scholarly journals Heliconical-layered nanocylinders (HLNCs) – hierarchical self-assembly in a unique B4 phase liquid crystal morphology

2019 ◽  
Vol 6 (5) ◽  
pp. 959-968 ◽  
Author(s):  
Sasan Shadpour ◽  
Ahlam Nemati ◽  
Nicola Jane Boyd ◽  
Lin Li ◽  
Marianne Estelle Prévôt ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Self Assembly ◽  
Crystal Morphology ◽  
Phase Liquid

Hierarchical self-assembly in bent-core liquid crystals – the B4 phase with heliconical-layered nanocylinder morphology.

Chiral-induced self-assembly sphere phase liquid crystal with fast switching time

2014 ◽  
Vol 104 (9) ◽  
pp. 091116 ◽  
Author(s):  
Ji-Liang Zhu ◽  
Shui-Bin Ni ◽  
Chao Ping Chen ◽  
Dong-Qing Wu ◽  
Xiao-Long Song ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Self Assembly ◽  
Switching Time ◽  
Fast Switching ◽  
Phase Liquid

scholarly journals Supramolecular self-assembly and physical-gel formation in disc-like liquid crystals: a scalable predictive model for gelation and an application in photovoltaics

RSC Advances ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 6335-6345
Author(s):  
Sehrish Iqbal ◽  
Ammar A. Khan
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Predictive Model ◽  
Self Assembly ◽  
Gel Formation ◽  
Discotic Liquid Crystal ◽  
Physical Gel

The application of triphenylene-based discotic liquid crystal derivatives as physical gelators is investigated.

Orientation, interaction and laser assisted self-assembly of organic single-crystal micro-sheets in a nematic liquid crystal

Soft Matter ◽  
2015 ◽  
Vol 11 (38) ◽  
pp. 7674-7679 ◽  
Author(s):  
M. V. Rasna ◽  
K. P. Zuhail ◽  
U. V. Ramudu ◽  
R. Chandrasekar ◽  
J. Dontabhaktuni ◽  
...  
Keyword(s):  
Experimental Study ◽  
Liquid Crystal ◽  
Liquid Crystals ◽  
Single Crystal ◽  
Nematic Liquid Crystal ◽  
Self Assembly ◽  
Nematic Liquid Crystals ◽  
Directed Assembly ◽  
Orientation Interaction ◽  
Organic Single Crystal

In this paper we report first experimental study on the orientation, interaction and directed-assembly of single crystal micro-sheets in nematic liquid crystals.

scholarly journals The influence of orienting layers on blue phase liquid crystals in rectangular geometries

2018 ◽  
Vol 10 (4) ◽  
pp. 100 ◽  
Author(s):  
Marzena Maria Sala-Tefelska ◽  
Kamil Orzechowski ◽  
Filip A. Sala ◽  
Tomasz R. Woliński ◽  
Olga Strzeżysz ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Electric Field ◽  
Low Voltage ◽  
Bragg Reflection ◽  
Phase Liquid ◽  
Blue Phase ◽  
Blue Phases ◽  
Alignment Layers ◽  
Polymer Stabilized

