scholarly journals Detection of CS in Neptune’s atmosphere from ALMA observations

2017 ◽  
Vol 608 ◽  
pp. L5 ◽  
Author(s):  
R. Moreno ◽  
E. Lellouch ◽  
T. Cavalié ◽  
A. Moullet
Keyword(s):  
Column Density ◽  
Lower Stratosphere ◽  
Giant Planet ◽  
Mixing Ratio ◽  
Carbon Sulfide ◽  
Vertical Location ◽  
Strong Depletion

Context. The large and vertically non-uniform abundance of CO in Neptune’s atmosphere has been interpreted as the result of past cometary impact(s), either single or distributed in size and time, which could also be at the origin of Neptune’s HCN. Aims. We aim to provide observational support for this scenario by searching for other comet-induced species, in particular carbon sulfide (CS) which has been observed continuously in Jupiter since the 1994 Shoemaker-Levy 9 impacts. Methods. In April 2016 we used the ALMA interferometer to search for CS(7-6) at 342.883 GHz in Neptune. Results. We report on the detection of CS in Neptune’s atmosphere, the first unambiguous observation of a sulfur-bearing species in a giant planet beyond Jupiter. Carbon sulfide appears to be present only at submillibar levels, with a column density of (2.0–3.1) × 1012 cm-2, and a typical mixing ratio of (2−20) × 10-11 that depends on its precise vertical location. The favoured origin of CS is deposition by a putative large comet impact several centuries ago, and the strong depletion of CS with respect to CO – compared to the Jupiter case – is likely due to the CS sticking to aerosols or clustering to form polymers in Neptune’s lower stratosphere. Conclusions. The CS detection, along with recent analyses of the CO profile, reinforces the presumption of a large comet impact into Neptune ~1000 yr ago, that delivered CO, CS, and HCN at the same time.

scholarly journals Ultrathin Tropical Tropopause Clouds (UTTCs): I. Cloud morphology and occurrence

2003 ◽  
Vol 3 (4) ◽  
pp. 1083-1091 ◽  
Author(s):  
Th. Peter ◽  
B. P. Luo ◽  
M. Wirth ◽  
C. Kiemle ◽  
H. Flentje ◽  
...  
Keyword(s):  
Gas Phase ◽  
Large Scale ◽  
Lower Stratosphere ◽  
Western Indian Ocean ◽  
Ice Crystals ◽  
Mixing Ratio ◽  
Efficient Point ◽  
Tropical Tropopause ◽  
Cold Point

Abstract. Subvisible cirrus clouds (SVCs) may contribute to dehydration close to the tropical tropopause. The higher and colder SVCs and the larger their ice crystals, the more likely they represent the last efficient point of contact of the gas phase with the ice phase and, hence, the last dehydrating step, before the air enters the stratosphere. The first simultaneous in situ and remote sensing measurements of SVCs were taken during the APE-THESEO campaign in the western Indian ocean in February/March 1999. The observed clouds, termed Ultrathin Tropical Tropopause Clouds (UTTCs), belong to the geometrically and optically thinnest large-scale clouds in the Earth's atmosphere. Individual UTTCs may exist for many hours as an only 200--300 m thick cloud layer just a few hundred meters below the tropical cold point tropopause, covering up to 105 km2. With temperatures as low as 181 K these clouds are prime representatives for defining the water mixing ratio of air entering the lower stratosphere.

Water-vapor Measurements in the Lower Stratosphere

1974 ◽  
Vol 52 (8) ◽  
pp. 1527-1531 ◽  
Author(s):  
H. J. Mastenbrook
Keyword(s):  
Water Vapor ◽  
Lower Stratosphere ◽  
Marked Decrease ◽  
Vapor Concentration ◽  
Water Vapor Concentration ◽  
Mixing Ratio ◽  
Stratospheric Water Vapor ◽  
Mixing Ratios ◽  
Natural Concentration ◽  
General Range

