scholarly journals Synchrotron X-ray spectroscopy for investigating vanadium speciation in marine sediment: limitations and opportunities

2018 ◽  
Vol 33 (10) ◽  
pp. 1689-1699 ◽  
Author(s):  
William W. Bennett ◽  
Enzo Lombi ◽  
Edward D. Burton ◽  
Scott G. Johnston ◽  
Peter Kappen ◽  
...  

Synchrotron-based X-ray spectroscopy is a powerful technique for investigating vanadium speciation in marine sediment.


Author(s):  
G. Van Tendeloo ◽  
J. Van Landuyt ◽  
S. Amelinckx

Polytypism has been studied for a number of years and a wide variety of stacking sequences has been detected and analysed. SiC is the prototype material in this respect; see e.g. Electron microscopy under high resolution conditions when combined with x-ray measurements is a very powerful technique to elucidate the correct stacking sequence or to study polytype transformations and deviations from the ideal stacking sequence.



Crystals ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 87 ◽  
Author(s):  
Cinzia Giannini ◽  
Massimo Ladisa ◽  
Davide Altamura ◽  
Dritan Siliqi ◽  
Teresa Sibillano ◽  
...  


Marine Drugs ◽  
2018 ◽  
Vol 16 (9) ◽  
pp. 329 ◽  
Author(s):  
Jian-Lin Xu ◽  
Hong-Xin Liu ◽  
Yu-Chan Chen ◽  
Hai-Bo Tan ◽  
Heng Guo ◽  
...  

Five new benzophenone derivatives named tenellones D–H (1–5), sharing a rare naturally occurring aldehyde functionality in this family, and a new eremophilane derivative named lithocarin A (7), together with two known compounds (6 and 8), were isolated from the deep marine sediment-derived fungus Phomopsis lithocarpus FS508. All of the structures for these new compounds were fully characterized and established on the basis of extensive spectroscopic interpretation and X-ray crystallographic analysis. Compound 5 exhibited cytotoxic activity against HepG-2 and A549 cell lines with IC50 values of 16.0 and 17.6 μM, respectively.



1989 ◽  
Vol 222 (1) ◽  
pp. 169-175 ◽  
Author(s):  
J.M. Eckert ◽  
K.E.A. Leggett ◽  
J.B. Keene ◽  
K.L. Williams


2014 ◽  
Vol 09 (03) ◽  
pp. 205-224 ◽  
Author(s):  
Veronica J. James

This discussion about diagnostic tests for cancer incorporates a powerful branch of Physics namely X-ray diffraction. Although this technique was used to solve the DNA structure using the X-ray diffraction pictures of Rosalind Franklin,1 and the structure of vitamin B12 by Dorothy Hodgkin2 and hosts of other medical related structures, it is poorly understood by the general medical profession and the community at large. To the nonphysicist the patterns appear to have no relation to the results produced. It might as well be written in Greek. The well-known quote of Poincaré, the famous French mathematician and scientist, in 1885 comes to mind: "Science is built up with facts as a house is with stones. But a collection of facts is no more a science than a heap of stones is a house." In order therefore to build a true understanding of this powerful technique it is necessary to build a firm understanding of the basic facts about this technique, so that the final results will be clear to all, as they will be held up by a firm house of knowledge. So let us take up the first stone.



2012 ◽  
Vol 545 ◽  
pp. 3-15
Author(s):  
Hoong Kun Fun ◽  
Suchada Chantrapromma ◽  
Nawong Boonnak

Drug discovery from natural products resources have been extensively studied. The most important step in the discovery process is the identification of compounds with interesting biological activity. Single crystal X-ray structure determination is a powerful technique for natural products research and drug discovery in which the detailed three-dimensional structures that emerge can be co-related to the activities of these structures. This article shall present (i) co-crystal structures, (ii) determination of absolute configuration and (iii) the ability to distinguish between whether a natural product compound is a natural product or a natural product artifact. All these three properties are unique to the technique of single crystal X-ray structure determination.





2015 ◽  
Vol 407 (24) ◽  
pp. 7487-7496 ◽  
Author(s):  
Milan Žižić ◽  
Tanja Dučić ◽  
Daniel Grolimund ◽  
Danica Bajuk-Bogdanović ◽  
Miroslav Nikolic ◽  
...  


Author(s):  
Gabrielle Schanne ◽  
Lucas Henry ◽  
How Chee Ong ◽  
andrea somogyi ◽  
Kadda Medjoubi ◽  
...  

Synchrotron Radiation X-ray Fluorescence (SXRF) imaging is a powerful technique for the visualization of metal complexes in biological systems. However, due to the lack of an endogenous elemental signature for...



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