Critical role of metal ions in surface engineering toward brightly luminescent and stable cesium lead bromide perovskite quantum dots

Nanoscale ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 2602-2607 ◽  
Author(s):  
Congyang Zhang ◽  
Bo Wang ◽  
Qun Wan ◽  
Long Kong ◽  
Weilin Zheng ◽  
...  

A facile metal ions-assistant ligand surface engineering strategy to synchronously boost photoluminescence quantum yield and stability of CsPbBr3 PQDs.

Author(s):  
Lin Yang ◽  
Bowen Fu ◽  
Xu Li ◽  
Hao Chen ◽  
Lili Li

All inorganic perovskite quantum dots (QDs) have received great attention owing to their excellent performance in optoelectronic applications. However, they often suffer from the defect-related photoluminescence (PL) quenching and phase...


Author(s):  
Junke Jiang ◽  
Feng Liu ◽  
Qing Shen ◽  
Shuxia Tao

Narrow-bandgap CsSnxPb1-xI3 perovskite quantum dots (QDs) show great promise for optoelectronic applications owing to their reduced use of toxic Pb, improved phase stability, and tunable band gaps in the visible...


Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 710 ◽  
Author(s):  
Sujeong Jung ◽  
Jae Ho Kim ◽  
Jin Woo Choi ◽  
Jae-Wook Kang ◽  
Sung-Ho Jin ◽  
...  

We determine the influence of substitutional defects on perovskite quantum dots through experimental and theoretical investigations. Substitutional defects were introduced by trivalent dopants (In, Sb, and Bi) in CsPbBr3 by ligand-assisted reprecipitation. We show that the photoluminescence (PL) emission peak shifts toward shorter wavelengths when doping concentrations are increased. Trivalent metal-doped CsPbBr3 enhanced the PL quantum yield (~10%) and air stability (over 10 days). Our findings provide new insights into the influence of substitutional defects on substituted CsPbBr3 that underpin their physical properties.


Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2484-2491 ◽  
Author(s):  
Yue Zhai ◽  
Xue Bai ◽  
Gencai Pan ◽  
Jinyang Zhu ◽  
He Shao ◽  
...  

Co-doping of cation (La3+) and anion (F−) ions is a feasible method to improve the optical properties of CsPbCl3 QDs, and high photoluminescence quantum yield of 36.5% is achieved in CsPb(Cl0.7F0.3)3:La3+ QDs.


2020 ◽  
Vol 5 (3) ◽  
pp. 580-585 ◽  
Author(s):  
Yalong Shen ◽  
Jun Yin ◽  
Bo Cai ◽  
Ziming Wang ◽  
Yuhang Dong ◽  
...  

Lead-free Bi-based perovskite FA3Bi2X9 (X = Cl, Br, and I) quantum dots (QDs) are synthesized for the first time at room temperature. The ligand-passivated FA3Bi2Br9 QDs exhibit blue emission at 437 nm with photoluminescence quantum yield (PLQY) up to 52%.


2019 ◽  
Vol 10 (41) ◽  
pp. 9530-9541 ◽  
Author(s):  
Dibyendu Ghosh ◽  
Dhirendra K. Chaudhary ◽  
Md. Yusuf Ali ◽  
Kamlesh Kumar Chauhan ◽  
Sayan Prodhan ◽  
...  

Grain boundaries in bulk perovskite films are considered as giant trapping sites for photo-generated carriers. Surface engineering via inorganic perovskite quantum dots has been employed for creating monolithically grained, pin-hole free perovskite films.


2021 ◽  
pp. 132425
Author(s):  
Omar Abdelkarim ◽  
Gurpreet S. Selopal ◽  
Karthik Suresh ◽  
Fabiola Navarro-Pardo ◽  
Pawan Kumar ◽  
...  

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