Nearly 10 years of water-vapor measurements to heights of 30 km provide a basis for assessing the natural concentration of stratospheric water vapor and its variability. The measurements which began in 1964 have been made at monthly intervals from the mid-latitude location of Washington, D.C, using a balloon-borne frost-point hygrometer. The observations show the mixing ratio of water-vapor mass to air mass in the stratosphere to be in the general range of 1 to 4 p.p.m. with a modal concentration between 2 and 3 p.p.m. An annual cycle of mixing ratio is evident for the low stratosphere. A trend of water-vapor increase observed during the first 6 years does not persist beyond 1969 or 1970. The 6 year increase was followed by a marked decrease in 1971, with mixing ratios remaining generally below 3 p.p.m. thereafter. The measurements of recent years suggest that the series of observations may have begun during a period of low water-vapor concentration in the stratosphere.

scholarly journals Quantifying the Imprint of a Severe Hector Thunderstorm during ACTIVE/SCOUT-O3 onto the Water Content in the Upper Troposphere/Lower Stratosphere

2009 ◽  
Vol 137 (8) ◽  
pp. 2493-2514 ◽  
Author(s):  
Charles Chemel ◽  
Maria R. Russo ◽  
John A. Pyle ◽  
Ranjeet S. Sokhi ◽  
Cornelius Schiller
Keyword(s):  
Water Vapor ◽  
Water Content ◽  
Lower Stratosphere ◽  
Horizontal Resolution ◽  
Convective Transport ◽  
Mixing Ratio ◽  
Field Campaign ◽  
Upper Troposphere ◽  
Ice Particles ◽  
Water Vapor Mixing Ratio

Abstract The development of a severe Hector thunderstorm that formed over the Tiwi Islands, north of Australia, during the Aerosol and Chemical Transport in Tropical Convection/Stratospheric-Climate Links with Emphasis on the Upper Troposphere and Lower Stratosphere (ACTIVE/SCOUT-O3) field campaign in late 2005, is simulated by the Advanced Research Weather Research and Forecasting (ARW) model and the Met Office Unified Model (UM). The general aim of this paper is to investigate the role of isolated deep convection over the tropics in regulating the water content in the upper troposphere/lower stratosphere (UT/LS). Using a horizontal resolution as fine as 1 km, the numerical simulations reproduce the timing, structure, and strength of Hector fairly well when compared with field campaign observations. The sensitivity of results from ARW to horizontal resolution is investigated by running the model in a large-eddy simulation mode with a horizontal resolution of 250 m. While refining the horizontal resolution to 250 m leads to a better representation of convection with respect to rainfall, the characteristics of the Hector thunderstorm are basically similar in space and time to those obtained in the 1-km-horizontal-resolution simulations. Several overshooting updrafts penetrating the tropopause are produced in the simulations during the mature stage of Hector. The penetration of rising towering cumulus clouds into the LS maintains the entrainment of air at the interface between the UT and the LS. Vertical exchanges resulting from this entrainment process have a significant impact on the redistribution of atmospheric constituents within the UT/LS region at the scale of the islands. In particular, a large amount of water is injected in the LS. The fate of the ice particles as Hector develops drives the water vapor mixing ratio to saturation by sublimation of the injected ice particles, moistening the air in the LS. The moistening was found to be fairly significant above 380 K and averaged about 0.06 ppmv in the range 380–420 K for ARW. As for UM, the moistening was found to be much larger (about 2.24 ppmv in the range of 380–420 K) than for ARW. This result confirms that convective transport can play an important role in regulating the water vapor mixing ratio in the LS.

A depletion of ammonia and water by storms in the deep atmosphere of Jupiter

2020 ◽  
Author(s):  
Tristan Guillot ◽  
David J Stevenson ◽  
Scott J Bolton ◽  
Cheng Li ◽  
Sushil K Atreya ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Giant Planet ◽  
Small Scale ◽  
Ammonia Vapor ◽  
Equatorial Zone ◽  
Water Ice ◽  
Deep Interior ◽  
New Vision ◽  
Temperature Liquid ◽  
Strong Depletion

