scholarly journals A solid-state chemical method for synthesizing MgO nanoparticles with superior adsorption properties

RSC Advances ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 2011-2017 ◽  
Author(s):  
Hongyu Zhang ◽  
Jindou Hu ◽  
Jing Xie ◽  
Shiqiang Wang ◽  
Yali Cao

As a traditional and effective adsorbent, MgO is a low-cost, eco-friendly, nontoxic, and economical material for wastewater treatment.

Coatings ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 693
Author(s):  
Angela Longo ◽  
Mariano Palomba ◽  
Gianfranco Carotenuto

The reduction of graphene oxide (GO) thin films deposited on substrates is crucial to achieve a technologically useful supported graphene material. However, the well-known thermal reduction process cannot be used with thermally unstable substrates (e.g., plastics and paper), in addition photo-reduction methods are expensive and only capable of reducing the external surface. Therefore, solid-state chemical reduction techniques could become a convenient approach for the full thickness reduction of the GO layers supported on thermally unstable substrates. Here, a novel experimental procedure for quantitative reduction of GO films on paper by a green and low-cost chemical reductant (L-ascorbic acid, L-aa) is proposed. The possibility to have an effective mass transport of the reductant inside the swelled GO solid (gel-phase) deposit was ensured by spraying a reductant solution on the GO film and allowing it to reflux in a closed microenvironment at 50 °C. The GO conversion degree to reduced graphene oxide (r-GO) was evaluated by Fourier transform infrared spectroscopy (FT-IR) in attenuated total reflectance (ATR) mode and X-ray Diffraction (XRD). In addition, morphology and wettability of GO deposits, before and after reduction, were confirmed by digital USB microscopy, scanning electron microscopy (SEM), and contact angle measurements. According to these structural characterizations, the proposed method allows a bulky reduction of the coating but leaves to a GO layer at the interface, that is essential for a good coating-substrate adhesion and this special characteristic is useful for industrial exploitation of the material.


2021 ◽  
Vol 2021 ◽  
pp. 1-19
Author(s):  
Samia Ben-Ali

The use of renewable substrates as biosorbents has a great attention in wastewater treatment. The pomegranate peel (PGP) constitutes one of these substrates. A review is carried out to investigate the potential of pomegranate peel (PGP) for wastewater treatment. Physical and chemical PGP properties are presented and compared to those of Tunisian pomegranate peel (El Gabsi). Raw and modified PGP performance and sorption capacity for metals, dyes, and organic pollutants are evaluated. Different experimental sorption conditions such as concentration, contact time, pH, temperature, and adsorbent dose used in the literature are illustrated. Studied and best-fitted kinetics and isotherm models to experimental data and thermodynamic parameters are compared. The effects of activating physical and/or chemical conditions on the activated PGP properties are presented. This paper reveals noteworthiness properties of raw PGP for wastewater treatment compared to this activated form. The comparison between activated and raw PGP morphology exhibits that the activation does not necessarily improve the PGP adsorption capacity. Despite a limited research carried out on the raw PGP biosorbent, it appears from this study that it has very good adsorption properties, making it a serious and low-cost renewable substrate toward practical applications in wastewater treatment compared to various other waste agricultural biomass.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1192
Author(s):  
Hisham S. M. Abd-Rabboh ◽  
Abd El-Galil E. Amr ◽  
Abdulrahman A. Almehizia ◽  
Ayman H. Kamel

In recent times, the application of the use of ion-selective electrodes has expanded in the field of pharmaceutical analyses due to their distinction from other sensors in their high selectivity and low cost of measurement, in addition to their high measurement sensitivity. Cost-effective, reliable, and robust all-solid-state potentiometric selective electrodes were designed, characterized, and successfully used for pholcodine determination. The design of the sensor device was based on the use of a screen-printed electrode modified with multiwalled carbon nanotubes (MWCNTs) as a solid-contact transducer. Tailored pholcodine (PHO) molecularly imprinted polymers (MIPs) were prepared, characterized, and used as sensory receptors in the presented potentiometric sensing devices. The sensors exhibited a sensitivity of 31.6 ± 0.5 mV/decade (n = 5, R2 = 0.9980) over the linear range of 5.5 × 10−6 M with a detection limit of 2.5 × 10−7 M. Real serum samples in addition to pharmaceutical formulations containing PHO were analyzed, and the results were compared with those obtained by the conventional standard liquid chromatographic approach. The presented analytical device showed an outstanding efficiency for fast, direct, and low-cost assessment of pholcodine levels in different matrices.


Author(s):  
Kathryn Holguin ◽  
Motahareh Mohammadiroudbari ◽  
Kaiqiang Qin ◽  
Chao Luo

Na-ion batteries (NIBs) are promising alternatives to Li-ion batteries (LIBs) due to the low cost, abundance, and high sustainability of sodium resources. However, the high performance of inorganic electrode materials...


2015 ◽  
Vol 184 ◽  
pp. 202-214 ◽  
Author(s):  
Abbas Mehrabadi ◽  
Rupert Craggs ◽  
Mohammed M. Farid

Data in Brief ◽  
2019 ◽  
Vol 26 ◽  
pp. 104308 ◽  
Author(s):  
Golan Yeganeh ◽  
Bahman Ramavandi ◽  
Hossein Esmaeili ◽  
Sajad Tamjidi

2020 ◽  
Vol 11 (1) ◽  
pp. 174
Author(s):  
Konstantinos P. Papadopoulos ◽  
Christina N. Economou ◽  
Athanasia G. Tekerlekopoulou ◽  
Dimitris V. Vayenas

Algal/cyanobacterial biofilm photobioreactors provide an alternative technology to conventional photosynthetic systems for wastewater treatment based on high biomass production and easy biomass harvesting at low cost. This study introduces a novel cyanobacteria-based biofilm photobioreactor and assesses its performance in post-treatment of brewery wastewater and biomass production. Two different supporting materials (glass/polyurethane) were tested to investigate the effect of surface hydrophobicity on biomass attachment and overall reactor performance. The reactor exhibited high removal efficiency (over 65%) of the wastewater’s pollutants (chemical oxygen demand, nitrate, nitrite, ammonium, orthophosphate, and total Kjeldahl nitrogen), while biomass per reactor surface reached 13.1 and 12.8 g·m−2 corresponding to 406 and 392 mg·L−1 for glass and polyurethane, respectively, after 15 days of cultivation. The hydrophilic glass surface favored initial biomass adhesion, although eventually both materials yielded complete biomass attachment, highlighting that cell-to-cell interactions are the dominant adhesion mechanism in mature biofilms. It was also found that the biofilm accumulated up to 61% of its dry weight in carbohydrates at the end of cultivation, thus making the produced biomass a suitable feedstock for bioethanol production.


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