In this paper, the influence of homeotropic and homogeneous orienting layers is presented in a cell filled with chiral nematic liquid crystals stabilized in a blue phase. The change of selective Bragg reflection from red to blue light was observed for homogeneous layers in rectangular geometries. The growth of blue phase crystals domains in a glass cell as well an influence of temperature and the electric field on such a structure, are also presented. Full Text: PDF ReferencesF. Reinitzer, Beitrage zur Kenntniss des Cholestherins, Monatsh Chem. 9, 421-441, (1888). CrossRef J. Yan, M. Jiao, L. Rao, and S.-T. Wu, "Direct measurement of electric-field-induced birefringence in a polymer-stabilized blue-phase liquid crystal composite", Opt. Express 18, 11450-11455 (2010) CrossRef Y. Chen, D. Xu, S.-T. Wu, S.-i. Yamamoto, Y. Haseba, "A low voltage and submillisecond-response polymer-stabilized blue phase liquid crystal", Appl. Phys. Lett. 102, 141116 (2013) CrossRef Y. Huang, H. Chen, G. Tan, H. Tobata, S. Yamamoto, E. Okabe, Y.-F. Lan, C.-Y. Tsai, and S.-T. Wu, "Optimized blue-phase liquid crystal for field-sequential-color displays", Opt. Mater. Express 7, 641-650 (2017) CrossRef V. Sridurai, M. Mathews, C. V. Yelamaggad, G. G. Nair, "Electrically Tunable Soft Photonic Gel Formed by Blue Phase Liquid Crystal for Switchable Color-Reflecting Mirror", ACS Appl. Mater. Interfaces, 9 (45), 39569-39575 (2017) CrossRef E. Oton, E. Netter, T. Nakano, Y. D.-Katayama, F. Inoue, "Monodomain Blue Phase Liquid Crystal Layers for Phase Modulation", Sci. Rep. vol.7, 44575 (2017) CrossRef Q. Liu, D. Luo, X. Zhang, S. Li, Z. Tian, "Refractive index and absorption coefficient of blue phase liquid crystal in terahertz band", Liq. Cryst., Vol. 44, No. 2, pp. 348-354 (2017) CrossRef Y. Li, Y. Liu, Q. Li, S.-T. Wu, "Polarization independent blue-phase liquid crystal cylindrical lens with a resistive film", Appl. Opt., Vol. 51, No. 14, pp. 2568-2572 (2012) CrossRef M. M. Sala-Tefelska, K. Orzechowski M. Sierakowski, A. Siarkowska, T.R. Woliński, O. Strzeżysz, P. Kula, "Influence of cylindrical geometry and alignment layers on the growth process and selective reflection of blue phase domains", Opt. Mater. 75, 211-215, (2018) CrossRef H. Claus, O. Willekens, O. Chojnowska, R. Dąbrowski, J. Beeckman, K. Neyts, "Inducing monodomain blue phase liquid crystals by long-lasting voltage application during temperature variation", Liq. Cryst. 43 (5), 688-693, (2016) CrossRef M. Takahashi, T. Ohkawa, H. Yoshida, J. Fukuda, H. Kikuchi, M. Ozaki, "Orientation of liquid crystalline blue phases on unidirectionally orienting surfaces", J. Phys. D: Appl. Phys. 51 (10), 104003 (2018) CrossRef P. Joshi, X. Shang, J. De Smet, E. Islamai, D. Cuypers, G. Van Steenberge, S. Van Vlierberghe, P. Dubruel, H. De Smet, "On the effect of alignment layers on blue phase liquid crystals", Appl. Phys. Lett. 106, 101105 (2015) CrossRef K. Orzechowski, M.W. Sierakowski, M. Sala-Tefelska, P. Joshi, T.R. Woliński, H.D. Smet, "Polarization properties of cubic blue phases of a cholesteric liquid crystal", Opt. Mater. 69, 259-264 (2017) CrossRef P.-J. Chen, M. Chen, S.-Y. Ni, H.-S. Chen, Y.-H. Lin, "Influence of alignment layers on crystal growth of polymer-stabilized blue phase liquid crystals", pt. Mater. Express 6, 1003-1010 (2016) CrossRef CrossRef

scholarly journals Theoretical approach of a polymer stabilized blue phase beam steering

2017 ◽  
Vol 9 (1) ◽  
pp. 14
Author(s):  
Jose Francisco Algorri ◽  
Virginia Urruchi ◽  
Noureddine Bennis ◽  
Jose Manuel Sanchez-Pena
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Response Time ◽  
Deflection Angle ◽  
Beam Steering ◽  
Phase Plate ◽  
First Case ◽  
Phase Liquid ◽  
Blue Phase ◽  
Polymer Stabilized