<p>Microwave observations by the Juno spacecraft have shown that, contrary to expectations, the concentration of ammonia is still variable down to pressures of tens of bars in Jupiter. While mid-latitudes show a strong depletion, the equatorial zone of Jupiter has an abundance of ammonia that is high and nearly uniform with depth. In parallel, Juno determined that the Equatorial Zone is peculiar for its absence of lightning, which is otherwise prevalent most everywhere else on the planet. We show that a model accounting for the presence of small-scale convection and water storms originating in Jupiter’s deep atmosphere accounts for the observations. At mid-latitudes, where thunderstorms powered by water condensation are present, ice particles may be lofted high in the atmosphere, in particular into a region located at pressures between 1.1 and 1.5 bar and temperatures between 173K and 188K, where ammonia vapor can dissolve into water ice to form a low-temperature liquid phase containing about 1/3 ammonia and 2/3 water. We estimate that, following the process creating hailstorms on Earth, this liquid phase enhances the growth of hail-like particles that we call ‘mushballs’. Their growth and fall over many scale heights can effectively deplete ammonia, and consequently, water to great depths in Jupiter’s atmosphere. In the Equatorial Zone, the absence of thunderstorms shows that this process is not occurring, implying that small-scale convection can maintain a near homogeneity of this region. We predict that water, which sinks along with ammonia, should also be depleted down to pressures of tens of bars. Except during storms, Jupiter's deep atmosphere should be stabilized by the mean molecular weight gradient created by the increase in abundance of ammonia and water with depth.  This new vision of the mechanisms at play, which are both deep and latitude-dependent, has consequences for our understanding of Jupiter’s deep interior and of giant-planet atmospheres in general.</p>

scholarly journals Vertical distributions of N<sub>2</sub>O isotopocules in the equatorial stratosphere

2018 ◽  
Vol 18 (2) ◽  
pp. 833-844 ◽  
Author(s):  
Sakae Toyoda ◽  
Naohiro Yoshida ◽  
Shinji Morimoto ◽  
Shuji Aoki ◽  
Takakiyo Nakazawa ◽  
...  
Keyword(s):  
High Latitude ◽  
Lower Stratosphere ◽  
Transport Model ◽  
Three Dimensional ◽  
Vertical Gradient ◽  
Mixing Ratio ◽  
Residual Circulation ◽  
Chemical Transport Model ◽  
Eastern Equatorial Pacific ◽  
Middle Stratosphere

Abstract. Vertical profiles of nitrous oxide (N2O) and its isotopocules, isotopically substituted molecules, were obtained over the Equator at altitudes of 16–30 km. Whole air samples were collected using newly developed balloon-borne compact cryogenic samplers over the eastern equatorial Pacific in 2012 and Biak Island, Indonesia, in 2015. They were examined in the laboratory using gas chromatography and mass spectrometry. The mixing ratio and isotopocule ratios of N2O in the equatorial stratosphere showed a weaker vertical gradient than the previously reported profiles in the subtropical and mid-latitude and high-latitude stratosphere. From the relation between the mixing ratio and isotopocule ratios, further distinct characteristics were found over the Equator: (1) observed isotopocule fractionations (ε values) in the middle stratosphere (25–30 km or [N2O] < ca. 260 nmol mol−1) are almost equal to ε values reported from broadband photolysis experiments conducted in the laboratory; (2) ε values in the lower stratosphere (< ca. 25 km or [N2O] > ca. 260 nmol mol−1) are about half of the experimentally obtained values, being slightly larger than those observed in the mid-latitude and high-latitude lower stratosphere ([N2O] > ca. 170 nmol mol−1). These results from the deep tropics suggest the following. (i) The timescale for quasi-horizontal mixing between tropical and mid-latitude air in the tropical middle stratosphere is sufficiently slow relative to the tropical upwelling rate that isotope fractionation approaches the Rayleigh limit for N2O photolysis. (ii) The air in the tropical lower stratosphere is exchanged with extratropical air on a timescale that is shorter than that of photochemical decomposition of N2O. Previously observed ε values, which are invariably smaller than those of photolysis, can be explained qualitatively using a three-dimensional chemical transport model and using a simple model that assumes mixing of “aged” tropical air and extratropical air during residual circulation. Results show that isotopocule ratios are useful to examine the stratospheric transport scheme deduced from tracer–tracer relations.

