scholarly journals Structure and mechanical properties of GR/UHMWPE nanocomposite ropes

2019 ◽  
Vol 131 ◽  
pp. 01127
Author(s):  
Wen Wen Yu ◽  
Jian Gao Shi ◽  
Yong Li Liu ◽  
Lei Wang

Ultra-high molecular weight polyethylene (UHMWPE) and graphene (GR) was melt compounded by reactive extrusion. Nanocomposite monofilaments were prepared by melt spinning through a co-rotating screw extruder and drawing at hot water. GR/UHMWPE nanocomposite ropes were twisted using nanocomposite monofilaments. A structure and mechanical properties of the GR/UHMWPE nanocomposite monofilaments and its ropes had been characterized by scanning electron microscopy (SEM), and mechanical test. Results showed that the monofilaments surface of monofilaments became rougher with introducing of GR nanosheets, which could be related to stacking of GR. The breaking load of GR/UHMWPE nanocomposite ropes was remarkably improved upon nanofiller addition, with the decrease of the elongation at break.

2012 ◽  
Vol 466-467 ◽  
pp. 332-335 ◽  
Author(s):  
Jiu Mei Xiao

The porous UHMWPE were prepared by wet process and biaxial stretching. The scanning electron microscopy (SEM) experimental results indicated that there were two discernible components: microfibril bundles and microfibril networks in the porous biaxial UHMWPE. The higher draw ratio along the longitudinal direction (the machine direction) contributed more to orientation of the UHMWPE fibrils. Along the transverse direction, fibrils were torn, and more microfibrils network with larger size formed. The mechanical test results showed that along the longitudinal direction, the UHMWPE exhibited higher tensile strength and lower elongation-at-break.


2008 ◽  
Vol 587-588 ◽  
pp. 520-524 ◽  
Author(s):  
Isabel Moura ◽  
Ana Vera Machado ◽  
Fernando M. Duarte ◽  
Gabriela Botelho ◽  
Regina Nogueira

This work aimed to prepare biodegradable polymeric materials based on blends of a synthetic high density polyethylene (HDPE) and biodegradable polymers such as polylactic acid (PCL) and poly(caprolactone) (PLA), in a co-rotating twin-screw extruder. A polyethylene modified with maleic anhydride was used as compatibiliser. The mechanical results showed that the addition of PLA improves the blends stiffness while the addition of PCL leads to materials with a greater elongation at break and a lower Young modulus. This feature is related with the mechanical properties of each material as well as the adhesion between them. Concerning the biodegradability tests, it was found that HDPE/PCL blend presents the highest degree of biodegradability.


Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4801
Author(s):  
Yasir Khaleel Kirmasha ◽  
Mohaiman J. Sharba ◽  
Zulkiflle Leman ◽  
Mohamed Thariq Hameed Sultan

Fiber composites are known to have poor through-thickness mechanical properties due to the absence of a Z-direction binder. This issue is more critical with the use of natural fibers due to their low strength compared to synthetic fibers. Stitching is a through-thickness toughening method that is used to introduce fibers in the Z-direction, which will result in better through-thickness mechanical properties. This research was carried out to determine the mechanical properties of unstitched and silk fiber-stitched woven kenaf-reinforced epoxy composites. The woven kenaf mat was stitched with silk fiber using a commercial sewing machine. The specimens were fabricated using a hand lay-up method. Three specimens were fabricated, one unstitched and two silk-stitched with deferent stitching orientations. The results show that the stitched specimens have comparable in-plane mechanical properties to the unstitched specimens. For the tensile mechanical test, stitched specimens show similar and 17.1% higher tensile strength compared to the unstitched specimens. The flexural mechanical test results show around a 9% decrease in the flexural strength for the stitched specimens. On the other hand, the Izod impact mechanical test results show a significant improvement of 33% for the stitched specimens, which means that stitching has successfully improved the out-of-plane mechanical properties. The outcome of this research indicates that the stitched specimens have better mechanical performance compared to the unstitched specimens and that the decrease in the flexural strength is insignificant in contrast with the remarkable enhancement in the impact strength.


2015 ◽  
Vol 735 ◽  
pp. 70-74
Author(s):  
Ibrahim Mohammed Inuwa ◽  
Azman Hassan ◽  
Sani Amril Samsudin

This work investigates the effect of compatibilizer concentration on the mechanical properties of compatibilized polyethylene terephthalate (PET) /polypropylene (PP) blends. A blend containing 70 % (wt) PET, 30 % (wt) PP and 5 - 15 phr compatibilizers were compounded using counter rotating twin screw extruder and fabricated into standard test samples using injection molding. The compatibilizer used is styrene-ethylene-butylene-styrene grafted maleic anhydride triblock copolymer (SEBS-g-MAH). Morphological studies show that the particle size of the dispersed PP phase is dependent on the compatibilizer content up to 10 phr. Impact strength and elongation at break showed maximum values with the addition of 10 phr SEBS-g-MAH and a corresponding decrease in flexural and young’s moduli; and strengths.. Overall the mechanical properties of PET/PP blends depend on the control of the morphology of the blend and can be achieved by effective compatibilization using 10 phr SEBS-g-MAH.


