficient algorithm, the direct electrifying method, for identifying backbone for 3D site and bond percolating networks. This algorithm is based on the current-carrying definition of backbone and carried out on the predetermined spanning cluster, which is assumed to be a resistor network. The scaling exponents so obtained for backbone mass, red bonds, and conductivity are in very good agreement with some existing results. The perfectly balanced bonds in 3D backbone structures are predicted first time to be 0.00179 ± 0.00009 and 0.00604 ± 0.00008 of the backbone mass for bond and site percolations, respectively.

scholarly journals Differential impedance spectra analysis reveals optimal actuation frequency in bulk mode acoustophoresis

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Valentina Vitali ◽  
Giulia Core ◽  
Fabio Garofalo ◽  
Thomas Laurell ◽  
Andreas Lenshof
Keyword(s):  
Precise Determination ◽  
Impedance Spectra ◽  
Actuation Frequency ◽  
Spectra Analysis ◽  
Resonance Modes ◽  
Bulk Mode ◽  
Working Frequency ◽  
First Time ◽  
Channel Resonance

AbstractThis work reports a method to select the optimal working frequency in transversal bulk resonator acoustophoretic devices by electrical impedance measurements. The impedance spectra of acoustophoretic devices are rich in spurious resonance peaks originating from different resonance modes in the system not directly related to the channel resonance, why direct measurement of the piezoelectric transducer impedance spectra is not a viable strategy. This work presents, for the first time, that the resonance modes of microchip integrated acoustophoresis channels can be identified by sequentially measuring the impedance spectra of the acoustophoretic device when the channel is filled with two different fluids and subsequently calculate the Normalized Differential Spectrum (NDS). Seven transversal bulk resonator acoustophoretic devices of different materials and designs were tested with successful results. The developed method enables a rapid, reproducible and precise determination of the optimal working frequency.

scholarly journals CKM PARAMETERS AND RARE B DECAYS

2006 ◽  
Vol 21 (08n09) ◽  
pp. 1683-1696 ◽  
Author(s):  
FRANCESCO FORTI
Keyword(s):  
B Meson ◽  
New Physics ◽  
Precise Determination ◽  
Model Parameters ◽  
B Decays ◽  
Unitarity Triangle ◽  
Indirect Determination ◽  
Radiative Transitions ◽  
First Time

Measurements of the angles and sides of the unitarity triangle and of the rates of rare B meson decays are crucial for the precise determination of Standard Model parameters and are sensitive to the presence of new physics particles in the loop diagrams. In this paper the recent measurements performed in this area by BABAR and Belle will be presented. The direct measurement of the angle α is for the first time as precise as the indirect determination. The precision of the |Vub| determination has improved significantly with respect to previous measurement. New limits on B → τν decays are presented, as well as updated measurements on b → s radiative transitions and a new observation of b → dγ transition made by Belle.

scholarly journals Simultaneous determination of CKM angle γ and charm mixing parameters

2021 ◽  
Vol 2021 (12) ◽  
Author(s):  
◽  
R. Aaij ◽  
A. S. W. Abdelmotteleb ◽  
C. Abellán Beteta ◽  
F. Abudinén ◽  
...  
Keyword(s):  
Hadron Collider ◽  
Precise Determination ◽  
Unitarity Triangle ◽  
Single Experiment ◽  
Mixing Parameters ◽  
Mixing Parameter ◽  
Lhcb Detector ◽  
First Time ◽  
Charm Mixing

Abstract A combination of measurements sensitive to the CP violation angle γ of the Cabibbo-Kobayashi-Maskawa unitarity triangle and to the charm mixing parameters that describe oscillations between D0 and $$ \overline{D} $$ D ¯ 0 mesons is performed. Results from the charm and beauty sectors, based on data collected with the LHCb detector at CERN’s Large Hadron Collider, are combined for the first time. This method provides an improvement on the precision of the charm mixing parameter y by a factor of two with respect to the current world average. The charm mixing parameters are determined to be $$ x=\left({0.400}_{-0.053}^{+0.052}\right)\% $$ x = 0.400 − 0.053 + 0.052 % and y = $$ \left({0.630}_{-0.030}^{+0.033}\right)\% $$ 0.630 − 0.030 + 0.033 % . The angle γ is found to be γ = $$ \left({65.4}_{-4.2}^{+3.8}\right){}^{\circ} $$ 65.4 − 4.2 + 3.8 ° and is the most precise determination from a single experiment.