scholarly journals Observations of volcanic SO<sub>2</sub> from MLS on Aura

2015 ◽  
Vol 8 (1) ◽  
pp. 195-209 ◽  
Author(s):  
H. C. Pumphrey ◽  
W. G. Read ◽  
N. J. Livesey ◽  
K. Yang
Keyword(s):  
Sulfur Dioxide ◽  
Internal Consistency ◽  
Lower Stratosphere ◽  
Volcanic Eruptions ◽  
Mixing Ratio ◽  
Sulfate Aerosols ◽  
Upper Troposphere ◽  
Volcanic Events ◽  
Total Column ◽  
Atmospheric Constituent

Abstract. Sulfur dioxide (SO2) is an important atmospheric constituent, particularly in the aftermath of volcanic eruptions. These events can inject large amounts of SO2 into the lower stratosphere, where it is oxidised to form sulfate aerosols; these in turn have a significant effect on the climate. The MLS instrument on the Aura satellite has observed the SO2 mixing ratio in the upper troposphere and lower stratosphere from August 2004 to the present, during which time a number of volcanic eruptions have significantly affected those regions of the atmosphere. We describe the MLS SO2 data and how various volcanic events appear in the data. As the MLS SO2 data are currently not validated we take some initial steps towards their validation. First we establish the level of internal consistency between the three spectral regions in which MLS is sensitive to SO2. We compare SO2 column values calculated from MLS data to total column values reported by the OMI instrument. The agreement is good (within about 1 DU) in cases where the SO2 is clearly at altitudes above 147 hPa.

Calibration of the Purple Crow Lidar vibrational Raman water-vapour mixing ratio and temperature measurements

2007 ◽  
Vol 85 (2) ◽  
pp. 119-129 ◽  
Author(s):  
P S Argall ◽  
R J Sica ◽  
C R Bryant ◽  
M Algara-Siller ◽  
H Schijns
Keyword(s):  
Water Vapour ◽  
Cross Sections ◽  
Lower Stratosphere ◽  
Temperature Profiles ◽  
Mixing Ratio ◽  
Atmospheric Transmission ◽  
External Calibration ◽  
Water Vapour Concentration ◽  
Vapour Concentration

Purple Crow Lidar (PCL) measurements of the vibrational Raman-shifted backscatter from water vapour and nitrogen molecules allows height profiles of the water-vapour mixing ratio to be measured from 500 m up into the lower stratosphere. In addition, the Raman nitrogen measurements allow the determination of temperature profiles from about 10 to 40 km altitude. However, external calibration of these measurements is necessary to compensate for instrumental effects, uncertainties in our knowledge of the relevant molecular cross sections, and atmospheric transmission. A comparison of the PCL-derived water-vapour concentration and temperature profiles with routine radiosonde measurements from Detroit and Buffalo on 37 and 141 nights, respectively, was undertaken to provide this calibration. The calibration is then applied to the measurements and monthly mean-temperature and water-vapour profiles are determined.PACS Nos.: 42.68.Wt, 42.79.Qx

scholarly journals What drives the observed variability of HCN in the troposphere and lower stratosphere?

2009 ◽  
Vol 9 (21) ◽  
pp. 8531-8543 ◽  
Author(s):  
Q. Li ◽  
P. I. Palmer ◽  
H. C. Pumphrey ◽  
P. Bernath ◽  
E. Mahieu
Keyword(s):  
Atmospheric Chemistry ◽  
Lower Stratosphere ◽  
Transport Model ◽  
Atmospheric Transport ◽  
Negative Bias ◽  
Mixing Ratio ◽  
Chemistry Transport Model ◽  
Annual Variations ◽  
Surface Emission ◽  
Chemistry Experiment

