scholarly journals Influence of metal coordination and light irradiation on hierarchical self-assembly processes

2019 ◽  
Vol 10 (3) ◽  
pp. 752-760 ◽  
Author(s):  
Kalathil K. Kartha ◽  
Naveen Kumar Allampally ◽  
Antiope T. Politi ◽  
Deepak D. Prabhu ◽  
Hayato Ouchi ◽  
...  

We unravel the impact of metal coordination and light irradiation on hierarchical self-assembly processes by combined theoretical and experimental results.

2020 ◽  
Vol 49 (39) ◽  
pp. 13685-13692
Author(s):  
Sinan Bayindir ◽  
Kwang Soo Lee ◽  
Nurullah Saracoglu ◽  
Jon R. Parquette

In this work, we report the impact of pH and metal coordination on the self-assembly of amphiphiles comprised of naphthalenediimide (NDI)–bis(indolyl)methane (BIM) chromophores with a charged l-lysine head group.


2016 ◽  
Author(s):  
Leonardo Becchetti ◽  
Maurizio Fiaschetti ◽  
Francesco Salustri

2019 ◽  
Vol 6 (6) ◽  
pp. 181902 ◽  
Author(s):  
Junchen Lv ◽  
Yuan Chi ◽  
Changzhong Zhao ◽  
Yi Zhang ◽  
Hailin Mu

Reliable measurement of the CO 2 diffusion coefficient in consolidated oil-saturated porous media is critical for the design and performance of CO 2 -enhanced oil recovery (EOR) and carbon capture and storage (CCS) projects. A thorough experimental investigation of the supercritical CO 2 diffusion in n -decane-saturated Berea cores with permeabilities of 50 and 100 mD was conducted in this study at elevated pressure (10–25 MPa) and temperature (333.15–373.15 K), which simulated actual reservoir conditions. The supercritical CO 2 diffusion coefficients in the Berea cores were calculated by a model appropriate for diffusion in porous media based on Fick's Law. The results show that the supercritical CO 2 diffusion coefficient increases as the pressure, temperature and permeability increase. The supercritical CO 2 diffusion coefficient first increases slowly at 10 MPa and then grows significantly with increasing pressure. The impact of the pressure decreases at elevated temperature. The effect of permeability remains steady despite the temperature change during the experiments. The effect of gas state and porous media on the supercritical CO 2 diffusion coefficient was further discussed by comparing the results of this study with previous study. Based on the experimental results, an empirical correlation for supercritical CO 2 diffusion coefficient in n -decane-saturated porous media was developed. The experimental results contribute to the study of supercritical CO 2 diffusion in compact porous media.


2021 ◽  
Vol 22 (6) ◽  
pp. 3098
Author(s):  
Aleksander Strugała ◽  
Jakub Jagielski ◽  
Karol Kamel ◽  
Grzegorz Nowaczyk ◽  
Marcin Radom ◽  
...  

Virus-like particles (VLPs), due to their nanoscale dimensions, presence of interior cavities, self-organization abilities and responsiveness to environmental changes, are of interest in the field of nanotechnology. Nevertheless, comprehensive knowledge of VLP self-assembly principles is incomplete. VLP formation is governed by two types of interactions: protein–cargo and protein–protein. These interactions can be modulated by the physicochemical properties of the surroundings. Here, we used brome mosaic virus (BMV) capsid protein produced in an E. coli expression system to study the impact of ionic strength, pH and encapsulated cargo on the assembly of VLPs and their features. We showed that empty VLP assembly strongly depends on pH whereas ionic strength of the buffer plays secondary but significant role. Comparison of VLPs containing tRNA and polystyrene sulfonic acid (PSS) revealed that the structured tRNA profoundly increases VLPs stability. We also designed and produced mutated BMV capsid proteins that formed VLPs showing altered diameters and stability compared to VLPs composed of unmodified proteins. We also observed that VLPs containing unstructured polyelectrolyte (PSS) adopt compact but not necessarily more stable structures. Thus, our methodology of VLP production allows for obtaining different VLP variants and their adjustment to the incorporated cargo.


