scholarly journals Synthesis of simple, low cost and benign sol–gel Cu2InxZn1−xSnS4alloy thin films: influence of different rapid thermal annealing conditions and their photovoltaic solar cells

RSC Advances ◽  
2018 ◽  
Vol 8 (17) ◽  
pp. 9038-9048 ◽  
Author(s):  
Yingrui Sui ◽  
Yanjie Wu ◽  
Yu Zhang ◽  
Fengyou Wang ◽  
Yanbo Gao ◽  
...  

Cu2InxZn1−xSnS4(x= 0.4) alloy thin films were synthesized on soda lime glass (SLG) substrate by a simple low-cost sol–gel method followed by a rapid annealing technique.

2015 ◽  
Vol 1109 ◽  
pp. 461-465 ◽  
Author(s):  
Nurbaya Zainal ◽  
Mohd Hafiz Wahid ◽  
Mohammad Rusop

Performance of lead titanate, (PbTiO3) thin films have been successfully investigated on microstructural properties, I-V characteristic, dielectric properties, and ferroelectric properties. PbTiO3offers variety of application as transducer, ferroelectric random access memory, transistor, high performance capacitor, sensor, and many more due to its ferroelectric behavior. Preparation of the films are often discussed in order to improve the structural properties, like existence of grain boundaries, particle uniformity, presents of microcrack films, porosities, and many more. Yet, researchers still prepare PbTiO3thin films at high crystallization temperature, certainly above than 600 ̊C to obtain single crystal perovskite structure that would be the reason to gain high spontaneous polarization behavior. Although this will results to high dielectric constant value, the chances that leads to high leakage current is a major failure in device performance. Thus, preparation the thin films at low annealing temperature quite an essential study which is more preferable deposited on low-cost soda lime glass. The study focuses on low annealing temperature of PbTiO3thin films through sol-gel spin coating method and undergo for dielectric and I-V measurements.


2021 ◽  
Vol 14 (3) ◽  
pp. 249-253

Abstract: In this paper, suitability of thallium sulphide films were investigated as an alternative to conventional silicon and germanium that were used as window layers in solar cells. Thin films were deposited on soda lime glass (SLG) substrates in a chemical bath containing Thallium Chloride (TlCl2) and Thiourea (NH2)2CS which was conditioned at 80 ºC for about 5 hours to deposit the films. Effects of annealing on the film samples at 300 ºC and 350 ºC were studied respectively by use of UV-VIS Avantes electrophotometer and Four-Point-Probe (FPP) machine in the light region with wavelength range from 200 nm to 1000 nm. The results obtained suggest that the thin films obtained are good materials for optoelectronics. The absorption spectra exhibited a relatively high energy band-gap. Materials of this nature are good for window layers which serve as passage to the absorber layer where needed charge carriers are produced. Keywords: Thin film, Thallium Sulphide, Window layer, Optoelectronics, Solar cells.


2014 ◽  
Vol 1004-1005 ◽  
pp. 774-777 ◽  
Author(s):  
Ji Wan Liu ◽  
Gui Lin Chen ◽  
Wei Feng Liu ◽  
Guo Shun Jiang ◽  
Chang Fei Zhu

A low-cost non-vacuum process for fabrication of Cu2SnSe3 film by sol-gel method and knife-coating process is described. First, a certain amount of Copper (I) chloride and tin (IV) tetrachloride was dissolve into the mixture of water and alcohol and then some Polyvinyl Pyrrolidone (PVP) was added to the solution to obtain based colloidal solution. Next, precursor thin layer was deposited by knife-blading technique on soda-lime glass (SLG). Finally, precursor layer was annealed at selenium flow atmosphere carried by Ar gas at 550oC. Through X-ray diffraction (XRD) and Raman spectra, it is found that pure Cu2SnSe3 film was prepared successfully. Scanning electron microscopy (SEM) and UV–vis–NIR absorbance spectroscopy were used to characterize its morphology and optical bandgap.


2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Weimin Li ◽  
Xia Yan ◽  
Armin G. Aberle ◽  
Selvaraj Venkataraj

Molybdenum (Mo) thin films are widely used as rear electrodes in copper indium gallium diselenide (CIGS) solar cells. The challenge in Mo deposition by magnetron sputtering lies in simultaneously achieving good adhesion to the substrates while retaining the electrical and optical properties. Bilayer Mo films, comprising five different thickness ratios of a high pressure (HP) deposited bottom layer and a low pressure (LP) deposited top layer, were deposited on 40 cm × 30 cm soda-lime glass substrates by DC magnetron sputtering. We focus on understanding the effects of the individual layer properties on the resulting bilayer Mo films, such as microstructure, surface morphology, and surface oxidation. We show that the thickness of the bottom HP Mo layer plays a major role in determining the micromechanical and physical properties of the bilayer Mo stack. Our studies reveal that a thicker HP Mo bottom layer not only improves the adhesion of the bilayer Mo, but also helps to improve the film crystallinity along the preferred [110] direction. However, the surface roughness and the porosity of the bilayer Mo films are found to increase with increasing bottom layer thickness, which leads to lower optical reflectance and a higher probability for oxidation at the Mo surface.