Nematic liquid crystal (LC)-based beam steering has been reported for wide applications. However, for conventional nematic LC beam steering the thickness is of several microns in order to have a wider deflection angle. The response time is relatively slow and the diffraction efficiency is low. In this work, novel beam steering based on polymer stabilized blue phase liquid crystal (PS-BPLC) has been designed and theoretically analyzed. This special mesophase of the chiral doped nematic LC has several advantageous characteristics, for example no need for alignment layers, microsecond response time and an isotropic voltage-off state. The results reveal control over phase retardation. The direction of the steered beam can be tuned by voltage. Depending on voltage configuration, either diffractive beam steering (0.5deg deviation for 1st order) or a tunable continuous phase (tunable deviation of 0.002deg) can be obtained. In the first case, the deflection angle could be tuned by stacks of samples. The second option has the same phase shift for the TE and TM modes so unpolarized light could be used. Full Text: PDF ReferencesF. Feng, I. White, T. Wilkinson, "Free Space Communications With Beam Steering a Two-Electrode Tapered Laser Diode Using Liquid-Crystal SLM", J. Lightwave Technol. 31, 2001 (2013). CrossRef E. Oton, J. Perez-Fernandez, D. Lopez-Molina, X. Quintana, J.M. Oton, M.A. Geday, "Reliability of Liquid Crystals in Space Photonics", IEEE Photonics Journal 7, 1 (2015). CrossRef J. Stockley, S. Serati, "Multi-access laser terminal using liquid crystal beam steering", IEEE in Aerospace Conference, 1972 (2005). CrossRef D. Zografopoulos and E. Kriezis, "Switchable beam steering with zenithal bistable liquid-crystal blazed gratings", Opt. Lett. 39, 5842 (2014). CrossRef Benedikt Scherger, et al., "Discrete Terahertz Beam Steering with an Electrically Controlled Liquid Crystal Device", J. Infrared. Millim. Terahertz Waves 33, 1117 (2012). CrossRef M.A. Geday, X. Quintana, E. Otón, B. Cerrolaza, D. Lopez, F. Garcia de Quiro, I. Manolis, A. Short, Proc. ICSO, Rhodes, Greece, pp. 1-4 (2010). CrossRef Y. Chen, S.-T. Wu, "The outlook for blue-phase LCDs", Proc. SPIE 9005, Advances in Display Technologies IV, 900508 (2014). CrossRef G.D. Love, A.F. Naumov, "Modal liquid crystal lenses", Liq. Cryst. Today 10, 1 (2000). CrossRef V. Urruchi, J.F. Algorri, J.M. Sánchez-Pena, M.A. Geday, X. Quintana, N. Bennis, "Lenticular Arrays Based on Liquid Crystals", Opto-Electron. Rev. 20, 38 (2012). CrossRef J.F. Algorri, G. Love, and V. Urruchi, "Modal liquid crystal array of optical elements", Opt. Express 21, 24809 (2013). CrossRef J.F. Algorri, V. Urruchi, N. Bennis, J. Sánchez-Pena, "Modal liquid crystal microaxicon array", Opt. Lett. 39, 3476 (2014). CrossRef J.F. Algorri, V. Urruchi, B. Garcia-Camara, J.M. Sánchez-Pena, "Generation of Optical Vortices by an Ideal Liquid Crystal Spiral Phase Plate", IEEE Elect. Dev. Lett. 35, 856 (2014). CrossRef D. Xu, Y. Chen, Y. Liu, S. Wu, "Refraction effect in an in-plane-switching blue phase liquid crystal cell", Opt. Express 21, 24721 (2013). CrossRef Z. Ge, S. Gauza, M. Jiao, H. Xianyu, S.T. Wu, "Electro-optics of polymer-stabilized blue phase liquid crystal displays", Appl. Phys. Lett. 94 101104 (2009). CrossRef J. Yan et al., "Extended Kerr effect of polymer-stabilized blue-phase liquid crystals", Appl. Phys. Lett. 96, 071105 (2010). CrossRef X. Wang, D. Wilson, R. Muller, P. Maker, D. Psaltis, "Liquid-crystal blazed-grating beam deflector, Appl. Opt. 39, 6545 (2000). CrossRef

scholarly journals Synthesis, Self-Assembly and Photoresponsive Behavior of Liquid Crystals Based on Azobenzene

Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1560
Author(s):  
Yaming Wu ◽  
Yuhai Liu ◽  
Jianxiang Chen ◽  
Runmiao Yang
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Self Assembly ◽  
Driving Force ◽  
1H Nmr Spectroscopy ◽  
Uv Light ◽  
Light Exposure ◽  
Scanning Calorimetry ◽  
Stimulus Response ◽  
Cis Isomer

A new amphiphilic surfactant (C4-Azo-C5-HDA) was formed by liquid crystals (LCs) based on azobenzene, whose structures were characterized by 1H-NMR spectroscopy. The reversible hydrogelation upon changes in temperature and light exposure was also studied. Under the irradiation of UV light, the trans-isomer of C4-Azo-C5-HDA rapidly photoisomerized to the cis-isomer, resulting in rapid disruption of the gel. The thermotropic liquid crystal behavior of the gelator was investigated via Differential Scanning Calorimetry (DSC) and Polarizing Optical Microscopy (POM). The biocompatibility experiment of multi-stimulus response of the liquid crystal provides a potential driving force for the development of biomaterials.

scholarly journals Adjacent functional group effects on the assembly of columnar liquid crystals

2020 ◽  
Vol 98 (7) ◽  
pp. 379-385
Author(s):  
Carson O. Zellman ◽  
Danielle Vu ◽  
Vance E. Williams
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Self Assembly ◽  
Room Temperature ◽  
Functional Group ◽  
The Self ◽  
Clearing Temperature ◽  
Crystal Phases ◽  
Potential Strategy ◽  
The Impact

