scholarly journals A process of leaching recovery for cobalt and lithium from spent lithium-ion batteries by citric acid and salicylic acid

RSC Advances ◽  
2021 ◽  
Vol 11 (44) ◽  
pp. 27689-27700
Author(s):  
Meiling Xu ◽  
Shumei Kang ◽  
Feng Jiang ◽  
Xinyong Yan ◽  
Zhongbo Zhu ◽  
...  

A new mixed organic acid of citric acid and salicylic acid is proposed to recover valuable Co and Li ions from spent LIBs. Under the optimum leaching conditions, the leaching efficiencies of Co and Li ions can reach 99.5% and 97%.

JOM ◽  
2019 ◽  
Vol 71 (10) ◽  
pp. 3673-3681 ◽  
Author(s):  
Guilan Gao ◽  
Xin He ◽  
Xiaoyi Lou ◽  
Zheng Jiao ◽  
Yaoguang Guo ◽  
...  

Metals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 316 ◽  
Author(s):  
Denis Werner ◽  
Urs Alexander Peuker ◽  
Thomas Mütze

The recycling of spent lithium-ion batteries (LIB) is becoming increasingly important with regard to environmental, economic, geostrategic, and health aspects due to the increasing amount of LIB produced, introduced into the market, and being spent in the following years. The recycling itself becomes a challenge to face on one hand the special aspects of LIB-technology and on the other hand to reply to the idea of circular economy. In this paper, we analyze the different recycling concepts for spent LIBs and categorize them according to state-of-the-art schemes of waste treatment technology. Therefore, we structure the different processes into process stages and unit processes. Several recycling technologies are treating spent lithium-ion batteries worldwide focusing on one or several process stages or unit processes.


2017 ◽  
Vol 46 (41) ◽  
pp. 14382-14392 ◽  
Author(s):  
Subramanian Natarajan ◽  
S. Anantharaj ◽  
Rajesh J. Tayade ◽  
Hari C. Bajaj ◽  
Subrata Kundu

The recovery of spinel MnCo2O4 from spent LIBs was achieved by a set of physical and chemical treatments, their employment for water oxidation in alkaline conditions was studied, and it was found that the recovered spinel MnCo2O4 were more effective than recovered monometallic oxides.


2015 ◽  
Vol 44 (42) ◽  
pp. 18624-18631 ◽  
Author(s):  
Zhao-Jin Wu ◽  
Dong Wang ◽  
Zhi-Fang Gao ◽  
Hai-Feng Yue ◽  
Wei-Ming Liu

This study on Cu-doped Li[NiCoMn]1/3O2 provides support for reusing Cu as a beneficial dopant in the production of metal-doped Li[NiCoMn]1/3O2 from spent LIBs.


Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3343
Author(s):  
Ayesha Arif ◽  
Ming Xu ◽  
Jamshaid Rashid ◽  
Chaudry Sajed Saraj ◽  
Wei Li ◽  
...  

Owing to technological advancements and the ever-increasing population, the search for renewable energy resources has increased. One such attempt at finding effective renewable energy is recycling of lithium-ion batteries and using the recycled material as an electrocatalyst for the oxygen evolution reaction (OER) step in water splitting reactions. In electrocatalysis, the OER plays a crucial role and several electrocatalysts have been investigated to improve the efficiency of O2 gas evolution. Present research involves the use of citric acid coupled with lemon peel extracts for efficient recovery of lithium cobaltate from waste lithium-ion batteries and subsequent use of the recovered cathode material for OER in water splitting. Optimum recovery was achieved at 90 °C within 3 h of treatment with 1.5 M citric acid and 1.5% extract volume. The consequent electrode materials were calcined at 600, 700 and 800 °C and compared to the untreated waste material calcined at 600 °C for OER activity. The treated material recovered and calcined at 600 °C was the best among all of the samples for OER activity. Its average particle size was estimated to be within the 20–100 nm range and required a low overpotential of 0.55 V vs. RHE for the current density to reach 10 mA cm2 with a Tafel value of 128 mV/dec.


2020 ◽  
Vol 4 (5) ◽  
pp. 2583-2592 ◽  
Author(s):  
Yong Wang ◽  
Xiaolan Wang ◽  
Hong Jin ◽  
Yu Bai ◽  
Hui Xu

Using silicon/carbon composites is one of the most attractive strategies to improve the anode performance for lithium ion batteries.


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