Author(s):  
Andrea Morone ◽  
Rocco Caferra ◽  
Alessia Casamassima ◽  
Alessandro Cascavilla ◽  
Paola Tiranzoni

AbstractThis work aims to identify and quantify the biases behind the anomalous behavior of people when they deal with the Three Doors dilemma, which is a really simple but counterintuitive game. Carrying out an artefactual field experiment and proposing eight different treatments to isolate the anomalies, we provide new interesting experimental evidence on the reasons why subjects fail to take the optimal decision. According to the experimental results, we are able to quantify the size and the impact of three main biases that explain the anomalous behavior of participants: Bayesian updating, illusion of control and status quo bias.


2004 ◽  
Vol 20 (3) ◽  
pp. 256-280 ◽  
Author(s):  
Xosé Rosales Sequeiros

This article explores second language (L2) learners’ interpretation of reflexive anaphora in VP-Ellipsis by critiquing the work of Ying (2003), who applies Relevance Theory to explain elliptical anaphora. It argues against four claims made in his analysis: that L2 learners apply maximal relevance in anaphoric interpretation; that a procedural account of the impact of referential sentences on VP-ellipsis disambiguation is appropriate; that an account of anaphoric interpretation preferences should be based on processing cost; and that differences in experimental results between intermediate and advanced L2 learners are due to the use of different comprehension strategies (see Sperber, 1994). Instead, it argues: that it is not maximal but rather optimal relevance that is at work; that the key in disambiguating anaphora in VP-elliptical sentences is the achievement of an optimally relevant interpretation; that the role of contextual assumptions in anaphora resolution is to enable L2 learners to derive enough contextual effects to make it worth their effort and, in doing so, identifying (as a side effect) what they take to have been the intended referent; and that what is crucial in the use of comprehension strategies is not processing effort, but rather consistency with the second principle of relevance. Overall, all these factors provide the basis for an alternative and more comprehensive explanation of the experimental results discussed by Ying.


2011 ◽  
Vol 332-334 ◽  
pp. 27-30 ◽  
Author(s):  
Mei Niu ◽  
Zi Lu Wu ◽  
Jin Ming Dai ◽  
Wen Sheng Hou ◽  
Sheng Shi ◽  
...  

Wool fiber was firstly pretreated by nano-SiO2/Ag antibacterial agent, and then dyed with an acid dyes at low temperature by ultrasonic dyeing. Many factors had an important influence on the dye ability and the antibacterial behavior during the dyeing process of antibacterial wool fiber. The experimental results indicate that the dye-takeup rates of antibacterial wool fiber were enhanced with the increase of the concentration of nano-SiO2/Ag, the dyeing temperature, the dyeing time and the ultrasonic frequency (less than 60Hz). However, the antibacterial ratios of wool fiber were declined in the impact of these factors other than the concentration of antibacterial agent.


2013 ◽  
Vol 281 ◽  
pp. 47-50
Author(s):  
Zhi Hong Chen

In this paper we propose a new steganographic method, which based on wet paper codes and wavelet transformation. The method is designed to embed secret messages in images' wavelet coefficients and depends on images' texture characters in local neighborhood. The receivers can extract secret bits from carrier images only by some matrix multiplications without knowing the formulas written by senders, which further improves steganographic security and minimizes the impact of embedding changes. The experimental results show that our proposed method has good robust and visual concealment performance and proves out it's a practical steganographic algorithm.


2016 ◽  
Vol 28 (12) ◽  
pp. 1614-1626 ◽  
Author(s):  
Wan-Li Song ◽  
Dong-Heng Li ◽  
Yan Tao ◽  
Na Wang ◽  
Shi-Chao Xiu

The aim of this work is to investigate the effect of the small magnetorheological fluid gap on the braking performance of the magnetorheological brake. In this article, theoretical analyses of the output torque are given first, and then the operating principle and design details of the magnetorheological brake whose magnetorheological fluid gap can be altered are presented and discussed. Next, the magnetic circuit of the proposed magnetorheological brake is conducted and further followed by a magnetostatic simulation of the magnetorheological brakes with different sizes of fluid gap. A prototype of the magnetorheological brake is fabricated and a series of tests are carried out to evaluate the braking performance and torque stability, as well as the verification of the simulation results. Experimental results show that the braking torque increases with the increase in the current, and the difference for the impact of the fluid gap on braking performance is huge under different currents. The rules, which the experimental results show, have an important significance on both the improvement of structure design for magnetorheological brake and the investigation of the wear property under different fluid gaps.


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