Abstract. We use the GEOS-Chem global 3-D chemistry transport model to investigate the relative importance of chemical and physical processes that determine observed variability of hydrogen cyanide (HCN) in the troposphere and lower stratosphere. Consequently, we reconcile ground-based FTIR column measurements of HCN, which show annual and semi-annual variations, with recent space-borne measurements of HCN mixing ratio in the tropical lower stratosphere, which show a large two-year variation. We find that the observed column variability over the ground-based stations is determined by a superposition of HCN from several regional burning sources, with GEOS-Chem reproducing these column data with a positive bias of 5%. GEOS-Chem reproduces the observed HCN mixing ratio from the Microwave Limb Sounder and the Atmospheric Chemistry Experiment satellite instruments with a mean negative bias of 20%, and the observed HCN variability with a mean negative bias of 7%. We show that tropical biomass burning emissions explain most of the observed HCN variations in the upper troposphere and lower stratosphere (UTLS), with the remainder due to atmospheric transport and HCN chemistry. In the mid and upper stratosphere, atmospheric dynamics progressively exerts more influence on HCN variations. The extent of temporal overlap between African and other continental burning seasons is key in establishing the apparent bienniel cycle in the UTLS. Similar analysis of other, shorter-lived trace gases have not observed the transition between annual and bienniel cycles in the UTLS probably because the signal of inter-annual variations from surface emission has been diluted before arriving at the lower stratosphere (LS), due to shorter atmospheric lifetimes.

scholarly journals Sulfur dioxide (SO<sub>2</sub>) from MIPAS in the upper troposphere and lower stratosphere 2002–2012

2015 ◽  
Vol 15 (12) ◽  
pp. 7017-7037 ◽  
Author(s):  
M. Höpfner ◽  
C. D. Boone ◽  
B. Funke ◽  
N. Glatthor ◽  
U. Grabowski ◽  
...  
Keyword(s):  
Sulfur Dioxide ◽  
Atmospheric Chemistry ◽  
Lower Stratosphere ◽  
Michelson Interferometer ◽  
Volcanic Eruptions ◽  
Aerosol Layer ◽  
Mixing Ratio ◽  
So2 Emissions ◽  
Data Set ◽  
Upper Troposphere

Abstract. Vertically resolved distributions of sulfur dioxide (SO2) with global coverage in the height region from the upper troposphere to ~20 km altitude have been derived from observations by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on Envisat for the period July 2002 to April 2012. Retrieved volume mixing ratio profiles representing single measurements are characterized by typical errors in the range of 70–100 pptv and by a vertical resolution ranging from 3 to 5 km. Comparison with observations by the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) revealed a slightly varying bias with altitude of −20 to 50 pptv for the MIPAS data set in case of volcanically enhanced concentrations. For background concentrations the comparison showed a systematic difference between the two major MIPAS observation periods. After debiasing, the difference could be reduced to biases within −10 to 20 pptv in the altitude range of 10–20 km with respect to ACE-FTS. Further comparisons of the debiased MIPAS data set with in situ measurements from various aircraft campaigns showed no obvious inconsistencies within a range of around ±50 pptv. The SO2 emissions of more than 30 volcanic eruptions could be identified in the upper troposphere and lower stratosphere (UTLS). Emitted SO2 masses and lifetimes within different altitude ranges in the UTLS have been derived for a large part of these eruptions. Masses are in most cases within estimations derived from other instruments. From three of the major eruptions within the MIPAS measurement period – Kasatochi in August 2008, Sarychev in June 2009 and Nabro in June 2011 – derived lifetimes of SO2 for the altitude ranges 10–14, 14–18 and 18–22 km are 13.3 ± 2.1, 23.6 ± 1.2 and 32.3 ± 5.5 days respectively. By omitting periods with obvious volcanic influence we have derived background mixing ratio distributions of SO2. At 10 km altitude these indicate an annual cycle at northern mid- and high latitudes with maximum values in summer and an amplitude of about 30 pptv. At higher altitudes of about 16–18 km, enhanced mixing ratios of SO2 can be found in the regions of the Asian and the North American monsoons in summer – a possible connection to an aerosol layer discovered by Vernier et al. (2011b) in that region.

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