2005 ◽  
Vol 475-479 ◽  
pp. 3897-3900
Author(s):  
Qing Ju Liu ◽  
Jin Zhang ◽  
Zhongqi Zhu ◽  
Yingxia Jin ◽  
Qing Hui Wang

TiO2-Al2O3 composite thin films were fabricated on soda-lime glass with sol-gel technology. By measuring the contact angle of water with the film surface and the analysis of the XRD and XPS, we studied the influence of Al2O3 doping concentration and film thickness on the hydrophilicity of the composite films. The results indicate that the doping of Al2O3 into TiO2 and the relatively large thickness of the films can improve their hydrophilicity.


2020 ◽  
Vol 33 (1) ◽  
pp. 24-30
Author(s):  
Anil Kumar Verma ◽  
Swati Sahu ◽  
Mohan Patel ◽  
Sanjay Tiwari

In this work, ZnO has been prepared by the sol-gel method and thin films have been deposited onto the ITO (Indium-Tin-Oxide) coated glass substrates by spin coating method at different ZnO concentration and spin parameters. For this, Sol-gel ZnO was synthesized by Zinc acetate dehydrate, 2-methoxethanol and ethanolamine as a starting material, solvent and stabilizer respectively. The study of deposition parameters on the structural, optical and electrical properties of the ZnO thin films was carried out. The Roughness and thickness were calculated by Profilometer. X-ray diffraction (XRD) analysis of the films showed the polycrystalline nature of the prepared films. Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) was used to describe the surface morphology and optical properties were studied using UV-VIS-IR Spectroscopy. The fabricated results showed that ZnO thin films is crystalline and low-cost techniques with good features that will be useful for Organic Solar Cells (OSCs) device as an electron transport layer.


Nanomaterials ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 955 ◽  
Author(s):  
Yingrui Sui ◽  
Yu Zhang ◽  
Dongyue Jiang ◽  
Wenjie He ◽  
Zhanwu Wang ◽  
...  

Cu2MgxZn1−xSnS4 (0 ≤ x ≤0.6) thin films were prepared by a simple, low-temperature (300 °C) and low-cost sol–gel spin coating method followed by post-annealing at optimum conditions. We optimized the annealing conditions and investigated the effect of Mg content on the crystalline quality, electrical and optical performances of the Cu2MgxZn1−xSnS4 thin films. It was found that the Cu2MgxZn1−xSnS4 film annealed at 580 °C for 60 min contained large grain, less grain boundaries and high carrier concentration. Pure phase kesterite Cu2MgxZn1−xSnS4 (0 ≤ x ≤ 0.6) thin films were obtained by using optimal annealing conditions; notably, the smaller Zn2+ ions in the Cu2ZnSnS4 lattice were replaced by larger Mg2+ ions. With an increase in x from 0 to 0.6, the band gap energy of the films decreased from 1.43 to 1.29 eV. When the ratio of Mg/Mg + Zn is 0.2 (x = 0.2), the grain size of Cu2MgxZn1−xSnS4 reaches a maximum value of 1.5 μm and the surface morphology is smooth and dense. Simultaneously, the electrical performance of Cu2MgxZn1−xSnS4 thin film is optimized at x = 0.2, the carrier concentration reaches a maximum value of 3.29 × 1018 cm−3.


2019 ◽  
Vol 203 ◽  
pp. 110168 ◽  
Author(s):  
Sven Kühnapfel ◽  
Stefanie Severin ◽  
Norbert Kersten ◽  
Paul Harten ◽  
Bert Stegemann ◽  
...  

2018 ◽  
Vol 778 ◽  
pp. 86-90
Author(s):  
Muhammad Yasir Khan ◽  
Ali Dad Chandio ◽  
Muhammad Sohail ◽  
Muhammad Arsalan ◽  
Muhammad Wasim Akhtar ◽  
...  

The nano-sized TiO2is an important material based on its application for solar cells. The low-cost synthesis of nano-sized TiO2is of high demand for commercial purposes. Synthesis of TiO2nanoparticles was achieved via the low-temperature Sol-gel method. Surface morphology was confirmed from SEM analysis, which showed that particle size is in the range of nanometer with no aggregation, The XRD results confirm the formation of anatase phase with high crystallinity. Furthermore, as prepared nano-sized TiO2particles were developed as sol-gel ink which was later deposited by spin coating on glass substrate with controlled spinning speed thereafter structural and optical properties were characterized by UV-vis spectroscopy, electrochemical impedance spectroscopy and DSC-TGA. The low-cost synthesis of TiO2nanoparticles with highly conductive thin films can be used as a potential material for future dye-sensitized solar cells


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