2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Yueyun Zhou ◽  
Lifa Luo ◽  
Wenyong Liu ◽  
Guangsheng Zeng ◽  
Yi Chen

To overcome the poor toughness of PC/PLA blends due to the intrinsic properties of materials and poor compatibility, thermoplastic urethane (TPU) was added to PC/PLA blends as a toughener; meantime, catalyst di-n-butyltin oxide (DBTO) was also added for catalyzing transesterification of components in order to modify the compatibility of blends. The mechanical, thermal, and rheological properties of blends were investigated systematically. The results showed that the addition of TPU improves the toughness of PC/PLA blends significantly, with the increase of TPU, the elongation at break increases considerably, and the impact strength increases firstly and then falls, while the tensile strength decreases significantly and the blends exhibit a typical plastic fracture behavior. Meantime, TPU is conducive to the crystallinity of PLA in blends which is inhibited seriously by PC and damages the thermal stability of blends slightly. Moreover, the increased TPU makes the apparent viscosity of blends melt decrease due to the well melt fluidity of TPU; the melt is closer to the pseudoplasticity melt. Remarkably, the transesterification between the components improves the compatibility of blends significantly, and more uniform structure results in a higher crystallinity and better mechanical properties.


2019 ◽  
Vol 90 (3-4) ◽  
pp. 294-301 ◽  
Author(s):  
Weraporn Pivsa-Art ◽  
Sommai Pivsa-Art

Multifilament yarns of polyoxymethylene (POM) and poly(lactic acid) (PLA) blends were prepared using a melt-spinning method. The ratios of the POM/PLA fibers studied were 10/90, 30/70, 50/50, 70/30, and 10/90 by weight compared with that of the pure polymers. The extrusion of the dry blend polymers was carried out using a single-screw extruder at 180–210℃ with a winding speed of 800 m/min. The thermal and morphological analysis of the multifilament yarn confirmed the phase separation of the two polymers. However, the mechanical properties of the blends showed excellent elongation at break, which confirmed the good distribution of PLA in the POM matrix. POM/PLA with weight ratios of 70/30 and 90/10 showed high tenacity. The elongation of the POM/PLA blends shows excellent results, which is unusual for polymer blends with phase separation.


2013 ◽  
Vol 353-356 ◽  
pp. 20-23
Author(s):  
Xiao Lei Wang ◽  
Shun Xi Yan ◽  
Guang Can Zhang

According to the problemsof serious deformation of soft rock roadways and lack of system andcomprehensive study on surrounding rock characteristics and failure mechanismin Shajihai mining area, this paper carried out a series of mechanicalexperiments on the characteristics of surrounding rock in this area includinguniaxial compression test, triaxial compression test and water absorption propertiestest. Mechanical test results show that the compressive strength of surroundingrock of roadway is generally low, and mudstone compressive strength is thelargest which is 19.23 MPa, and compressive strength of the minimum is coalwhich is 11.32 MPa under natural condition. However sandstone and mudstone’sability of water absorbing is strong, and coal saturation strength issignificantly greater than that of mudstone and sandstone. Therefore, we shouldmake full use of the strength of coal in roadway layout and support design.


2011 ◽  
Vol 374-377 ◽  
pp. 170-173
Author(s):  
Li Min Tai

Through the graft copolymerization of LLDPE and the AA-MMA prepolymer by reactive extrusion on the single-screw extruder, the LLPE-g-AA-MMA was prepared and used as compatibilizer for starch/PE blends, and then the compatibilization effect was investigated. The results exhibited that the addition of this compatibilizer substantially improved the mechanical properties, especially the tensile strength. Scanning electron micrographs of the blend specimens also supported the above observations.


2011 ◽  
Vol 378-379 ◽  
pp. 735-739
Author(s):  
Yue Wen Li ◽  
Xin Hua Chen

Reactive compatibilization between high-density polyethylene(HDPE) and wood-flour was achieved via direct reactive extrusion of glycidyl methacrylate(GMA), initiator, HDPE and wood-flour. Impact rupture surface of the composite was observed by scanning electron microscope(SEM), and its load deformation temperature(HDT) and mechanical properties were tested. Effect of GMA dosage and extrusion temperature on reactive compatibilization of the composite was analysed. The result indicated that the anchoring strength of interface in the composite was obviously strengthened, and its HDT, tensile strength, flexural strength, notched impact strength and elongation at break of the composite were distinctly improved due to the addition of GMA and dicumyl peroxide(DCP). When the composite was extruded at 180°C, the peak values of its HDT, tensile strength, flexural strength, elongation at break and notched impact strength respectively were 84°C, 40Mpa, 45Mpa, 11% and 6.6KJ.m-2, which respectively increased by 17°C, 74%, 36%, 83% and 69% than that of the composite without reactive compatibilization, and when the composite was extruded at 190°C, the peak values of its HDT, tensile strength, flexural strength, elongation at break and notched impact strength respectively were 84°C, 40Mpa, 44Mpa, 11% and 6.6KJ.m-2, which respectively increased by 20°C, 60%, 26%, 83% and 83% than that of the composite without reactive compatibilization. When GMA usage increased, the HDT and mechanical properties of the composite increased first, then descended, and the optimum usage of GMA was 1wt%-3wt%.


2014 ◽  
Vol 1025-1026 ◽  
pp. 221-226 ◽  
Author(s):  
Supavinee Sareeladdanon ◽  
Pranut Potiyaraj

Nanocomposite is one of the most favorable approaches to improve mechanical properties of polymers. This study prepared polymer composite of PLA and LLDPE with different amount of rice husk silica (0.5 and 1 wt%). The composites were prepared by melt-mixing in a twin-screw extruder and processed into film by a chill roll cast extruder. The mechanical properties were investigated through tensile testing and tear testing. The result show that the tensile modulus of PLA decreased with 1wt% rice husk silica. Similarly, tensile modulus of LLDPE dropped with the addition of silica. However, with the addition 0.5 and 1 wt% rice husk silica, the elongation at break of PLA and LLDPE composites increases significantly.


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