Determination of europium isotope ratios in natural waters by MC-ICP-MS

2017 ◽  
Vol 32 (5) ◽  
pp. 987-995 ◽  
Author(s):  
Gabriel Gustinelli Arantes de Carvalho ◽  
Pedro Vitoriano Oliveira ◽  
Lu Yang
Keyword(s):  
Inductively Coupled Plasma ◽  
Natural Waters ◽  
Precise Determination ◽  
Single Step ◽  
Inductively Coupled ◽  
Analytical Protocol ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
First Time

An analytical protocol for the accurate and precise determination of the europium isotope ratio in low level natural waters is presented for the first time by using multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) with a single-step column separation with di(2-ethylhexyl) orthophosphoric acid (HDEHP) resin.

scholarly journals Possible substellar companions in low-mass eclipsing binaries: GU Bootis and YY Geminorum

2018 ◽  
Vol 620 ◽  
pp. A72
Author(s):  
M. Wolf ◽  
H. Kučáková ◽  
P. Zasche ◽  
J. Vraštil ◽  
K. Hoňková ◽  
...  
Keyword(s):  
Precise Determination ◽  
Time Effect ◽  
Eclipsing Binaries ◽  
Physical Parameters ◽  
The Third ◽  
Low Mass ◽  
Orbital Periods ◽  
First Time

We present the next results of our long-term observational project to analyze the variations in the orbital periods of low-mass eclipsing binaries. About 70 new precise mid-eclipse times recorded with a CCD were obtained for two eclipsing binaries with short orbital periods: GU Boo (P = 0.​d49) and YY Gem (0.​d81). Observed-minus-calculated diagrams of the stars were analyzed using all reliable timings, and new parameters of the light-time effect were obtained. We derived for the first time or improved the short orbital periods of possible third bodies of 11 and 54 years for these low-mass binaries, respectively. We calculated that the minimum masses of the third components are close to 50 MJup, which corresponds to the mass of brown dwarfs. The multiplicity of these systems also plays an important role in the precise determination of their physical parameters.

scholarly journals An overtone Cepheid variable in an LMC eclipsing binary

2004 ◽  
Vol 193 ◽  
pp. 372-376 ◽  
Author(s):  
D. Lepischak ◽  
D.L. Welch
Keyword(s):  
Evolutionary History ◽  
Binary Systems ◽  
Precise Determination ◽  
Light Curves ◽  
Intermediate Mass ◽  
Eclipsing Binary ◽  
Spectroscopic Binary ◽  
First Time ◽  
Absolute Luminosity

AbstractEclipsing binary systems potentially allow the direct and precise determination of the important properties of their component stars. An eclipsing binary containing a Cepheid variable which is also a double-lined spectroscopic binary would allow, for the first time, the direct measurement of the absolute luminosity and mass of the Cepheid. The MACHO Project LMC database contains five systems whose light curves show variations due to both eclipses and pulsation but only one has been clearly identified as an intermediate-mass, Population I object. This object, MACHO 81.8997.87 (= OGLELMC_SC16 119952) is a 2.035-d overtone Cepheid in an 800.4-d binary system with an M-type companion. Here we present the results of the analysis of the light curve of this system, the implications for its evolutionary history and discuss the prospects for future observations.

New X-ray powder diffraction data for Fe, B substituted Rb-leucites (RbFeSi2O6 and RbBSi2O6)

1997 ◽  
Vol 12 (2) ◽  
pp. 87-89 ◽  
Author(s):  
D. Mazza ◽  
M. Lucco Borlera
Keyword(s):  
Powder Diffraction ◽  
Sol Gel ◽  
Precise Determination ◽  
Lattice Parameters ◽  
X Ray ◽  
Space Groups ◽  
Gel Preparation ◽  
First Time ◽  
Icdd Card

The boron and iron for aluminum substitution in the Rb-leucite structure (RbAlSi2O6, ICDD card 38-201) has been examined by sol-gel preparation of different samples along the three compositional joins Rb(X,Y)Si2O6, where X and Y are any two of the elements Al, Fe, B. The compound RbBSi2O6 (a0=12.831 Å) is here described and characterized by X-ray powder diffraction for the first time, while the compound RbFeSi2O6 is reexamined with a more precise determination of lattice parameters and diffraction intensities with respect to ICDD card 31-1189. The lattice parameters and the space groups of different selected terms of the three solid solutions are reported.

scholarly journals New insight on the simultaneous H2 and HNO2 production in concentrated HNO3 aqueous solutions under alpha radiation

RSC Advances ◽  
2021 ◽  
Vol 11 (20) ◽  
pp. 12141-12152
Author(s):  
Raluca M. Musat ◽  
Jean-Luc Roujou ◽  
Vincent Dauvois ◽  
Muriel Ferry ◽  
Carole Marchand ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Precise Determination ◽  
Alpha Radiation ◽  
System P ◽  
Set Up ◽  
First Time

For the first time ever, a specially designed set-up, coupled to the CEMHTI cyclotron allowed in situ monitoring of HNO2 and precise determination of H2 production in the external α radiolysis of HNO3 solution, while ensuring no perturbation of the investigated system.

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