Although the impact of individual functional groups on the self-assembly of columnar liquid crystal phases has been widely studied, the effect of varying multiple substituents has received much less attention. Herein, we report a series of dibenzo[a,c]phenazines containing an alcohol or ether adjacent to an electron-withdrawing ester or acid. With one exception, these difunctional mesogens form columnar phases. The phase behavior appeared to be dominated by the electron-withdrawing substituent; transition temperatures were similar to derivatives with these groups in isolation. In most instances, the addition of an electron-donating group ortho to an ester or acid suppressed the melting temperature and elevated the clearing temperature, leading to broader liquid crystal thermal ranges. This effect was more pronounced for derivatives functionalized with longer chain hexyloxy groups. These results suggest a potential strategy for controlling the phase ranges of columnar liquid crystals and achieving room temperature mesophases.

scholarly journals Periodic assembly of nanoparticle arrays in disclinations of cholesteric liquid crystals

2017 ◽  
Vol 114 (9) ◽  
pp. 2137-2142 ◽  
Author(s):  
Yunfeng Li ◽  
Elisabeth Prince ◽  
Sangho Cho ◽  
Alinaghi Salari ◽  
Youssef Mosaddeghian Golestani ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Self Assembly ◽  
Soft Matter ◽  
Cholesteric Liquid Crystal ◽  
Topological Defects ◽  
Spatial Inhomogeneity ◽  
Cholesteric Phase ◽  
Anisotropic Surface ◽  
Linear Defects

An important goal of the modern soft matter science is to discover new self-assembly modalities to precisely control the placement of small particles in space. Spatial inhomogeneity of liquid crystals offers the capability to organize colloids in certain regions such as the cores of the topological defects. Here we report two self-assembly modes of nanoparticles in linear defects-disclinations in a lyotropic colloidal cholesteric liquid crystal: a continuous helicoidal thread and a periodic array of discrete beads. The beads form one-dimensional arrays with a periodicity that matches half a pitch of the cholesteric phase. The periodic assembly is governed by the anisotropic surface tension and elasticity at the interface of beads with the liquid crystal. This mode of self-assembly of nanoparticles in disclinations expands our ability to use topological defects in liquid crystals as templates for the organization of nanocolloids.

Liquid-crystal metasurfaces: Self-assembly for versatile optical functionality

2022 ◽  
Author(s):  
Irina V. Kasyanova ◽  
Maxim V. Gorkunov ◽  
Serguei P. Palto
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Self Assembly ◽  
Fluid Phase ◽  
Photonic Devices ◽  
Light Diffraction ◽  
Applied Potential ◽  
Surface Alignment ◽  
Optical Functions ◽  
External Stimuli

Abstract Liquid crystals subjected to modulated surface alignment assemble into metasurface-type structures capable of various flat-optical functionalities, including light diffraction and focusing, deflection and splitting. Remaining in a fluid phase, they are susceptible to external stimuli, and, in particular, can be efficiently controled by low voltages. We overview the existing approaches to the design and fabrication of liquid-crystal metasurfaces, highlight their realized optical functions and discuss the applied potential in emerging photonic devices.

Liquid Crystal Influenced Self-assembly in Mesogenic Polymer and Liquid Crystal Blends

2004 ◽  
Vol 856 ◽  
Author(s):  
Lanfang Li ◽  
Carmen Otilia Catanescu ◽  
Liang-Chy Chien
Keyword(s):  
Liquid Crystal ◽  
Liquid Crystals ◽  
Self Assembly ◽  
Polymer Network ◽  
Monomer Concentration ◽  
Curing Temperature ◽  
Low Molecular Weight ◽  
Photo Polymerization ◽  
Anisotropic Elastic ◽  
Polymerization Conditions

ABSTRACTIn this work, we found that by performing photo-polymerization of the mesogenic monomer RM257 in liquid crystals, well organized polymer walls were formed through out the cell by self-assembly of the polymer within the anisotropic host – the liquid crystal. The polymerization conditions, which were parameterized as UV intensity, photo-reactivity (characterized by photo initiator concentration), curing temperature, monomer concentration and mesophase of the liquid crystal host, were systematically varied. Different liquid crystal host also raised some difference in polymer network. We believe this kind of morphology comes from spinodal decomposition and the anisotropic elastic property of the liquid crystal host. It is found that for RM257 and low molecular weight nematic liquid crystals a monomer concentration of 5% is sufficient to use liquid crystal hosts to work as templates for well structured polymer walls.

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